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    • 1. 发明授权
    • Process for producing 1,3-butadiene
    • 生产1,3-丁二烯的方法
    • US4504692A
    • 1985-03-12
    • US588085
    • 1984-03-09
    • Masatoshi ArakawaHayao YoshiokaKazuyoshi Nakazawa
    • Masatoshi ArakawaHayao YoshiokaKazuyoshi Nakazawa
    • C07C5/48C07C1/00C07C5/333C07C7/08C07C11/167C07C67/00C07C5/09
    • C07C11/167C07C7/08
    • A process for producing 1,3-butadiene which comprises feeding a fraction comprising C.sub.4 -paraffins and C.sub.4 -olefins as the main components and being free from isobutene, 1,3-butadiene and C.sub.4 -acetylenes to a dehydrogenation or oxidative dehydrogenation step (step A), where the n-butenes contained therein is converted to 1,3-butadiene; feeding the 1,3-butadiene-containing hydrocarbon fraction thus obtained (fraction C) to an extractive distillation column (column B), in which said fraction C is distilled in an atmosphere of a selective solvent while obtaining a fraction comprising C.sub.4 -paraffins as the main hydrocarbon component from the top of the column; withdrawing a fraction comprising n-butenes as the main component as a side stream from a stage on the upper side of the aforementioned fraction C-feeding stage and on the lower side of the selective solvent-feeding stage and recycling it into step A while withdrawing a fraction comprising 1,3-butadiene as the main hydrocarbon component and also containing the selective solvent from the bottom of column B; and separating 1,3-butadiene from the 1,3-butadiene-containing fraction.
    • 一种1,3-丁二烯的制造方法,其特征在于,以含有C4链烷烃和C4-烯烃为主要成分,不含异丁烯,1,3-丁二烯,C4-乙炔的馏分进行脱氢或氧化脱氢工序 A),其中所含的正丁烯转化为1,3-丁二烯; 将由此获得的含1,3-丁二烯的烃馏分(馏分C)加入到萃取蒸馏塔(B馏分)中,其中所述馏分C在选择性溶剂的气氛中蒸馏,同时得到包含C 4链烷烃的馏分 来自塔顶的主要烃成分; 从上述级分C供给级的上侧的阶段和选择性溶剂供给级的下侧取出包含作为主要成分的正丁烯作为主要成分的馏分,并将其再循环到步骤A中,同时退出 包含1,3-丁二烯作为主要烃成分并且还含有来自塔B底部的选择性溶剂的馏分; 并从含1,3-丁二烯的级分中分离出1,3-丁二烯。
    • 2. 发明授权
    • Process for producing 1,3-butadiene or 2-methyl-1,3-butadiene having
high purity
    • 制备高纯度的1,3-丁二烯或2-甲基-1,3-丁二烯的方法
    • US4401515A
    • 1983-08-30
    • US242676
    • 1981-03-11
    • Masatoshi ArakawaKazuyoshi Nakazawa
    • Masatoshi ArakawaKazuyoshi Nakazawa
    • C07C1/00C07C7/08C07C11/12C07C11/167C07C11/18C07C67/00B01D3/40
    • C07C7/08Y10S203/20
    • In a process for producing butadiene or isoprene having a high purity comprising a step of treating a C.sub.4 or C.sub.5 hydrocarbon mixture containing butadiene or isoprene by an extractive distillation method in the presence of a selective solvent to obtain crude butadiene or crude isoprene and a step of separating a heavy fraction contained in a small quantity in the thus obtained crude butadiene or crude isoprene by a conventional distillation method in a heavy fraction separating tower, the heat energy can be saved to a great extent by thermally coupling the tower for distilling crude butadiene or crude isoprene used in the above-mentioned extractive-distillation step with the above-mentioned heavy fraction separating tower, namely by feeding a part or the whole of the vapor stream from the top of said tower for distilling crude butadiene or isoprene to said heavy fraction separating tower and feeding a liquid at a rate corresponding to the whole or a part of the reflux rate necessary for the operation of the tower for distilling crude butadiene or crude isoprene, from the heavy fraction separating tower to the tower for distilling crude butadiene or crude isoprene.
    • 在生产具有高纯度的丁二烯或异戊二烯的方法中,包括在选择性溶剂的存在下通过萃取蒸馏法处理含有丁二烯或异戊二烯的C 4或C 5烃混合物以获得粗丁二烯或粗异戊二烯的步骤, 通过常规蒸馏法在重馏分分离塔中分离由此得到的粗丁二烯或粗异戊二烯中少量含有的重馏分,通过热塔连接用于蒸馏粗丁二烯的热量可以节省很多的热量, 在上述提取 - 蒸馏步骤中使用的粗异戊二烯与上述重馏分分离塔,即通过从塔的顶部进料一部分或全部蒸汽流,以将粗丁二烯或异戊二烯蒸馏到所述重馏分 分离塔并以对应于t所需的全部或部分回流速率的速率进料液体 他操作塔,用于将粗丁二烯或粗异戊二烯从重馏分分离塔蒸馏到塔中以蒸馏粗丁二烯或粗异戊二烯。
    • 3. 发明授权
    • Method for recovering a polymer
    • 回收聚合物的方法
    • US06403761B2
    • 2002-06-11
    • US09885114
    • 2001-06-21
    • Nobuyasu TakamiKazumi UchimuraKunio YoshiokaKazuyoshi Nakazawa
    • Nobuyasu TakamiKazumi UchimuraKunio YoshiokaKazuyoshi Nakazawa
    • C08F600
    • C08F6/12C08C2/06
    • A method for recovering a polymer efficiently from a polymer solution obtained by a solution polymerization is provided. By means of a method for recovering a polymer comprising heating a polymer solution obtained by a solution polymerization indirectly in a pipe to evaporate a solvent while forming a gas-liquid mixed phase flow or a gas-liquid-solid mixed phase flow followed by supplying the mixture to a recovery tank under pressure or under reduced pressure to separate the polymer from the solvent, the polymer can efficiently be separated from the solvent without changing the physical characteristics or the chemical characteristics of the polymer. When recovering a polymer from a polymer solution having a high viscosity, an infusion of water or steam serves to reduce the viscosity of the polymer solution and also to increase the linear velocity of a gas, whereby preventing the occlusion of a pipe and facilitating the operation.
    • 提供了通过溶液聚合获得的聚合物溶液有效回收聚合物的方法。 通过回收聚合物的方法,包括在形成气液混合相流或气 - 液 - 固混合相流的同时,在管中间接加热由溶液聚合获得的聚合物溶液以蒸发溶剂,然后将 混合物在压力或减压下进入回收罐,以将聚合物与溶剂分离,聚合物可有效地从溶剂中分离而不改变聚合物的物理特性或化学特性。 当从具有高粘度的聚合物溶液中回收聚合物时,输入水或蒸汽用于降低聚合物溶液的粘度并增加气体的线速度,从而防止管道堵塞并促进操作 。