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    • 1. 发明授权
    • Method of preparing an optical polymerizate
    • 光聚合物的制备方法
    • US07098290B1
    • 2006-08-29
    • US09695332
    • 2000-10-25
    • Michael O. OkoroaforRobert A. SmithRifat TabakovicMarvin J. GrahamRobert D. Herold
    • Michael O. OkoroaforRobert A. SmithRifat TabakovicMarvin J. GrahamRobert D. Herold
    • C08G18/10C08G18/32C08G18/38C08G18/46C08G18/72
    • C08G18/3876C08G18/324C08G18/4277C08G18/758C08G18/7642C08G18/765Y10S348/902Y10T428/31551
    • The present invention is directed to a novel method of preparing a polymerizate, which includes the step of polymerizing a two-component composition, which includes: a first component containing at least one polycyanate reactant having at least two functional groups selected from isocyanate, isothiocyanate and combinations thereof, the polycyanate reactant being the reaction product of: a polythiol monomer having at least two thiol groups; and a polycyanate monomer having at least two functional groups selected from isocyanate, isothiocyanate and combinations thereof; and a second component containing at least one polyamine reactant having at least two functional groups selected from primary amine, secondary amine and combinations thereof. The molar equivalent ratio of (NCO+NCS) groups from the first component to (—NH2+—NH—) groups from the second component is from 0.5 to 100. The present invention is also directed to polymerizates prepared according to the method of the present invention. The present invention is further directed to photochromic articles that may be prepared from the polymerizates of the present invention.
    • 本发明涉及一种制备聚合物的新方法,其包括聚合双组分组合物的步骤,其包括:含有至少一种具有至少两个选自异氰酸酯,异硫氰酸酯的官能团的聚氰酸酯反应物的第一组分和 聚氰酸酯反应物是以下物质的反应产物:具有至少两个硫醇基团的多硫醇单体; 和具有至少两个选自异氰酸酯,异硫氰酸酯及其组合的官能团的聚氰酸酯单体; 和含有至少一种具有至少两个选自伯胺,仲胺及其组合的官能团的多胺反应物的第二组分。 来自第二组分的来自第一组分的(NCO + NCS)基团与(-NH 2 N + N - NH-)基团的摩尔当量比为0.5至100.本发明还涉及 根据本发明的方法制备的聚合物。 本发明还涉及可由本发明的聚合物制备的光致变色制品。