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1. 发明授权

US06291717B1 Process for producing aldehyde 失效
标题翻译：生产醛的方法
公开(公告)号：US06291717B1
公开(公告)日：2001-09-18
申请号：US09457742
申请日：1999-12-10
申请人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
发明人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
IPC分类号： C07C4550
CPC分类号： C07F9/025 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.
摘要翻译：一种生产醛的方法，其包括在反应区中在至少包含铑和有机亚磷酸酯的铑络合物催化剂的存在下使烯属化合物与一氧化碳和氢气反应制备醛的反应步骤，分离步骤通过从取自反应区的反应溶液中分离醛获得含有铑络合物催化剂的催化剂溶液，以及将催化剂溶液再循环到反应区中的再循环步骤，其中醛与反应溶液分离以使催化剂溶液中醛浓度为0.5〜99重量％。

2. 发明授权

US06583324B2 Process for producing aldehyde 有权
公开(公告)号：US06583324B2
公开(公告)日：2003-06-24
申请号：US09954171
申请日：2001-09-18
申请人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
发明人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
IPC分类号： C07C4550
CPC分类号： C07F9/025 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.

3. 发明授权

US06610891B1 Method of producing aldehydes 有权
标题翻译：生产醛的方法
公开(公告)号：US06610891B1
公开(公告)日：2003-08-26
申请号：US09454817
申请日：1999-12-03
申请人： Lionel O'Young , Masaki Takai , Tooru Tsukahara , Akio Nakanishi
发明人： Lionel O'Young , Masaki Takai , Tooru Tsukahara , Akio Nakanishi
IPC分类号： C07C4549
CPC分类号： C07C45/50 , B01J31/185 , B01J2231/321 , B01J2531/80 , B01J2531/822 , Y02P20/582 , C07C47/02
摘要： A method of producing aldehydes in a hydroformylation system wherein an olefinic compound is reacted with hydrogen and carbon monoxide in a hydroformylation reaction in the presence of a catalyst is provided. The hydroformylation system includes a reactor and a downstream catalyst process path. The temperature in the reactor and downstream catalyst process path is less than approximately 100° C., and preferably less than approximately 85° C., and most preferably less than approximately 80° C., such that formation of high boiler components from the reaction are substantially minimized. Further, the method of the present invention reduces degradation or decomposition of the catalyst, and in particular the ligand compound.
摘要翻译：提供了一种在加氢甲酰化体系中生产醛的方法，其中烯烃化合物在氢化甲酰化反应中在催化剂存在下与氢气和一氧化碳反应。加氢甲酰化体系包括反应器和下游催化剂工艺路径。反应器和下游催化剂工艺路径中的温度小于约100℃，优选小于约85℃，最优选小于约80℃，从而形成来自反应的高沸点组分基本上最小化。此外，本发明的方法减少了催化剂，特别是配体化合物的降解或分解。

4. 发明申请

US20060106181A1 Method for producing allyl compound, and ether or ester compound produced thereby 有权
公开(公告)号：US20060106181A1
公开(公告)日：2006-05-18
申请号：US11300290
申请日：2005-12-15
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C08F20/10 , C07C69/52
CPC分类号： C07C41/16 , C07C67/10 , Y02P20/582 , C07C69/78 , C07C43/215 , C07C43/15 , C07C43/1785 , C07C43/23
摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

5. 发明授权

US07423168B2 Method for producing allyl compound 失效
标题翻译：烯丙基化合物的制造方法
公开(公告)号：US07423168B2
公开(公告)日：2008-09-09
申请号：US10649767
申请日：2003-08-28
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C07C69/76 , C07C41/06
CPC分类号： C07C41/16 , C07C41/06 , C07C67/10 , C07C69/78 , C07C43/15 , C07C43/215
摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent having a structure different from that of the allyl starting material compound in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a monodentate phosphite compound having a structure of the following formula (1): P(OR1)(OR2)(OR3) (1) wherein R1, R2 and R3 are respectively independently an alkyl group which may have a substituent, carbon chains of R1, R2 and R3 may have at least one carbon-carbon double bond or triple bond, and at least two optional groups of R1, R2 and R3 may bond to each other to form at least one cyclic structure.
摘要翻译：一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括使烯丙基原料化合物与具有与烯丙基原料化合物不同的结构的氧亲核剂在存在含有至少一种含有选自属于周期表第8族至第10族的过渡金属的过渡金属的过渡金属化合物和具有下式（1）的结构的单齿亚磷酸酯化合物的催化剂：在线公式描述=“在线公式”end =“lead”？> P（OR ^{2 ）（OR ^{2 < / SUP>）（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1，R 2，和 R 3分别独立地是可以具有取代基的烷基，R 1，R 2和R 3的碳链， / SUP>可能在l 东一个碳 - 碳双键或三键，并且R 1，R 2和R 3的至少两个任选基团可以键合到彼此形成至少一个循环结构。}}

6. 发明授权

US07173157B2 Method for producing an allyl compound 有权
标题翻译：烯丙基化合物的制造方法
公开(公告)号：US07173157B2
公开(公告)日：2007-02-06
申请号：US10650697
申请日：2003-08-29
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C07C41/06 , C07C69/76
CPC分类号： C08G63/52 , C07C41/16 , C07C67/10 , C07C209/66 , C07C2601/14 , C08G63/87 , C07C69/78 , C07C211/35 , C07C43/215 , C07C43/15
摘要： An allyl compound having a formula different from that of an allyl starting compound is prepared by a process of reacting the allyl starting compound with a nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of elements belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6Π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an optionally substituted alkylene group, an optionally substituted arylene group, an optionally substituted alkylene-arylene group or an optionally substituted diarylene group.
摘要翻译：通过使烯丙基起始化合物与亲核剂在含有至少一种含有过渡金属的过渡金属的催化剂存在下反应的方法来制备具有与烯丙基起始化合物不同的烯丙基化合物，由属于元素周期表第8至10族的元素和至少一种选自具有下式（I）至（III）的化合物的二齿配位的亚磷酸酯化合物组成：其中A 1〜分别独立地为在邻位具有支链烷基的二亚芳基，R 1至R 6分别独立地为可以具有取代基的烷基或可具有取代基的芳基（包括在环的上侧和下侧形成芳香族6Pi电子云的杂环化合物，以下相同），Z 1 到Z 3 分别独立地为任选取代的亚烷基，任选取代的亚芳基，任选取代的亚烷基 - 亚芳基或任选取代的亚芳基。

7. 发明授权

US07241857B2 Method for producing allyl compound, and ether or ester compound produced thereby 有权
标题翻译：制备烯丙基化合物的方法和由此制备的醚或酯化合物
公开(公告)号：US07241857B2
公开(公告)日：2007-07-10
申请号：US11300290
申请日：2005-12-15
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C08G65/34 , C08F20/10
CPC分类号： C07C41/16 , C07C67/10 , Y02P20/582 , C07C69/78 , C07C43/215 , C07C43/15 , C07C43/1785 , C07C43/23
摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.
摘要翻译：一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

8. 发明授权

US07119222B2 Method for producing allyl compound, and ether or ester compound produced thereby 有权
标题翻译：制备烯丙基化合物的方法和由此制备的醚或酯化合物
公开(公告)号：US07119222B2
公开(公告)日：2006-10-10
申请号：US10648210
申请日：2003-08-27
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C07C69/533 , C07C41/06
CPC分类号： C07C41/16 , C07C67/10 , Y02P20/582 , C07C69/78 , C07C43/215 , C07C43/15 , C07C43/1785 , C07C43/23
摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.
摘要翻译：一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

9. 发明申请

US20050075518A1 Method for producing allyl compound, and allyl compound produced thereby 有权
标题翻译：制备烯丙基化合物的方法和由此制备的烯丙基化合物
公开(公告)号：US20050075518A1
公开(公告)日：2005-04-07
申请号：US10650697
申请日：2003-08-29
申请人： Masaki Takai , Yoshiyuki Tanaka
发明人： Masaki Takai , Yoshiyuki Tanaka
IPC分类号： C07C41/16 , C07C67/10 , C07C209/66 , C07C211/35 , C08G63/52 , C08G63/87 , C07C41/06
CPC分类号： C08G63/52 , C07C41/16 , C07C67/10 , C07C209/66 , C07C2601/14 , C08G63/87 , C07C69/78 , C07C211/35 , C07C43/215 , C07C43/15
摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.
摘要翻译：一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属的过渡金属化合物的催化剂存在下使烯丙基原料化合物与亲核剂反应选自属于元素周期表第8族至第10族的过渡金属和至少一种选自下式（I）至（III）的结构的化合物的二齿配位的亚磷酸酯化合物：其中A A 1〜A 3分别独立地为在邻位具有支链烷基的二亚芳基，R 1〜R 6分别独立地为可以具有取代基的烷基或芳基，可以具有取代基（包括在环的上侧和下侧形成芳香族6pi电子云的杂环化合物，以下相同）和Z 1〜Z 3分别独立地为可以具有取代基的亚烷基，可以具有取代基的亚芳基，可以具有取代基的亚芳基 - 亚芳基或可具有取代基的二亚芳基取代基。

10. 发明授权

US5936130A Process for preparing a rhodium complex solution and process for producing an aldehyde 失效
标题翻译：制备铑配合物溶液的方法和制备醛的方法
公开(公告)号：US5936130A
公开(公告)日：1999-08-10
申请号：US926481
申请日：1997-09-10
申请人： Tomoyuki Mori , Masaki Takai , Tomohiko Inoue , Kazuyuki Yokoyama
发明人： Tomoyuki Mori , Masaki Takai , Tomohiko Inoue , Kazuyuki Yokoyama
IPC分类号： C01G55/00 , B01J31/24 , B01J31/40 , C07C45/50 , C07C47/055
CPC分类号： B01J31/1845 , B01J31/2404 , B01J31/4046 , B01J31/4053 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/0235 , B01J31/04 , B01J31/26 , Y02P20/584
摘要： A process for producing a rhodium complex solution, which comprises contacting an aqueous solution of a water-soluble rhodium compound and an organic solvent solution of a water-insoluble tertiary organic phosphorus compound, preferably in the presence of a C.sub.2-8 carboxylic acid, in a gas atmosphere containing carbon monoxide, followed by two phase separation, and recovering an organic solvent phase containing a rhodium-tertiary organic phosphorus compound complex. As the above aqueous solution of a rhodium compound, an aqueous solution having rhodium extracted into an aqueous phase from a waste catalyst liquid separated from a hydroformylation reaction step by oxidation treatment in the presence of a recovery accelerator such as a carboxylic acid, an amine, ammonia or an inorganic acid, is used, whereby recycling of rhodium represented by hydroformylation reaction/recovery of the catalyst/regeneration of the catalyst, is made possible, and a cumbersome step of preparing a complex catalyst from an inorganic salt or the like, or a step of preparing a soluble salt from a metal or oxide by combustion in water of the recovered catalyst, can be omitted.
摘要翻译：一种制备铑络合物溶液的方法，其包括使水溶性铑化合物的水溶液与水不溶性叔有机磷化合物的有机溶剂溶液，优选在C2-8羧酸存在下，在含有一氧化碳的气体气氛，然后进行两相分离，并回收含有铑 - 叔有机磷化合物络合物的有机溶剂相。作为上述铑化合物的水溶液，通过在回收促进剂如羧酸，胺等存在下，通过氧化处理，从加氢甲酰化反应步骤中分离出的废催化剂液体将含有铑的水溶液萃取到水相中，氨或无机酸，从而可以通过加氢甲酰化反应/催化剂的回收/催化剂的再生来代替的铑的回收成为可能，并且从无机盐等制备复合催化剂的繁琐步骤，或可以省略通过在回收的催化剂的水中燃烧而从金属或氧化物制备可溶性盐的步骤。

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