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    • 3. 发明授权
    • Color photographs and method for preparation of the same
    • 彩色照片及其制备方法
    • US5194348A
    • 1993-03-16
    • US462930
    • 1990-01-12
    • Masakazu MorigakiNobuo SetoOsamu TakahashiHideaki Naruse
    • Masakazu MorigakiNobuo SetoOsamu TakahashiHideaki Naruse
    • G03C7/392
    • G03C7/39296G03C7/39208G03C7/39236G03C7/3924G03C7/39248G03C7/39252G03C7/39256G03C7/39268G03C7/39272
    • Disclosed in a color photograph containing a storability-improving compound capable of forming a chemical bond with an aromatic amine series color developing agent that remains in a photographic material after having been processed for color development to give a chemically inactive and substantially colorless compound in at least one photographic layer on a support. Also disclosed is a method for preparation of color photographs wherein a photographic material containing a silver halide emulsion layer and a color image-forming coupler capable of forming a dye by an oxidation-coupling reaction with an aromatic amine series color developing agent, as coated on a support, is imagewise exposed to light and then subjected to photographic processing, comprising carrying out the photographic processing in the presence of the afore described storability-improving compound. By the use of the storability-improving compound, the color images formed on the color photographs do not fade when stored for long periods of time.
    • 公开在含有能够与芳族胺系彩色显影剂形成化学键的储存性提高化合物的彩色照片中,所述芳香族胺系彩色显影剂在经过显色处理后保留在照相材料中,以至少至少产生化学惰性和基本上无色的化合物 支持上的一个照相层。 还公开了一种制备彩色照片的方法,其中含有卤化银乳剂层的照相材料和能够通过与芳族胺系彩色显影剂的氧化偶合反应形成染料的彩色成像剂,涂覆在 支撑体,成像曝光,然后进行照相处理,包括在上述保存性改善化合物的存在下进行照相处理。 通过使用保存性提高化合物,在长时间存储时,彩色照片上形成的彩色图像不会褪色。
    • 4. 发明授权
    • Color diffusion transfer photosensitive material
    • 彩色扩散转印感光材料
    • US5419996A
    • 1995-05-30
    • US214231
    • 1994-03-17
    • Hideaki NaruseNobuo SetoMasakazu MorigakiMasayuki Negoro
    • Hideaki NaruseNobuo SetoMasakazu MorigakiMasayuki Negoro
    • G03C8/08G03C8/24G03C8/42G03C8/10G03C8/56
    • G03C8/08G03C8/246Y10S430/142
    • Disclosed is a color diffusion transfer photosensitive material containing a compound represented by a color diffusion transfer photosensitive material containing at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom, an aliphatic group or an aryl group; and R.sub.3 represents an aliphatic group or a group represented by the following general formula (Ab): ##STR2## wherein R.sub.4 represents a hydrogen atom, an aliphatic group or an aryl group and R.sub.5 represents an aliphatic group, an aryl group or an amino group; and further, R.sub.1 and R.sub.2, R.sub.1 and R.sub.3, R.sub.2 and R.sub.3, or R.sub.4 and R.sub.5 may combine with each other to form a 5- to 7-membered ring, or R.sub.1, R.sub.2 and R.sub.3 may combine with one another to form a bicyclo ring; wherein the total number of carbon atoms contained in R.sub.1, R.sub.2 and R.sub.3 is not smaller than 10, at least either R.sub.1 or R.sub.2 is an aliphatic group, and R.sub.3 is a group represented by general formula (Ab) when one of the groups R.sub.1 and R.sub.2 is an aliphatic group and the other is an aryl group.
    • 本发明公开了含有由以下通式(I)表示的至少一种化合物的颜色扩散转印感光材料表示的化合物的颜色扩散转印感光材料:其中R1和R2各自表示氢原子, 脂族基团或芳基; R 3表示脂肪族基团或下述通式(Ab)表示的基团:其中,R 4表示氢原子,脂肪族基团或芳基,R 5表示脂肪族基团,芳基或 氨基; 此外,R 1和R 2,R 1和R 3,R 2和R 3或R 4和R 5可以彼此结合形成5-至7-元环,或者R 1,R 2和R 3可以彼此结合形成双环 环; 其中R1,R2和R3中含有的碳原子总数不小于10,R 1或R 2中的至少一个为脂族基,R 3为通式(Ab)表示的基团, R2是脂族基团,另一个是芳基。
    • 7. 发明授权
    • Silver halide color photographic materials containing an antisain agent
and a magenta coupler in lipophilic fine particles
    • 在亲脂性细颗粒中含有防锈剂和品红色成色剂的卤化银彩色照相材料
    • US4770987A
    • 1988-09-13
    • US943035
    • 1986-12-17
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiTadahisa Sato
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiTadahisa Sato
    • G03C7/26G03C7/32G03C7/38G03C7/388G03C7/392G03C1/06
    • G03C7/39236
    • A silver halide color photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer having dispersed therein lipophilic fine particles containing an image dye forming lipophilic coupler, wherein the lipophilic fine particles further contain at least one lipophilic compound having a water-solubility of not more than 1% by weight at 25.degree. C. and represented by formula (I):R.sub.0 SO.sub.2 X (I)wherein R.sub.0 represents a substituted or unsubstituted alkyl, aryl or heterocyclic group having 8 or more total carbon atoms; and X represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, a nitrogen-containing organic base, ammonium or a group represented by formula (A): ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl or heterocyclic group; R.sub.2 represents a hydrogen atom, a halogen atom or a substituted or unsubstituted alkyl, aryl, acyloxy or sulfonyl group; and R.sub.3 represents a hydrogen atom or a hydrolyzable group.The material prevents stain formation on the non-color-developed areas due to aging and the like after processing.
    • 公开了一种卤化银彩色照相材料,其包括其上提供有至少一个卤化银乳剂层的载体,所述卤化银乳剂层分散有含有形成亲脂性成色剂的图像染料的亲脂性微粒,其中亲脂性微粒还含有至少一种亲脂性化合物, 在25℃下水溶性不超过1重量%,由式(I)表示:R 0 SO 2 X(I)其中R 0表示具有8个或更多总碳原子的取代或未取代的烷基,芳基或杂环基; X表示氢原子,碱金属原子,碱土金属原子,含氮有机碱,铵或式(A)表示的基团:其中R 1表示氢原子或 取代或未取代的烷基,芳基或杂环基; R 2表示氢原子,卤素原子或取代或未取代的烷基,芳基,酰氧基或磺酰基; 并且R 3表示氢原子或可水解基团。 该材料防止由于加工后的老化等而在非显色区域上形成污斑。
    • 8. 发明授权
    • Silver halide color photographic materials
    • US4983507A
    • 1991-01-08
    • US262603
    • 1988-10-26
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • G03C7/26G03C7/38G03C7/392
    • G03C7/3805G03C7/39252
    • The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta coupler(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (II) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.
    • 10. 发明授权
    • Silver halide color photographic materials
    • 卤化银彩色照相材料
    • US5041365A
    • 1991-08-20
    • US555676
    • 1990-07-19
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • G03C7/26G03C7/38G03C7/392
    • G03C7/3805G03C7/39252
    • The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta couplers(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (III) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.