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1. 发明授权

US4283512A Copolymer having peroxy bonds in the molecule thereof and a process for producing the same 失效
标题翻译：在其分子中具有过氧键的共聚物及其制造方法
公开(公告)号：US4283512A
公开(公告)日：1981-08-11
申请号：US097627
申请日：1979-11-27
申请人： Masaru Matsushima , Takeshi Komai , Masaharu Nakayama
发明人： Masaru Matsushima , Takeshi Komai , Masaharu Nakayama
IPC分类号： C06B47/14 , C08F2/20 , C08F4/36 , C08F283/00 , C08F283/02
CPC分类号： C08F283/00 , C06B47/145 , C08F4/36
摘要： A copolymer having peroxy bonds in the molecule thereof which is obtained by copolymerizing an diacyl type polymeric peroxide having ester bonds therein with one or more monomers having double bonds therein, may have a broad range of average molecular weight and a lot of peroxy bonds therein, and it may be used as an useful polymerization initiator in producing a block copolymer.
摘要翻译：通过使其中具有酯键的二酰基型聚合过氧化物与一种或多种具有双键的单体共聚而得到的分子中具有过氧键的共聚物，其平均分子量和大量过氧键可以具有宽范围，并且可以在制备嵌段共聚物中用作有用的聚合引发剂。

2. 发明授权

US4315997A Styrene resin-block copolymer composition 失效
标题翻译：苯乙烯树脂嵌段共聚物组合物
公开(公告)号：US4315997A
公开(公告)日：1982-02-16
申请号：US165471
申请日：1980-07-02
申请人： Norihisa Ujikawa , Masaharu Nakayama , Masaru Matsushima
发明人： Norihisa Ujikawa , Masaharu Nakayama , Masaru Matsushima
IPC分类号： C08L25/00 , B29C57/10 , C08L23/00 , C08L25/04 , C08L51/00 , C08L51/02 , C08L53/00 , C08L77/00 , C08L101/00 , C08L25/14
CPC分类号： C08L25/04 , B29C57/10 , C08L53/00 , C10M2203/00 , C10M2207/028 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/30 , C10M2207/302 , C10M2207/304 , C10M2207/34 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10N2260/04 , C10N2270/02 , Y10S525/904
摘要： A styrene resin composition which is admixed with a styrene-vinyl acetate block copolymer is improved in the fluidity without degrading the mechanical strength and electric insulation resistance. Said vinyl acetate block polymer can easily be obtained by using a polymeric peroxide having ester bonds in the molecule thereof, notwithstanding that a copolymer of a styrene and a vinyl acetate could not be prepared easily by the prior art.
摘要翻译：与苯乙烯 - 乙酸乙烯酯嵌段共聚物混合的苯乙烯树脂组合物的流动性得到改善，而不降低机械强度和电绝缘性。所述乙酸乙烯酯嵌段聚合物可以通过使用其分子中具有酯键的聚合物过氧化物来容易地获得，尽管现有技术不能容易地制备苯乙烯和乙酸乙烯酯的共聚物。

3. 发明授权

US4303762A Low shrinking unsaturated polyester resin composition 失效
标题翻译：低收缩不饱和聚酯树脂组合物
公开(公告)号：US4303762A
公开(公告)日：1981-12-01
申请号：US210101
申请日：1980-11-24
申请人： Masaharu Nakayama , Masaru Matsushima , Shigeki Banno , Nobuo Kanazawa
发明人： Masaharu Nakayama , Masaru Matsushima , Shigeki Banno , Nobuo Kanazawa
IPC分类号： C08F4/00 , C08F4/28 , C08F4/36 , C08F283/01 , C08F293/00 , C08F295/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L53/00 , C08L67/00 , C08L67/06 , C08L77/00 , C08L101/00
CPC分类号： C08L67/06
摘要： A composition of matter which is prepared by blended with an unsaturated resin with a block copolymer which is obtained by employing a polymeric peroxide has dispersion stability during long storage found in no conventional one.A hardened moulding product obtained from the aforementioned composition matters is small in its volume shrinkage and exhibit smoothness and gloss to the surface thereof even it is employed after long period storage.
摘要翻译：通过与不饱和树脂共混制备的通过使用聚合过氧化物获得的嵌段共聚物制备的物质组合物在长期储存期间具有不存在常规的分散稳定性。由上述组合物获得的硬化成型品的体积收缩率小，即使长时间保存后使用也表现出平滑性和光泽。

4. 发明授权

US4659769A Process for preparing a non-aqueous liquid dispersion of polymer made with a polymeric peroxide 失效
标题翻译：制备由聚合物过氧化物制成的聚合物的非水性液体分散体的方法
公开(公告)号：US4659769A
公开(公告)日：1987-04-21
申请号：US465074
申请日：1983-02-09
申请人： Hiroshi Ohmura , Masaharu Nakayama
发明人： Hiroshi Ohmura , Masaharu Nakayama
IPC分类号： C08F2/08 , C08F2/14 , C08F4/36 , C08F4/38 , C08F293/00 , C08F299/00
CPC分类号： C08F4/36 , C08F293/00
摘要： A specialized polymeric peroxide is copolymerized with vinyl type monomers in the presence of organic liquid, thereby obtaining a solution of a copolymer having peroxy bonds therein.This solution is admixed with vinyl type monomers which are different in composition from the ones used in the first copolymerization, and the resultant mixture is subjected to block copolymerization.The obtained block copolymer solution is admixed with an organic liquid which exert solubility to one of polymers of the vinyl type monomers which are employed in the first or second copolymerization, whereby a non aqueous system liquid dispersion is obtained.This dispersion contains a block copolymer in a high concentration and it also is splendid in uniformity of dispersion and dispersion stability.
摘要翻译：在有机液体存在下，将特殊的聚合过氧化物与乙烯基类单体共聚，从而得到其中具有过氧键的共聚物的溶液。将该溶液与在第一共聚合中使用的组合物不同的乙烯基类单体混合，将所得混合物进行嵌段共聚。将获得的嵌段共聚物溶液与在第一次或第二次共聚中使用的乙烯基型单体的聚合物之一中溶解度的有机液体混合，从而得到非水系统液体分散体。该分散体含有高浓度的嵌段共聚物，并且还具有分散稳定性和分散稳定性的均匀性。

5. 发明授权

US4593067A Low shrinkable unsaturated polyester resin composition 失效
标题翻译：低收缩不饱和聚酯树脂组合物
公开(公告)号：US4593067A
公开(公告)日：1986-06-03
申请号：US686145
申请日：1984-12-26
申请人： Masaharu Nakayama , Kyosuke Fukushi , Yasuo Moriya , Nobuyoshi Suzuki
发明人： Masaharu Nakayama , Kyosuke Fukushi , Yasuo Moriya , Nobuyoshi Suzuki
IPC分类号： C08L53/00 , C08F283/01 , C08F287/00 , C08F293/00 , C08F295/00 , C08F299/04 , C08L23/00 , C08L51/00 , C08L51/02 , C08L67/00 , C08L67/06 , C08L77/00 , C08L101/00
CPC分类号： C08F299/04 , C08F287/00 , C08L67/06
摘要： Disclosed herein is a low shrinkable unsaturated polyester resin composition consisting of (A) 20-70% by weight of an unsaturated polyester, (B) 28-60% by weight of a monomer polymerizable with the above unsaturated polyester, and (C) 2-20% by weight of a block copolymer mixture. The mixtures of the monomer (B) and the block copolymer mixture (C), and a mixture of the polyester (A), the monomer (B), and the block copolymer mixture (C) are in a non-aqueous dispersion state. The block copolymer mixture is obtained by polymerizing either one of the monomers defined below in (a) and (b) with a polymerization initiator a polymeric perioxide represented by the formula: ##STR1## in which R.sub.1 represents a divalent branched hydrocarbon group having 10-30 carbons, and R.sub.2 and R.sub.3 represent a hydrogen atom, a hydroxyl group or an alkali metal, and the average polymerization degree n is 2-40, and is used to obtain a first polymer having peroxy bonds in its molecule, and block-polymerizing the first polymer with the remaining monomer (a) or (b) which has not been used in the first polymerization reaction wherein, (a) is a monomer or a monomer mixture consisting of 70-100% by weight of styrene monomer and 30-0% by weight of a monomer polymerizable therewith.(b) is a monomer or a mixture of monomers consisting of 70-100% by weight of C.sub.1-4 alkyl ester of acrylic acid or methacrylic acid and 0-30% by weight of a monomer polymerizable therewith.
摘要翻译：本发明公开了一种低收缩不饱和聚酯树脂组合物，其包含（A）20-70重量％的不饱和聚酯，（B）28-60重量％的可与上述不饱和聚酯聚合的单体和（C）2 -20重量％的嵌段共聚物混合物。单体（B）和嵌段共聚物混合物（C）的混合物以及聚酯（A），单体（B）和嵌段共聚物混合物（C）的混合物处于非水分散状态。嵌段共聚物混合物是通过将下列（a）和（b）中定义的单体之一与聚合引发剂一起聚合而得到的，所述聚合引发剂是下式表示的聚合二氧化物：其中R 1表示二价支链烃基具有10-30个碳，R2和R3表示氢原子，羟基或碱金属，平均聚合度n为2-40，用于获得分子中具有过氧键的第一聚合物，以及将第一聚合物与在第一聚合反应中未使用的剩余单体（a）或（b）嵌段聚合，其中（a）是由70-100重量％的苯乙烯单体组成的单体或单体混合物和30-0重量％的可与其聚合的单体。（b）是由70-100重量％的丙烯酸或甲基丙烯酸的C 1-4烷基酯和0-30重量％的与其可聚合的单体组成的单体或单体混合物。

6. 发明授权

US06586617B1 Sulfonamide derivatives 失效
标题翻译：磺酰胺衍生物
公开(公告)号：US06586617B1
公开(公告)日：2003-07-01
申请号：US09958953
申请日：2001-12-18
申请人： Takanori Tabuchi , Tetsuhiro Yamamoto , Masaharu Nakayama
发明人： Takanori Tabuchi , Tetsuhiro Yamamoto , Masaharu Nakayama
IPC分类号： C07C25550
CPC分类号： C07C327/58 , A01N41/06 , A01N43/10 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/653 , A01N43/80 , A01N43/82 , A01N43/90 , C07C311/13 , C07C311/21 , C07C311/29 , C07C311/44 , C07C311/46 , C07C311/48 , C07C311/49 , C07C311/51 , C07C317/36 , C07C317/48 , C07C323/49 , C07C323/63 , C07C327/48 , C07C2601/02 , A01N2300/00
摘要： The present invention relates to microbicides for agricultural or horticultural use containing a sulfonamide derivative.
摘要翻译：本发明涉及含有磺酰胺衍生物的用于农业或园艺用途的杀微生物剂。

7. 发明授权

US5118879A Fluoroalkyl derivative and process for preparing the same 失效
标题翻译：氟代醇衍生物及其制备方法
公开(公告)号：US5118879A
公开(公告)日：1992-06-02
申请号：US601736
申请日：1990-10-25
申请人： Nobumasa Kamigata , Masato Yoshida , Hideo Sawada , Masaharu Nakayama
发明人： Nobumasa Kamigata , Masato Yoshida , Hideo Sawada , Masaharu Nakayama
IPC分类号： C07C19/10 , C07C21/18 , C07C22/08 , C07C25/13 , C07C25/24 , C07C43/225 , C07C205/11
CPC分类号： C07C25/24 , C07C19/10 , C07C205/11 , C07C21/18 , C07C22/08 , C07C25/13 , C07C43/225
摘要： Fluoroalkyl derivatives which are novel compounds represented by the following general formula (I) or (II) of: ##STR1## orR.sub.1 --CH.dbd.CR.sub.2 (CF.sub.2).sub.n F (II)(wherein R.sub.1 stands for ##STR2## (where X stands for a hydrogen atom, a chlorine atom, a bromine atom, a fluorine atom, an iodine atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group or a nitro group), an aroyloxy group, or an alkyl or alkoxycarbonyl group having 1 to 20 carbon atoms, and R.sub.2 stands for a hydrogen atom or a methyl group; and n stands for an integer of from 1 to 20.) A process for the preparation of the derivative is a process comprising reacting an olefin compound and a fluoroalkanesulfonyl chloride in the presence of a metal catalyst, or a process comprising an additional alkali treatment step which follows the aforementioned process.
摘要翻译： PCT No.PCT / JP90 / 00242 Sec。 371 1990年10月25日第 102（e）1990年10月25日日期PCT提交1990年2月27日PCT公布。出版物WO90 / 09972 1990年9月7日，由以下通式（I）或（II）表示的新化合物：（I）或R1-CH = CR2（CF2）nF（Ⅱ）（其中R1 代表（其中X代表氢原子，氯原子，溴原子，氟原子，碘原子，甲基，乙基，甲氧基，乙氧基或硝基）芳氧基，碳原子数1〜20的烷基或烷氧基羰基，R2表示氢原子或甲基，n表示1〜20的整数）。衍生物是一种方法，包括在金属催化剂存在下使烯烃化合物和氟烷基磺酰氯反应，或包括依照上述方法的另外的碱处理步骤的方法。

8. 发明授权

US4366290A Unsaturated polyester resin composition 失效
标题翻译：不饱和聚酯树脂组合物
公开(公告)号：US4366290A
公开(公告)日：1982-12-28
申请号：US282884
申请日：1981-07-13
申请人： Norihisa Ujikawa , Masaharu Nakayama
发明人： Norihisa Ujikawa , Masaharu Nakayama
IPC分类号： C08L67/00 , C08F4/36 , C08F18/24 , C08F289/00 , C08F299/04 , C08L1/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/06 , C08L101/00
CPC分类号： C08F299/045 , C08F18/24 , C08F289/00 , C08F4/36 , C08L67/06
摘要： An unsaturated polyester resin composition which is obtained by incorporating a thermoplastic random-copolymer having peroxycarbonate groups in the molecule thereof into an unsaturated polyester resin, which composition is excellent in low shrinkage characteristics and it is not weakened in mechanical strength.
摘要翻译：通过在其分子中含有具有过氧碳酸酯基的热塑性无规共聚物而成为不饱和聚酯树脂而得到的不饱和聚酯树脂组合物，该组合物的低收缩特性优异，机械强度不降低。

9. 发明授权

US3954880A Method for producing high-purity dicumyl peroxide 失效
标题翻译：生产高纯度二异辛基过氧化物的方法
公开(公告)号：US3954880A
公开(公告)日：1976-05-04
申请号：US586640
申请日：1975-06-13
申请人： Masaharu Nakayama , Isao Hayashi , Makoto Muraguchi
发明人： Masaharu Nakayama , Isao Hayashi , Makoto Muraguchi
IPC分类号： C07C407/00 , C07C179/04
CPC分类号： C07C407/003
摘要： High-purity dicumyl peroxide is obtained by mixing a melted crude dicumyl peroxide containing not less than 50% of dicumyl peroxide with an aqueous solution of surfactant, emulsifying the resulting mixture, and cooling the emulsion to a temperature lower than the temperature for solidifying dicumyl peroxide.
摘要翻译：通过将含有不少于50％过氧化二异丙苯的熔融粗制二异丙基过氧化物与表面活性剂水溶液混合，乳化所得混合物，并将乳液冷却至低于固化二异丙苯过氧化物的温度的温度，得到高纯度二异辛基过氧化物。

10. 发明授权

US07803822B2 Triazole derivative and use thereof 失效
标题翻译：三唑衍生物及其用途
公开(公告)号：US07803822B2
公开(公告)日：2010-09-28
申请号：US11887936
申请日：2006-04-06
申请人： Keiji Kubo , Mamoru Tobisu , Eiji Honda , Takahiko Taniguchi , Yoshiyuki Fukase , Masaki Kawamura , Masaharu Nakayama
发明人： Keiji Kubo , Mamoru Tobisu , Eiji Honda , Takahiko Taniguchi , Yoshiyuki Fukase , Masaki Kawamura , Masaharu Nakayama
IPC分类号： A61K31/41 , C07D249/00
CPC分类号： C07D249/06 , C07D401/04 , C07D401/10 , C07D401/12 , C07D403/06 , C07D403/12 , C07D405/12 , C07D409/04 , C07D409/12 , C07D411/12 , C07D413/06 , C07D413/12 , C07D417/06 , C07D417/12 , C07D471/04 , C07D487/04
摘要： The present invention relates to a thrombin receptor antagonist containing a compound represented by the formula (I) wherein R1a, R1b and R2 are each a hydrogen atom, an optionally substituted hydrocarbon group, an optionally substituted heterocyclic group, or an optionally substituted alkoxy, R3 is a group represented by the formula —NHCOR4, —NHSO2R5, —NHCON(R6a)(R6b), —NHCOOR7 or —CONHR8 wherein R4, R5, R6a, R6b, R7 and R8 are each a hydrogen atom, an optionally substituted hydrocarbon group, an optionally substituted heterocyclic group and the like), ring A is monocyclic aromatic ring optionally further having substituent(s), R1a and R1b are optionally bonded to each other to form an optionally substituted nitrogen-containing non-aromatic heterocycle, or a salt thereof or a prodrug thereof. The thrombin receptor antagonist of the present invention has a thrombin receptor (particularly PAR-1) antagonistic action and is useful for the prophylaxis or treatment of PAR-1 mediated pathological condition or disease.
摘要翻译：本发明涉及含有式（I）表示的化合物的凝血酶受体拮抗剂，其中R1a，R1b和R2各自为氢原子，任选取代的烃基，任选取代的杂环基或任选取代的烷氧基，R 3 是由式-NHCOR4，-NHSO2R5，-NHCON（R6a）（R6b），-NHCOOR7或-CONHR8表示的基团，其中R4，R5，R6a，R6b，R7和R8各自为氢原子，任选取代的烃基，任选取代的杂环基等），环A是任选进一步具有取代基的单环芳环，R 1a和R 1b任选地彼此键合以形成任选取代的含氮非芳族杂环或盐或其前药。本发明的凝血酶受体拮抗剂具有凝血酶受体（特别是PAR-1）拮抗作用，可用于预防或治疗PAR-1介导的病理状态或疾病。

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