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    • 4. 发明授权
    • Polymerization regulators and compositions for resin
    • 聚合调节剂和树脂组合物
    • US07169845B2
    • 2007-01-30
    • US10297383
    • 2002-04-04
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • C08L81/00C08K3/16
    • C08G75/08C07D331/02
    • In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1–C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1–C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13–16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1–C10 hydocarbyl or hydrogen, R4 is C1–C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1–C10 alkoxyl, C1–C10 alkylthio, or C1–C10 mercaptoalkythio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
    • 在本发明中,在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物:其中R 5是C 1 -C 10亚烃基或单键,R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢,Y为O,S,Se或Te,p为1的整数 至5和q为0至5的整数,在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合:其中R“ 1,R 2和R 3各自为C 1 -C 10氢碳基或氢,R 4为C 1 -C 10亚烃基或单 键,X为F,Cl,Br,I,As,SH,OH,C 1 -C 10烷氧基,C 1 -C 10烷硫基或C 1 -C 10巯基偶氮,m为1〜5的整数, 作为光学材料。 通过使用聚合调节剂,可以适当调节环硫化合物的聚合速度,得到缺陷少的固化树脂。 通过使用卤化物,可以防止在储存或铸造操作期间起始组合物的粘度的增加。
    • 8. 发明授权
    • Polymerization regulator and composition for resin
    • 聚合调节剂和树脂组合物
    • US07446163B2
    • 2008-11-04
    • US11189859
    • 2005-07-27
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • C08G75/08
    • C08G75/08C07D331/02
    • In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
    • 在本发明中,在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物:其中R 5是C 1 -C 10亚烃基或单键,R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢,Y为O,S,Se或Te,p为1的整数 至5和q为0至5的整数,在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合:其中R“ R 1,R 2和R 3各自为C 1 -C 10烃基或氢,R 4为C 1 -C 10亚烃基或单 键,X为F,Cl,Br,I,As,SH,OH,C1-C10烷氧基,C1-C10烷硫基或C1-C10巯基烷硫基,m为1〜5的整数, 作为光学材料。 通过使用聚合调节剂,可以适当调节环硫化合物的聚合速度,得到缺陷少的固化树脂。 通过使用卤化物,可以防止在储存或铸造操作期间起始组合物的粘度的增加。
    • 9. 发明申请
    • Polymerization regulator and composition for resin
    • 聚合调节剂和树脂组合物
    • US20050261467A1
    • 2005-11-24
    • US11189859
    • 2005-07-27
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • Masaki TamuraTakahiro MatsuiMasanori ShimutaYuichi YoshimuraMotoharu TakeuchiHiroshi HorikoshiHiroyuki Okada
    • C07D331/02C08G75/08C08G75/00
    • C08G75/08C07D331/02
    • In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
    • 在本发明中,在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物:其中R 5是C 1 -C 10亚烃基或单键,R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢,Y为O,S,Se或Te,p为1的整数 至5和q为0至5的整数,在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合:其中R“ R 1,R 2和R 3各自为C 1 -C 10烃基或氢,R 4为C 1 -C 10亚烃基或单 键,X为F,Cl,Br,I,As,SH,OH,C1-C10烷氧基,C1-C10烷硫基或C1-C10巯基烷硫基,m为1〜5的整数, 作为光学材料。 通过使用聚合调节剂,可以适当调节环硫化合物的聚合速度,得到缺陷少的固化树脂。 通过使用卤化物,可以防止在储存或铸造操作期间起始组合物的粘度的增加。