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    • 6. 发明授权
    • Dielectric ceramic composition
    • 介电陶瓷组合物
    • US4985381A
    • 1991-01-15
    • US483052
    • 1990-02-21
    • Yoshiaki MoriMasaru FujinoHiroshi TakagiYukio Sakabe
    • Yoshiaki MoriMasaru FujinoHiroshi TakagiYukio Sakabe
    • C04B35/00C04B35/49C04B35/493H01B3/12H01G4/12
    • C04B35/493H01G4/1245H01G4/1263
    • A dielectric ceramic composition consists essentially of a basic composition of a ternary system, Pb(Mg.sub.1/2 W.sub.1/2)O.sub.3 -PbTiO.sub.3 -PbZrO.sub.3, and 0.05 to 6.5 wt % of an antireducing agent incorporated therein. The basic composition comprises a main component represented by the general formula: xPb(Mg.sub.1/2 ; W.sub.1/2)O.sub.3 -yPbTiO.sub.3 -zPbZrO.sub.3 wherein x, y and z are mole percentages of the respective components, and 0.3 to 2.0 wt % of ZnO contained therein. The main component has a composition falling within the area of a polygen ABCD defined by points A(52.0, 44.0, 4.0), B(47.0, 38.3, 15.0), C(44.0, 40.0, 16.0), D(49.0, 46.0, 5.0) in the attached figure. The antireducing agent has a composition expressed by the general formula:.alpha.Li.sub.2 O+.beta.RO+.gamma.B.sub.2 O.sub.3 +(1-.alpha.-.beta.-.gamma.)SiO.sub.2wherein RO is at least one oxide selected from the group consisting of BaO, CaO, SrO and MgO, .alpha., .beta. and .gamma. are mole fracions of the respective components and take each value within the following respective ranges, 0
    • 电介质陶瓷组合物基本上由三元体系的基本组成Pb(Mg1 / 2W1 / 2)O3-PbTiO3-PbZrO3和0.05至6.5wt%的引入其中的抗氧化剂组成。 基本组成包括由以下通式表示的主要成分:xPb(Mg1 / 2; W1 / 2)O3-yPbTiO3-zPbZrO3其中x,y和z为各成分的摩尔百分数,0.3〜2.0重量%的ZnO 其中包含。 主要组分的组成落在由A点(52.0,44.0,4.0),B(47.0,38.3,15.0),C(44.0,40.0,16.0),D(49.0,46.0, 5.0)在附图中。 抗氧化剂具有由以下通式表示的组成:αLi 2 O +βRO +γB 2 O 3 +(1-α-β-γ)SiO 2,其中RO是选自BaO,CaO,SrO和MgO中的至少一种氧化物,α β和γ是相应组分的摩尔分数,并取每个值在以下相应的范围内,0 <α<0.2,0.1≤β≤0.55,0<γ<0.4。 主成分可以含有以MnO 2计为2.0重量%以下的氧化锰。
    • 8. 发明授权
    • Nonreducible dielectric ceramic composition
    • 不可还原电介质陶瓷组合物
    • US4859641A
    • 1989-08-22
    • US169393
    • 1988-03-09
    • Masaru FujinoGoro NishiokaYukio Sakabe
    • Masaru FujinoGoro NishiokaYukio Sakabe
    • C04B35/49H01G4/12
    • H01G4/1227C04B35/49
    • A nonreducible dielectric ceramic composition consists essentially of a main component expressed by the formula:(Sr.sub.1-x Ca.sub.x).sub.m (Ti.sub.1-y Zr.sub.y)O.sub.3wherein x an dy are molar fractions of the respective elements, and m is molar ratio of (Sr.sub.1-x Ca.sub.x) to (Ti.sub.1 -yZr.sub.y), and wherein x, y and m take values within the following respective ranges: 0.30.ltoreq.x.ltoreq.0.50, 0.03.ltoreq.y.ltoreq.0.20, 0.95.ltoreq.m.ltoreq.1.08, and secondary components composed of at least manganese oxides and SiO.sub.2. The content of each secondary component per 100 parts by weight of the main component is 0.01 to 2.00 parts by weight for manganese oxides in terms of MnO.sub.2, and 0.10 to 4.00 parts by weight for SiO.sub.2. The composition may contain, as one of the secondary components, 0.01 to 1.00 parts by weight of MgO or ZnO per 100 parts by weight of the main component. The composition is useful as material for multilayer ceramic capacitors.
    • 不可还原电介质陶瓷组合物基本上由以下式表示的主要组分组成:(Sr1-xCax)m(Ti1-yZry)O3,其中x an dy是各元素的摩尔分数,m是(Sr1-xCax) )至(Ti1-yZry),并且其中x,y和m取值在以下各自的范围内:0.30
    • 9. 发明授权
    • Dielectric ceramic composition
    • 介电陶瓷组合物
    • US4753905A
    • 1988-06-28
    • US891470
    • 1986-07-29
    • Goro NishiokaYukio SakabeJunichi ImanariMasaru Fujino
    • Goro NishiokaYukio SakabeJunichi ImanariMasaru Fujino
    • C04B35/499H01G4/12C04B35/46
    • C04B35/499H01G4/1263
    • A dielectric ceramic composition consists essentially of a main component composed of a solid solution of a three component system Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3 -Pb(Zn.sub.1/3 Nb.sub.2/3)O.sub.3 -PbTiO.sub.3, characterized in that said main component consists essentially of 68.05 to 69.60 wt % of Pb.sub.3 O.sub.4, 2.41 to 4.00 wt % of MgO, 0.08 to 3.15 wt % of ZnO, 24.01 to 26.66 wt % of Nb.sub.2 O.sub.5, and 0.13 to 2.59 wt % of TiO.sub.2, and has a set of compositional proportions of the three components falling within an area defined by a polygon ABCD encompassed by points A, B, C, and D in FIG. 1, and that a subsidiary component consisting essentially of MgO is incorporated into said main component in an amount of not more than 1.0 part by weight (except 0 part by weight) with respect to 100 part by weight of the main component. The composition may further contain, as a part of the subsidiary component, manganese and/or a compound represented by the general formula: A(Cu.sub.1/2 W.sub.1/2)O.sub.3 (wherein A is one or more elements selected from the group consisting of Pb, Ba, Sr, and Ca).
    • 电介质陶瓷组合物主要由由三组分Pb(Mg1 / 3Nb2 / 3)O3-Pb(Zn1 / 3Nb2 / 3)O3-PbTiO3的固溶体组成的主要组分组成,其特征在于所述主要组分基本上由 的Pb 3 O 4为68.05〜69.60重量%,MgO为2.41〜4.00重量%,ZnO为0.08〜3.15重量%,Nb 2 O 5为24.01〜26.66重量%,TiO 2为0.13〜2.59重量%,成分比例为 落在由图1中的点A,B,C和D包围的多边形ABCD限定的区域内的三个分量。 1,并且基本上由MgO组成的辅助组分相对于主要组分的100重量份以不超过1.0重量份(除了0重量份)的量掺入所述主要组分中。 该组合物还可以含有作为辅助成分的一部分的锰和/或由以下通式表示的化合物:A(Cu1 / 2W1 / 2)O3(其中A是一种或多种选自Pb ,Ba,Sr和Ca)。