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1. 发明授权

US5990192A Radiation-curable water-dilutable urethane resins, preparation process and use 失效
标题翻译：可辐射固化水可稀释的聚氨酯树脂，制备方法和用途
公开(公告)号：US5990192A
公开(公告)日：1999-11-23
申请号：US57583
申请日：1998-04-09
申请人： Martin Gerlitz , Rami-Raimund Awad , Ulrike Kuttler , Thomas Fraydl , Martin Leitner , Andreas Kocsar
发明人： Martin Gerlitz , Rami-Raimund Awad , Ulrike Kuttler , Thomas Fraydl , Martin Leitner , Andreas Kocsar
IPC分类号： C08G18/67 , C09D175/14 , C08G18/62
CPC分类号： C09D175/14 , C08G18/6705 , C08G18/675 , Y10T428/31591
摘要： Radiation-curable water-dilutable urethane resins obtainable by reacting cycloaliphatic and/or aromatic diisocyanates with a mixture of a (meth)acryloyl-containing dihydroxy compound in an amount such that the amount of reactive hydroxyl groups present therein is from 0.2 to 0.6 mol, and with a tri or tetrahydric polyol which has been partly esterified with (meth)acrylic acid and has a residual average hydroxyl functionality of from 1.0 to 1.4 in the molecule, in an amount such that the amount of the reactive hydroxyl groups is from 0.4 to 0.8 mol, the sum of the amounts of the reactive hydroxyl groups always being 1.0 mol, and from 40 to 60% of the isocyanate groups being converted into urethane groups, and reacting the resulting intermediate with an aliphatic saturated monocarboxylic acid having at least two hydroxyl groups in an amount such that the amount of the reactive hydroxyl groups is from 0.6 to 1 mol, until the hydroxyl groups have undergone complete reaction and reacting this product, if desired, with further part-esterified polyol in an amount such that the amount of hydroxyl groups in the polyol is from 0 to 0.5 mol until the remaining free isocyanate groups have undergone complete reaction, the molar proportions of the components being chosen so that the ratio of the number of isocyanate groups to the number of hydroxyl groups is from 0.9:1 to 1:1 and the reaction product possesses carboxyl groups in accordance with an acid number of from 20 to 40 mg/g and has a specific double bond content of not more than 3.5 mol/kg.
摘要翻译：可通过使脂环族和/或芳族二异氰酸酯与含（甲基）丙烯酰基的二羟基化合物的混合物使其中存在的反应性羟基的量为0.2至0.6mol的量反应得到的可辐射固化水可稀释的聚氨酯树脂，和与（甲基）丙烯酸部分酯化并且在分子中具有1.0至1.4的残余平均羟基官能度的三元或四元多元醇，其量使得反应性羟基的量为0.4至 0.8mol，反应性羟基的总量总计为1.0mol，异氰酸酯基的40-60％转化为氨基甲酸酯基团，并使得到的中间体与具有至少两个羟基的脂族饱和一元羧酸反应基团的量使得反应性羟基的量为0.6至1mol，直到羟基已经完全反应并使其反应是产物，如果需要，还有部分酯化的多元醇的量使得多元醇中羟基的量为0至0.5mol，直到剩余的游离异氰酸酯基团经历了完全反应，选择的组分的摩尔比例使得异氰酸酯基数与羟基数的比例为0.9:1至1:1，并且反应产物具有根据酸值为20至40mg / g的羧基，并且具有特定的双键含量不超过3.5 mol / kg。

2. 发明授权

US06265461B1 High-solids, radiation-curable water-soluble combinations of polyester resins 有权
标题翻译：高固体，可辐射固化的聚酯树脂的水溶性组合
公开(公告)号：US06265461B1
公开(公告)日：2001-07-24
申请号：US09383091
申请日：1999-08-25
申请人： Edmund Urbano , Ulrike Kuttler , Martin Gerlitz , Rami-Raimund Awad
发明人： Edmund Urbano , Ulrike Kuttler , Martin Gerlitz , Rami-Raimund Awad
IPC分类号： C09D16707
CPC分类号： C09D167/07 , C08G63/21 , C08L67/00
摘要： Radiation curable polyester composition AB, capable of forming solutions or dispersions in water of high solid content which can be produced by mixing or pre-condensing a water soluble, radiation-curable emulsifying resin A which contains ester and acid groups and has an acid number from 20 to 300 mg/g and water-insoluble, radiation-curable polymer B containing ester and/or ether groups, wherein resin A is a reaction product of an alkoxylated polyol A1 having at least 3 hydroxyl groups and 3 to 10 oxyalkylene units per molecule, these oxyalkylene units containing 2 to 4 carbon atoms each, with an &agr;, &bgr;-unsaturated carboxylic acid A2 having each a free carboxyl group per molecule, and a carboxylic acid A3 which is at least tri-functional and wherein polymer B is a reaction product of aliphatic, linear, branched or cyclic alcohols B1 with compounds B2, selected from alkylene oxides B21, dicarboxylic acids B22 and aliphatic lactones B23 having 4 to 12 carbon atoms as well as compounds B3 selected from &agr;,&bgr;-unsaturated carboxylic acids with 1 to 2 carboxyl groups in the molecule, aqueous coating compositions made therefrom, and a method of using these for coating of heat-sensitive substrates.
摘要翻译：可辐射固化的聚酯组合物AB，其能够在高固含量的水中形成溶液或分散体，其可通过将含有酯和酸基团并具有酸值的水溶性可辐射固化的乳化树脂A混合或预冷凝来制备 20至300mg / g和含有酯和/或醚基团的水不溶性可辐射固化聚合物B，其中树脂A是每分子具有至少3个羟基和3至10个氧化烯单元的烷氧基化多元醇A1的反应产物，各自含有2至4个碳原子的这些氧化烯单元与每分子具有游离羧基的α，β-不饱和羧酸A2和至少三官能的羧酸A3，其中聚合物B是反应脂肪族，直链，支链或环状醇B1与化合物B2的选自烯化氧B21，二羧酸B22和碳原子数4〜12的脂肪族内酯B23以及组合物 ds B3选自分子中具有1至2个羧基的α，β-不饱和羧酸，由其制备的水性涂料组合物，以及使用它们来涂覆热敏性基材的方法。

3. 发明授权

US5596065A Water-dilutable urethane resins, process for the preparation, and the use thereof 失效
标题翻译：水可稀释的聚氨酯树脂，制备方法及其用途
公开(公告)号：US5596065A
公开(公告)日：1997-01-21
申请号：US506761
申请日：1995-07-26
申请人： Martin Gerlitz , Rami-Raimund Awad , Thomas Fraydl
发明人： Martin Gerlitz , Rami-Raimund Awad , Thomas Fraydl
IPC分类号： C07C275/60 , C08G18/81 , C08G18/10
CPC分类号： C08G18/815 , C07C275/60 , C08G18/8175
摘要： Process for the preparation of water-dilutable urethane resins and use of the so produced urethane resins, for example, as binders for coating materials which can be crosslinked by free-radical polymerization.
摘要翻译：用于制备水可稀释聚氨酯树脂的方法和使用如此制备的聚氨酯树脂，例如作为可通过自由基聚合交联的涂料的粘合剂。

4. 发明申请

US20050287302A1 Aqueous non-ionically stabilized epoxy resins 失效
标题翻译：水性非离子稳定化环氧树脂
公开(公告)号：US20050287302A1
公开(公告)日：2005-12-29
申请号：US10531090
申请日：2003-10-17
申请人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
发明人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
IPC分类号： C08F299/02 , C08G18/67 , C08G59/16 , C08L63/10 , C08L75/14 , C09D163/10 , C09D175/14 , B05D3/02 , C08L63/00
CPC分类号： C08G18/675 , C08F299/026 , C08G59/1461 , C08L63/10 , C08L75/14 , C09D163/10 , C09D175/14 , C08L2666/20 , C08L2666/22
摘要： Aqueous radiation curable binders comprising non-ionically stabilised epoxy resins ABC, characterised in that they comprise building blocks of epoxy resins A modified with polyethylene glycol, of epoxy resins B that are free from polyethylene glycol, and of olefinically unsaturated acids C, and that at least 50% of all reaction products derived from the epoxy resins A and B comprise at least one ester group formed by reaction of a terminal epoxy group with an olefinically unsaturated acid C, a process for their preparation, and use thereof as coating composition
摘要翻译：包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂，其特征在于它们包含不含聚乙二醇的环氧树脂B和不饱和C的环氧树脂A和聚乙二醇改性的结构单元，衍生自环氧树脂A和B的所有反应产物的至少50％包含由末端环氧基与烯属不饱和酸C反应形成的至少一个酯基，其制备方法及其用作涂料组合物

5. 发明授权

US07560143B2 Aqueous non-ionically stabilized epoxy resins 失效
标题翻译：水性非离子稳定化环氧树脂
公开(公告)号：US07560143B2
公开(公告)日：2009-07-14
申请号：US10531090
申请日：2003-10-17
申请人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
发明人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
IPC分类号： B05D3/06 , B05D1/02 , B05D1/18 , C08F2/46 , C08G63/00 , C08L63/00 , B32B15/092 , B32B27/38
CPC分类号： C08G18/675 , C08F299/026 , C08G59/1461 , C08L63/10 , C08L75/14 , C09D163/10 , C09D175/14 , C08L2666/20 , C08L2666/22
摘要： Aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC. Resins ABC are an adduct mixture of: adducts formed by the reaction of polyethylene glycol-modified epoxy resins A with olefinically unsaturated acids C, and adducts formed by the reaction of epoxy resins B, that are free from polyethylene glycol derived groups, with olefinically unsaturated acids C. A process for preparing aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC, and a process of coating a substrate with aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC.
摘要翻译：包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂。树脂ABC是以下加合物混合物：由聚乙二醇改性的环氧树脂A与烯属不饱和酸C反应形成的加合物，和不含聚乙二醇衍生基团的环氧树脂B与烯属不饱和酸反应形成的加成物酸C.制备包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂的方法，以及用包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂涂覆基材的方法。

6. 发明授权

US06350796B1 Ionically on nonionically stabilized epoxy adducts as water-dilutable base resins for 2-component isocyanate crosslinkable systems 失效
标题翻译：作为用于2-组分异氰酸酯交联体系的水可稀释基础树脂，非离子稳定的环氧加合物
公开(公告)号：US06350796B1
公开(公告)日：2002-02-26
申请号：US09427435
申请日：1999-10-26
申请人： Gert Dworak , Martin Gerlitz , Roland Feola , Manfred Weinberger
发明人： Gert Dworak , Martin Gerlitz , Roland Feola , Manfred Weinberger
IPC分类号： C08K320
CPC分类号： C09D175/04 , C08G18/0814 , C08G18/0823 , C08G18/6407
摘要： Two-component systems based on aqueous dispersions of hydrophilic epoxy adducts Ah having hydroxyl groups as reactive groups and unblocked difunctional or polyfunctional isocyanates B, said hydrophilic epoxy adducts Ah being selected from cationically stabilized hydrophilic epoxy adducts Ak, anionically stabilized hydrophilic epoxy adducts Aa and also nonionically stabilized epoxy adducts An and zwitterionically stabilized epoxy-amine adducts Aak.
摘要翻译：基于亲水性环氧加合物Ah的水分散体的双组分体系Ah具有作为反应性基团的羟基和未封闭的双官能或多官能异氰酸酯B，所述亲水性环氧加合物Ah选自阳离子稳定的亲水性环氧加合物Ak，阴离子稳定的亲水环氧加成物Aa，以及非离子稳定化环氧加合物An和两性离子稳定的环氧胺加合物Aak。

7. 发明授权

US08765799B2 Streptospirole derivatives 有权
标题翻译：链球菌衍生物
公开(公告)号：US08765799B2
公开(公告)日：2014-07-01
申请号：US13056751
申请日：2009-07-16
申请人： Cosima Dufour-Schroif , Joachim Wink , Martin Gerlitz , Hélène Olivan , Michael Kurz
发明人： Cosima Dufour-Schroif , Joachim Wink , Martin Gerlitz , Hélène Olivan , Michael Kurz
IPC分类号： A61K31/407 , C07D491/107 , C07D498/10
CPC分类号： C07D498/10 , C07D491/107
摘要： The invention relates to streptospirole derivatives of the general formula (I), wherein R1, R2, R3, X1, X2, Y1 and Y2 are as defined herein, a process for the preparation of said compounds by fermenting the microorganism Streptomyces sp. ST 108140 (DSM 19369) and optionally derivatizing the compounds produced by said microorganism, a pharmaceutical composition comprising at least one compound of the formula (I), and the use of a compound of the formula (I) for the preparation of a medicament for the treatment and/or prophylaxis of bacterial infections.
摘要翻译：本发明涉及通式（I）的链霉菌素衍生物，其中R1，R2，R3，X1，X2，Y1和Y2如本文所定义，通过发酵微生物Streptomyces sp。 ST108404（DSM19369），并任选地衍生由所述微生物产生的化合物，包含至少一种式（I）化合物的药物组合物和式（I）化合物在制备药物中的应用治疗和/或预防细菌感染。

8. 发明授权

US06211286B1 Binders for soft feel coating materials 失效
标题翻译：粘合剂柔软涂层材料
公开(公告)号：US06211286B1
公开(公告)日：2001-04-03
申请号：US09483592
申请日：2000-01-14
申请人： Markus A. Schafheutle , Martin Gerlitz , Anton Arzt , Julius Burkl , Joerg Wango , Martina Glettler
发明人： Markus A. Schafheutle , Martin Gerlitz , Anton Arzt , Julius Burkl , Joerg Wango , Martina Glettler
IPC分类号： C08L6900
CPC分类号： C09D175/12 , C08G18/0823 , C08G18/12 , C08G18/284
摘要： Aqueous binders for soft feel materials, comprising predominantly aliphatic, water-soluble or water-dispersible polymers A having terminal or lateral cyclic carbonate groups and an amine B having at least two primary amino groups, the ratio of the number of primary amino groups in the component B to the number of cyclic carbonate groups in the component A being from 7:3 to 3:7.
摘要翻译：用于软感材料的水性粘合剂，主要包含具有末端或侧向环状碳酸酯基团的脂族，水溶性或水分散性聚合物A和具有至少两个伯氨基的胺B，其中伯氨基组分B与组分A中的环状碳酸酯基团数目为7:3至3:7。

9. 发明申请

US20110295009A1 STREPTOSPIROLE DERIVATIVES 有权
公开(公告)号：US20110295009A1
公开(公告)日：2011-12-01
申请号：US13056751
申请日：2009-07-16
申请人： Cosima Dufour-Schroif , Joachim Wink , Martin Gerlitz , Helene Olivan , Michael Kurz
发明人： Cosima Dufour-Schroif , Joachim Wink , Martin Gerlitz , Helene Olivan , Michael Kurz
IPC分类号： C07D491/107 , C12N1/20 , C12P17/16
CPC分类号： C07D498/10 , C07D491/107
摘要： The invention relates to streptospirole derivatives of the general formula (I), wherein R1, R2, R3, X1, X2, Y1 and Y2 are as defined herein, a process for the preparation of said compounds by fermenting the microorganism Streptomyces sp. ST 108140 (DSM 19369) and optionally derivatizing the compounds produced by said microorganism, a pharmaceutical composition comprising at least one compound of the formula (I), and the use of a compound of the formula (I) for the preparation of a medicament for the treatment and/or prophylaxis of bacterial infections.
摘要翻译：本发明涉及通式（I）的链霉菌素衍生物，其中R1，R2，R3，X1，X2，Y1和Y2如本文所定义，通过发酵微生物Streptomyces sp。 ST108404（DSM19369），并任选地衍生由所述微生物产生的化合物，包含至少一种式（I）化合物的药物组合物和式（I）化合物在制备药物中的应用治疗和/或预防细菌感染。

10. 发明授权

US06653369B2 Water dilutable amine curing agents for aqueous two component epoxy resin systems 有权
标题翻译：水可稀释胺固化剂用于水性双组分环氧树脂体系
公开(公告)号：US06653369B2
公开(公告)日：2003-11-25
申请号：US10139461
申请日：2002-05-06
申请人： Martin Gerlitz , Thomas Fischer , Andreas Gollner , Manfred Gogg , Elfriede Prucher , Heike Schneeberger , Josef Wenzl
发明人： Martin Gerlitz , Thomas Fischer , Andreas Gollner , Manfred Gogg , Elfriede Prucher , Heike Schneeberger , Josef Wenzl
IPC分类号： C08K320
CPC分类号： C08G59/184
摘要： Water dilutable amine curing agents for aqueous epoxy resin dispersions, comprising a combination of an epoxide-amine adduct with an emulsifier, the epoxide-amine adduct being obtainable by reacting a polyepoxide with a reaction product of an amine and an epoxide component or an amine and subsequent reaction with an epoxide component, the amount of amine being chosen such that the number of nitrogen-attached hydrogen atoms the number of epoxide groups by a factor of from 2 to 10, and the emulsifier being obtainable by reacting diepoxides or polyepoxides with compounds that are at least difunctional with respect to epoxides, optionally with compounds D that are monofunctional with respect to epoxides, and with amines G which contain at least one tertiary and at least one primary or at least two secondary amino group(s).
摘要翻译：用于水性环氧树脂分散体的水可稀释胺固化剂，其包括环氧胺 - 胺加合物与乳化剂的组合，所述环氧胺 - 加合物可通过使多环氧化物与胺和环氧化物组分或胺的反应产物反应获得，随后与环氧化物组分的反应，选择胺的量使得连接氮原子的氢原子数目为2至10的环氧化物基团数，并且乳化剂可通过使二环氧化物或聚环氧化物与化合物至少对于环氧化物是双官能的，任选地与化合物D相对于环氧化物是单官能的，以及含有至少一个叔胺和至少一个伯或至少两个仲氨基的胺G.

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