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    • 9. 发明授权
    • Photosensitive trihalomethyl-s-triazine compound and photopolymerizable
composition
    • 光敏三卤代甲基-s-三嗪化合物和光聚合组合物
    • US5489499A
    • 1996-02-06
    • US329646
    • 1994-10-25
    • Masatoshi Yumoto
    • Masatoshi Yumoto
    • C07D251/24C08F2/50G03F7/029G03C1/725G03F7/028
    • C07D251/24C08F2/50G03F7/0295Y10S430/12Y10S430/121
    • A photosensitive trihalomethyl-s-triazine compound and a photopolymerizable composition containing the photosensitive trihalomethyl-s-triazine compound. The photosensitive trihalomethyl-s-triazine compound is represented by formula (I): ##STR1## wherein X represents a chlorine atom or a bromine atom; Y represents an alkyl group, a CF.sub.3 group, a CF.sub.2 Cl group, an alkyl group substituted with a group or an atom other than hydrogen atoms, a C.sub.6 F.sub.5 group, or a group represented by --Z--CO--OR.sup.3 or --C.sub.6 H.sub.4 --R.sup.4, in which R.sup.3 represents a hydrogen atom or alkyl group, Z represents --C.sub.2 H.sub.4 --, --C.sub.3 H.sub.6 --, --CH.dbd.CH--, or o-phenylene group, and R.sup.4 represents a hydrogen atom, a hydroxyl group, an alkyl group, a substituted alkyl group, an aryl group, an alkoxy group, a substituted alkoxy group, a halogen atom, an alkoxycarbonyl group, a cyano group, an acyl group, a nitro group, a formyl group, a mercapto group, an alkylthio group, or a dialkylamino group; R.sup.1 and R.sup.2 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group, an aryl group, an alkoxy group, a substituted alkoxy group, an acyloxy group, a halogen atom, an alkoxycarbonyl group, a cyano group, a nitro group, a carboxyl group, or a group represented by formula (II) or (III): ##STR2## wherein R.sup.5 and R.sup.6 each independently represent a hydrogen atom, an alkyl group, a substituted alkyl group, or a substituted aryl group, ##STR3## wherein R.sup.7 and R.sup.8 each independently represent a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, or an acyl group, and wherein R.sup.5 and R.sup.7 may be connected to R.sup.6 and R.sup.8 respectively, to form a ring.
    • 感光性三卤甲基-s-三嗪化合物和含有感光性三卤甲基-s-三嗪化合物的光聚合性组合物。 感光性三卤甲基-s-三嗪化合物由式(I)表示:其中X表示氯原子或溴原子; Y表示烷基,CF 3基,CF 2 Cl基,被基团或除氢原子以外的原子取代的烷基,C 6 F 5基或-Z-CO-OR 3或-C 6 H 4 -R 4表示的基团, 其中R3表示氢原子或烷基,Z表示-C2H4-,-C3H6-,-CH = CH-或邻亚苯基,R4表示氢原子,羟基,烷基,取代基 烷基,芳基,烷氧基,取代的烷氧基,卤素原子,烷氧基羰基,氰基,酰基,硝基,甲酰基,巯基,烷硫基或 二烷基氨基 R 1和R 2各自独立地表示氢原子,羟基,烷基,芳基,烷氧基,取代的烷氧基,酰氧基,卤素原子,烷氧基羰基,氰基,硝基 ,羧基或由式(II)或(III)表示的基团:ntly表示氢原子,烷基,取代的烷基或取代的芳基,其中R7和R8 各自独立地表示氢原子,烷基,取代的烷基,芳基,取代的芳基或酰基,并且其中R5和R7可以分别连接到R6和R8以形成环。