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1. 发明授权

US06316677B1 Production process of bisphenol compounds 失效
标题翻译：双酚化合物的生产工艺
公开(公告)号：US06316677B1
公开(公告)日：2001-11-13
申请号：US09270016
申请日：1999-03-16
申请人： Masahiro Enna , Naoshi Nagai , Toshiyuki Isaka
发明人： Masahiro Enna , Naoshi Nagai , Toshiyuki Isaka
IPC分类号： C07C3912
CPC分类号： C07C37/84 , C07C37/14 , C07C37/16 , C07C39/16 , C07C39/15
摘要： A process for the production of a bisphenol compound comprising: a step for reacting a phenolic compound (a) with at least one compound (b) selected from the group consisting of dialkenylbenzene compounds, bis(hydroxyalkyl)benzene compounds and (hydroxyalkyl)-alkenylbenzene compounds or at least one compound (c) selected from the group consisting of monoalkenylphenolic compounds and mono(hydroxyalkyl)phenolic compounds in the presence of an acidic catalyst to obtain a reaction mixture containing said bisphenol compound, a step for neutralizing the reaction mixture with an anion exchange resin, a step for removing a remaining phenolic compound from the reaction mixture to concentrate the neutralized reaction mixture, and a step for isolating the bisphenol compound from the resulting concentrated mixture. This process enables to produce a bisphenol compound, which is useful for preparing raw materials of thermoplastic polymers, surface-active agents and stabilizers.
摘要翻译：一种制备双酚化合物的方法，包括：使酚类化合物（a）与至少一种选自二苯基苯化合物，双（羟烷基）苯化合物和（羟基烷基） - 烯基苯的化合物（b）反应的步骤化合物或至少一种选自单链烯基酚化合物和单（羟基烷基）酚类化合物的化合物（c），在酸性催化剂存在下，得到含有所述双酚化合物的反应混合物，将反应混合物与阴离子交换树脂，用于从反应混合物中除去剩余的酚类化合物以浓缩中和的反应混合物的步骤，以及从所得浓缩混合物中分离双酚化合物的步骤。该方法能够生产双酚化合物，其可用于制备热塑性聚合物的原料，表面活性剂和稳定剂。

2. 发明授权

US06933411B2 Aromatic diamine and polyimide thereof 失效
标题翻译：芳族二胺及其聚酰亚胺
公开(公告)号：US06933411B2
公开(公告)日：2005-08-23
申请号：US10718532
申请日：2003-11-24
申请人： Naoshi Nagai , Masaru Kawaguchi
发明人： Naoshi Nagai , Masaru Kawaguchi
IPC分类号： C07C217/90 , C08G73/10
CPC分类号： C08G73/1071 , C08G73/1039 , C08G73/105
摘要： The aromatic diamine compound of the present invention is represented by the following formula (1), and from the aromatic diamine compound a polyimide having a repeating unit represented by the following formula (4), which has low-temperature adherability, can be obtained. In the formulas (1) and (4), n is an integer of 3 to 7, each R is independently an atom or a group selected from the group consisting of a hydrogen atom, a halogen atom and a hydrocarbon group, the same or different two hetero atoms selected from nitrogen atoms and oxygen atoms bonded to each benzene ring are at the ortho- or meta-positions to each other on at least one benzene ring, and when n is 3, the hetero atoms are at the ortho- or meta-positions to each other on all the benzene rings. In the formula (4), Y is a tetravalent organic group.
摘要翻译：本发明的芳香族二胺化合物由下式（1）表示，由芳族二胺化合物得到具有低温粘合性的下述式（4）表示的重复单元的聚酰亚胺。在式（1）和（4）中，n为3〜7的整数，R各自独立地为选自氢原子，卤素原子和烃基的原子或基团，相同或选自与每个苯环键合的氮原子和氧原子的不同的两个杂原子在至少一个苯环上彼此相邻或间位，当n为3时，杂原子处于邻位或间隔在所有苯环上彼此相互排列。在式（4）中，Y是四价有机基团。

3. 发明授权

US5932759A Process for producing substituted amines and a method for purifying synthetic intermediates therefor 失效
标题翻译：制备取代胺的方法及其合成中间体的纯化方法
公开(公告)号：US5932759A
公开(公告)日：1999-08-03
申请号：US800149
申请日：1997-02-13
申请人： Yoshio Motoyama , Naoshi Nagai , Takeshi Ishitoku , Noriaki Kihara
发明人： Yoshio Motoyama , Naoshi Nagai , Takeshi Ishitoku , Noriaki Kihara
IPC分类号： C07C239/20 , C07C261/00
CPC分类号： C07C239/20
摘要： The present invention relates to a process for producing a substituted amine represented by the general formula (IV):R.sup.2 NHOR.sup.3 (IV)(wherein R.sup.2 represents a hydrogen atom, a hydrocarbon group or a heteroatom-containing hydrocarbon group, and R.sup.3 represents a hydrocarbon group or a heteroatom-containing hydrocarbon group), which comprises the steps of:(b) reacting a hydroxamic acid represented by the general formula (II):R.sup.1 CONHOH (II)(wherein R.sup.1 represents a hydrogen atom or a hydrocarbon group) in the presence of a base with a reaction reagent capable of introducing a hydrocarbon or a heteroatom-containing hydrocarbon group to an oxygen atom and/or a nitrogen atom to form a substituted hydroxamic acid represented by the general formula (III): ##STR1## (wherein R.sup.1, R.sup.2 and R.sup.3 possess the same meanings as defined above),(c) hydrolyzing said substituted hydroxamic acid (III) in the presence of a base or an acid to produce a substituted amine represented by the general formula (IV):R.sup.2 NHOR.sup.3 (IV)(wherein R.sup.2 and R.sup.3 possess the same meanings as defined above). The present further relates to a method for purifying a synthetic intermediate for said substituted amine.
摘要翻译：本发明涉及由通式（IV）表示的取代胺的制备方法：R2NHOR3（IV）（其中R2表示氢原子，烃基或含杂原子的烃基，R3表示烃基或含杂原子的烃基），其包括以下步骤：（b）使通式（II）表示的异羟肟酸：R 1 CONHOH（II）（其中R 1表示氢原子或烃基）的具有能够将烃或含杂原子的烃基引入氧原子和/或氮原子的反应试剂形成由通式（III）表示的取代的异羟肟酸的反应试剂：其中R1，R2和 R3具有与上述相同的含义），（c）在碱或酸的存在下水解所述取代的异羟肟酸（III）以产生由通式（IV）表示的取代胺：R2NHOR3（IV）（其中 R 2和R3具有与上述相同的含义）。本发明还涉及纯化所述取代胺的合成中间体的方法。

4. 发明申请

US20130344273A1 MOLDED ARTICLE 有权
标题翻译：模制品
公开(公告)号：US20130344273A1
公开(公告)日：2013-12-26
申请号：US13980950
申请日：2012-01-18
申请人： Kaori Matoishi , Takuma Yano , Hiromasa Marubayashi , Naoki Tomoshige , Naoshi Nagai , Tamotsu Harada , Kuniaki Kawabe
发明人： Kaori Matoishi , Takuma Yano , Hiromasa Marubayashi , Naoki Tomoshige , Naoshi Nagai , Tamotsu Harada , Kuniaki Kawabe
IPC分类号： C08L23/26
CPC分类号： C08L23/26 , C08F8/42 , C08F10/00 , C08F110/02 , C08F2810/40 , C08L23/10 , C08L83/00 , C08L83/04 , C08L101/10 , C08L2312/08 , Y10T428/1397 , Y10T428/249921 , C08L51/06
摘要： A molded article formed of a composition including 100 parts by weight of at least one kind of resin selected from the group consisting of thermoplastic resins and thermosetting resins, and 0.01 parts by weight to 10,000 parts by weight of a silylated polyolefin, which is obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and a vinyl group-containing compound having a defined number average molecular weight, a derivative thereof, or a mixture of these, —Si(R1)H—Y1— (1) wherein R1 and Y1 are defined and with the proviso that the silylated polyolefin is not obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and having two or more SH groups per molecule and a compound having 2.0 or more vinyl groups on average per molecule as the vinyl group-containing compound.
摘要翻译：由包含100重量份的选自热塑性树脂和热固性树脂的至少一种树脂和0.01重量份至10,000重量份的甲硅烷基化聚烯烃的组合物形成的模塑制品，其通过包含式（1）表示的结构单元的含硅化合物和具有确定数均分子量的含乙烯基的化合物，其衍生物或它们的混合物之间的反应-Si（R1）H- Y 1 - （1）其中R1和Y1被定义，条件是甲硅烷基化聚烯烃不是通过含有由式（1）表示的结构单元的含硅化合物与每分子具有两个或更多个SH基团的反应而得到的和每分子平均具有2.0个以上乙烯基的化合物作为含乙烯基的化合物。

5. 发明申请

US20120095167A1 METHOD FOR PREVENTING FOULING IN CHEMICAL EQUIPMENT AND ANTIFOULING AGENT 失效
标题翻译：防止化学设备和反应剂发生化学反应的方法
公开(公告)号：US20120095167A1
公开(公告)日：2012-04-19
申请号：US13258554
申请日：2010-03-31
申请人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
发明人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
IPC分类号： C08L53/00 , C08F4/00 , C08F293/00
CPC分类号： C08G65/329 , C08F210/16 , C08G2261/126 , C08L71/02 , C08L2205/05 , C10G75/04 , C10G2300/1088 , C10G2300/4075 , C10G2400/22 , C08F2/005 , C08F210/14 , C08F2500/17 , C08F2500/12 , C08F2500/18 , C08F210/08 , C08L23/00
摘要： The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer having Mn of 30,000 or less to a component in the chemical equipment.
摘要翻译：本发明提供一种防止化学设备中结垢的方法，包括向化学设备中的组分添加包含Mn为30,000以下的聚氧化烯聚合物的防污剂。

6. 发明授权

US07977429B2 Polymers and uses thereof 有权
标题翻译：聚合物及其用途
公开(公告)号：US07977429B2
公开(公告)日：2011-07-12
申请号：US10587419
申请日：2005-01-20
申请人： Naoshi Nagai , Masahiko Mitsuzuka , Kazuoki Nakai , Motoaki Isokawa , Shiro Nakatsuka , Daiki Taneichi , Shirou Honma , Toshimitsu Narutaki
发明人： Naoshi Nagai , Masahiko Mitsuzuka , Kazuoki Nakai , Motoaki Isokawa , Shiro Nakatsuka , Daiki Taneichi , Shirou Honma , Toshimitsu Narutaki
IPC分类号： C08L63/00
CPC分类号： C08G65/02 , A61K8/8111 , A61K8/89 , A61Q19/00 , C08F8/00 , C08F8/08 , C08F8/14 , C08F8/18 , C08F8/32 , C08F8/42 , C08F2810/40 , C08G65/34 , C08G69/40 , C08G73/028 , C08G75/02 , C08G77/442 , C08L71/02 , C08L77/00 , C08L79/02 , C08L81/02 , C08L2666/02 , C08F110/02 , C08F210/16
摘要： Polymers having polyolefin segments as the side chain, with a structural unit represented by the following Formula (1): wherein A is an olefin polymer having a weight average molecular weight of 400 to 500,000; R is H, an alkyl group, or an aralkyl group; W and Z are each O, HN, or S; and x and y are each 0 or 1, with the proviso that at least one of them is 1. The polymer can be applied as an antistatic agent, a cosmetic additive, a releasing agent for toner, a pigment dispersant, a lubricant for vinyl chloride resins, a coating material, an emulsion composition and the like.
摘要翻译：具有聚烯烃链段作为侧链的聚合物具有由下式（1）表示的结构单元：其中A是重均分子量为400至500,000的烯烃聚合物; R是H，烷基或芳烷基; W和Z各自为O，HN或S; 并且x和y各自为0或1，条件是它们中的至少一个为1.聚合物可以作为抗静电剂，化妆品添加剂，调色剂用脱模剂，颜料分散剂，乙烯基润滑剂氯化物树脂，涂料，乳液组合物等。

7. 发明授权

US06743959B1 Method for the dehydrogenation of triisopropyl benzene and diisopropyl benzene 有权
标题翻译：三异丙基苯和二异丙基苯脱氢的方法
公开(公告)号：US06743959B1
公开(公告)日：2004-06-01
申请号：US10069643
申请日：2002-02-28
申请人： Hiroyoshi Watanabe , Tatsumi Matsushita , Shinobu Aoki , Naoshi Nagai , Hisaharu Kuboyama
发明人： Hiroyoshi Watanabe , Tatsumi Matsushita , Shinobu Aoki , Naoshi Nagai , Hisaharu Kuboyama
IPC分类号： C07C5367
CPC分类号： B01J23/94 , B01J23/76 , B01J23/78 , B01J38/06 , B01J38/12 , C07C5/333 , C07C5/3335 , C07C5/48 , C07C2521/10 , C07C2523/04 , C07C2523/745 , C07C2523/78 , C07C2523/881 , Y02P20/52 , Y02P20/584 , C07C15/44
摘要： An economical and industrial method for the dehydrogenation of triisopropyl benzene can be provided by carrying out the reaction employing a solid catalyst having an iron compound and potassium compound as major components or an iron compound, potassium compound, and magnesium compound as major components, as a dehydrogenating catalyst for producing diisopropyl isopropenyl benzene, isopropyl diisopropenyl benzene and/or triisopropenyl benzene from triisopropyl benzene. In the dehydrogenation of triisopropyl benzene or diisopropyl benzene, by carrying out an off-and-on reaction in which the above described solid catalyst is employed and with which a regeneration period with steam or oxygen or air is provided, an economical and industrial dehydrogenation method having an extended life of the catalyst can be provided and will have an industrial superiority.
摘要翻译：可以通过使用具有铁化合物和钾化合物作为主要成分的固体催化剂或铁化合物，钾化合物和镁化合物作为主要成分进行反应来提供三异丙基苯脱氢的经济和工业方法，作为用于从三异丙基苯生产二异丙基异丙烯基苯，异丙基二异丙烯基苯和/或三异丙烯基苯的脱氢催化剂。在三异丙基苯或二异丙基苯的脱氢中，通过进行使用上述固体催化剂和提供蒸汽或氧气或空气的再生时间的脱离反应，经济和工业脱氢方法可以提供催化剂的使用寿命并具有工业上的优越性。

8. 发明授权

US08513362B2 Polyolefin polymer having polar group, method for production thereof, and water dispersion material and mold release agent composition 有权
标题翻译：具有极性基团的聚烯烃聚合物，其制造方法以及水分散材料和脱模剂组合物
公开(公告)号：US08513362B2
公开(公告)日：2013-08-20
申请号：US12452435
申请日：2008-06-17
申请人： Makoto Suzuki , Naoshi Nagai
发明人： Makoto Suzuki , Naoshi Nagai
IPC分类号： C08F8/10 , C08F8/12 , C08F8/46 , C08F8/42 , B29C33/62
CPC分类号： B29C33/62 , C08F8/44 , C08F8/46 , C08F110/02 , C08F2810/30 , C08F2810/40 , C08J3/05 , C08J2323/26 , C08L23/26 , C08L69/00 , C09D11/106 , C08F210/16 , C08L2666/06 , C08F4/64048 , C08F210/06 , C08F210/08
摘要： To provide a polyolefin polymer having a polar group represented by Formula (i) produced by modifying, with a high modification ratio, a double bond in a polymer having the double bond at one terminal, both terminals, or at the inside of a polymer chain thereof that is obtained by a known method; a method for producing the polyolefin polymer; and a water dispersion material and a mold release agent composition each containing the polyolefin polymer, wherein, PO, A, B, D, E, d, e, M, i, j, and n are defined as in the application.
摘要翻译：提供具有式（i）表示的极性基团的聚烯烃聚合物，其通过以高改性比改性在聚合物链的一个末端，两个末端或内部具有双键的聚合物中的双键而制备其通过已知方法获得; 聚烯烃聚合物的制造方法; 以及各自含有聚烯烃聚合物的水分散体材料和脱模剂组合物，其中，PO，A，B，D，E，d，e，M，i，j和n如本申请中所定义。

9. 发明授权

US08354529B2 Polyamine derivative and polyol derivative 有权
标题翻译：多胺衍生物和多元醇衍生物
公开(公告)号：US08354529B2
公开(公告)日：2013-01-15
申请号：US13289013
申请日：2011-11-04
申请人： Naruyoshi Mita , Mitsuaki Chida , Masaru Kawaguchi , Kengo Otsuka , Naoshi Nagai , Takaaki Yamazaki , Tetsuya Ichihashi
发明人： Naruyoshi Mita , Mitsuaki Chida , Masaru Kawaguchi , Kengo Otsuka , Naoshi Nagai , Takaaki Yamazaki , Tetsuya Ichihashi
IPC分类号： C07D401/14 , C08K5/3492 , C08L101/00 , C09K15/30
CPC分类号： C09K15/30 , C07D401/14 , C07D493/10 , C08K5/34926 , C09K15/16
摘要： A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R4) or an oxygen atom; R1 is an n-valent hydrocarbon group; R2 is an hydrogen atom or an alkyl; R3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.
摘要翻译：具有哌啶基氨基三嗪骨架的新型多胺衍生物或多元醇衍生物; 这些化合物的盐; 一个生产它们的过程; 包含任何这些化合物的有机材料稳定剂; 稳定有机材料的方法; 和稳定的有机金属材料。通式为（1）的化合物（其中X为N（R4）或氧原子; R1为n价烃基; R2为氢原子或烷基; R3为氢原子，烷基，烷氧基或酰基; R 4为氢原子或烷基，n为3〜16的整数）可有效地抑制有机材料的光，热，氧，臭氧和电磁波的劣化，例如X 射线和γ射线。

10. 发明申请

US20120053270A1 POLYAMINE DERIVATIVE AND POLYOL DERIVATIVE 有权
标题翻译：聚氨酯衍生物和多元醇衍生物
公开(公告)号：US20120053270A1
公开(公告)日：2012-03-01
申请号：US13289013
申请日：2011-11-04
申请人： NARUYOSHI MITA , Mitsuaki Chida , Masaru Kawaguchi , Kengo Otsuka , Naoshi Nagai , Takaaki Yamazaki , Tetsuya Ichihashi
发明人： NARUYOSHI MITA , Mitsuaki Chida , Masaru Kawaguchi , Kengo Otsuka , Naoshi Nagai , Takaaki Yamazaki , Tetsuya Ichihashi
IPC分类号： C08K5/3492 , C08L23/06 , C08L23/12 , C07D401/14 , C07D493/10
CPC分类号： C09K15/30 , C07D401/14 , C07D493/10 , C08K5/34926 , C09K15/16
摘要： A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R4) or an oxygen atom; R1 is an n-valent hydrocarbon group; R2 is an hydrogen atom or an alkyl; R3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.
摘要翻译：具有哌啶基氨基三嗪骨架的新型多胺衍生物或多元醇衍生物; 这些化合物的盐; 一个生产它们的过程; 包含任何这些化合物的有机材料稳定剂; 稳定有机材料的方法; 和稳定的有机金属材料。通式为（1）的化合物（其中X为N（R4）或氧原子; R1为n价烃基; R2为氢原子或烷基; R3为氢原子，烷基，烷氧基或酰基; R 4为氢原子或烷基，n为3〜16的整数）可有效地抑制有机材料的光，热，氧，臭氧和电磁波的劣化，例如X 射线和γ射线。

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