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    • 4. 发明授权
    • Method of making reinforced filament with doubly-embedded nanotubes
    • 双层纳米管加强丝的制备方法
    • US07837905B2
    • 2010-11-23
    • US12121985
    • 2008-05-16
    • Delmar L. BarkerMead M. JordanW. Howard Poisl
    • Delmar L. BarkerMead M. JordanW. Howard Poisl
    • D01D5/12D01F1/10D01F9/22
    • B82Y30/00D01F1/10D01F9/20Y10T428/2918
    • Strengthened filaments and fibers are realized by mixing and dissolving monomer and catalyst in a solvent into open-ended nanotubes to form a polymer precursor prior to polymerization in which the open nanotubes are filled with monomer and catalyst. The remaining steps for forming a stabilized filament may follow the conventional sequence. The result is that the nanotubes are “doubly-embedded” in the polymer matrix (bonds to the polymer inside and extending through the nanotube and bonds to other polymer chains outside the nanotube) in the filament. These additional bonds provide additional mechanical strength. The number of bonds may be further enhanced by pretreating the nanotubes to create defects in the nanotubes to form sites along the inner and outer walls for additional polymer-to-nanotube bonds. The aligned filaments may be radiated to create additional polymer-to-nanotube bonds such as between the polymer chain inside the nanotube and the inner walls of the nanotube and to create nanotube-to-nanotube bonds. In the case of carbon fiber, the carbonized filament may be radiated to create additional carbon-carbon bonds prior to twisting the filaments into the fiber.
    • 通过将单体和催化剂在溶剂中混合并溶解到开放式纳米管中以在聚合之前形成聚合物前体,其中开放纳米管填充有单体和催化剂来实现加强的长丝和纤维。 用于形成稳定的丝的其余步骤可以遵循常规顺序。 结果是纳米管被“双嵌入”在聚合物基质中(与内部聚合物结合并延伸穿过纳米管并与纳米管外部的其它聚合物链结合)。 这些附加键提供额外的机械强度。 可以通过预处理纳米管以在纳米管中产生缺陷以形成沿着内壁和外壁的位点用于另外的聚合物 - 纳米管键来进一步增强键的数量。 可以辐射对准的长丝以产生另外的聚合物 - 纳米管结合,例如在纳米管内部的聚合物链和纳米管的内壁之间,并产生纳米管与纳米管的键。 在碳纤维的情况下,碳化细丝可以在将细丝扭曲成纤维之前被辐射以产生额外的碳 - 碳键。
    • 7. 发明申请
    • REINFORCED FILAMENT WITH DOUBLY-EMBEDDED NANOTUBES AND METHOD OF MANUFACTURE
    • 具有双嵌段纳米管的增强型薄膜及其制造方法
    • US20090286079A1
    • 2009-11-19
    • US12121985
    • 2008-05-16
    • Delmar L. BarkerMead M. JordanW. Howard Poisl
    • Delmar L. BarkerMead M. JordanW. Howard Poisl
    • C08K3/04B32B1/00
    • B82Y30/00D01F1/10D01F9/20Y10T428/2918
    • Strengthened filaments and fibers are realized by mixing and dissolving monomer and catalyst in a solvent into open-ended nanotubes to form a polymer precursor prior to polymerization in which the open nanotubes are filled with monomer and catalyst. The remaining steps for forming a stabilized filament may follow the conventional sequence. The result is that the nanotubes are “doubly-embedded” in the polymer matrix (bonds to the polymer inside and extending through the nanotube and bonds to other polymer chains outside the nanotube) in the filament. These additional bonds provide additional mechanical strength. The number of bonds may be further enhanced by pretreating the nanotubes to create defects in the nanotubes to form sites along the inner and outer walls for additional polymer-to-nanotube bonds. The aligned filaments may be radiated to create additional polymer-to-nanotube bonds such as between the polymer chain inside the nanotube and the inner walls of the nanotube and to create nanotube-to-nanotube bonds. In the case of carbon fiber, the carbonized filament may be radiated to create additional carbon-carbon bonds prior to twisting the filaments into the fiber.
    • 通过将单体和催化剂在溶剂中混合并溶解到开放式纳米管中以在聚合之前形成聚合物前体,其中开放纳米管填充有单体和催化剂来实现加强的长丝和纤维。 用于形成稳定的丝的其余步骤可以遵循常规顺序。 结果是纳米管被“双嵌入”在聚合物基质中(与内部聚合物结合并延伸穿过纳米管并与纳米管外部的其它聚合物链结合)。 这些附加键提供额外的机械强度。 可以通过预处理纳米管以在纳米管中产生缺陷以形成沿着内壁和外壁的位点用于另外的聚合物 - 纳米管键来进一步增强键的数量。 可以辐射对准的长丝以产生另外的聚合物 - 纳米管结合,例如在纳米管内的聚合物链和纳米管的内壁之间,并产生纳米管与纳米管的键。 在碳纤维的情况下,碳化细丝可以在将细丝扭曲成纤维之前被辐射以产生额外的碳 - 碳键。