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1. 发明申请

US20090221741A1 AQUEOUS BINDERS FOR COATINGS WITH IMPROVED GLOSS 有权
标题翻译：具有改进的GLOSS的涂料的水性粘合剂
公开(公告)号：US20090221741A1
公开(公告)日：2009-09-03
申请号：US12293091
申请日：2007-03-04
申请人： Johann Billiani , Karl Rossmann , Rami-Raimund Awad , Thomas Fraydl , Ingo Kriessmann
发明人： Johann Billiani , Karl Rossmann , Rami-Raimund Awad , Thomas Fraydl , Ingo Kriessmann
IPC分类号： C09D133/02
CPC分类号： C09D133/066 , C08F212/08 , C08F220/06 , C08F220/18
摘要： A water-reducible mixture of (meth)acrylic copolymers having a hydroxyl number of from 40 mg/g to 250 mg/g, an acid number of from 15 mg/g to 80 mg/g, a weight average molar mass Mw from 9 kg/mol to 40 kg/mol and a glass transition temperature Tg from −40° C. to 80° C., based on polymerised monomers comprising at least one alkyl ester A of an olefinically un-saturated carboxylic acid having from 1 to 8 carbon atoms in the alkyl group, at least one hydroxy functional alkyl ester B of an olefinically unsaturated carboxylic acid, at least one aliphatic compound C that has both hydroxy and carboxyl functionalities, or which is a lactone or a cyclic lactone, at least one vinyl monomer D which does not comprise a moiety derived from an olefinically unsaturated carboxylic acid, at least one olefinically unsaturated carboxylic acid E, a process for its preparation, and a method of use thereof in the preparation of paints.
摘要翻译：具有羟值为40mg / g至250mg / g，酸值为15mg / g至80mg / g，重量平均摩尔质量Mw为9的（甲基）丙烯酸共聚物的水可稀释混合物 kg / mol至40kg / mol，玻璃化转变温度Tg为-40℃至80℃，基于包含至少一种具有1至8个的烯属不饱和羧酸的烷基酯A的聚合单体烷基中的碳原子，烯属不饱和羧酸的至少一种羟基官能的烷基酯B，至少一种具有羟基和羧基官能团的脂肪族化合物C，或者是内酯或环状内酯，至少一种乙烯基单体D，其不包含衍生自烯属不饱和羧酸的部分，至少一种烯属不饱和羧酸E，其制备方法及其在制备涂料中的用途。

2. 发明申请

US20060057397A1 Fiber-reinforced laminates 审中-公开
标题翻译：纤维增强层压板
公开(公告)号：US20060057397A1
公开(公告)日：2006-03-16
申请号：US11266946
申请日：2005-11-04
申请人： Rami-Raimund Awad , Florian Lunzer
发明人： Rami-Raimund Awad , Florian Lunzer
IPC分类号： B32B27/40
CPC分类号： B32B38/00 , B29C35/0805 , B29C70/08 , B29C2035/0827 , B32B2038/0076 , B32B2305/08 , B32B2305/74 , B32B2310/0806 , Y10T428/2964 , Y10T428/31551 , Y10T428/31855
摘要： Fiber-reinforced laminates comprising at least two layers at least one of which comprises a polymer curable by irradiation with high-energy light, processes for producing them, and their use.
摘要翻译：包含至少两层的纤维增强层压板，其中至少一层包括通过用高能量光照射可固化的聚合物，其制备方法及其用途。

3. 发明授权

US06515042B2 Aqueous self-crosslinking copolymer dispersions, a process for preparing them and their use in binders for coating materials 有权
标题翻译：水性自交联共聚物分散体，其制备方法及其在涂料粘合剂中的应用
公开(公告)号：US06515042B2
公开(公告)日：2003-02-04
申请号：US09419214
申请日：1999-10-15
申请人： Ingo Kriessmann , Rami-Raimund Awad , Hannelore Gsöll , Bernhard Hirschmann , Karl Rossmann
发明人： Ingo Kriessmann , Rami-Raimund Awad , Hannelore Gsöll , Bernhard Hirschmann , Karl Rossmann
IPC分类号： C09D15100
CPC分类号： C08F265/06 , C08F257/02 , C09D151/00 , Y10S525/902
摘要： Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.
摘要翻译：在单体混合物A的第一阶段中通过自由基引发共聚获得的水性自交联共聚物分散体ABC包含具有羰基的烯属不饱和单体A1，不饱和羧酸或不饱和二羧酸A2的单酯，选自乙烯基芳族化合物的单体A3，甲基丙烯酸正丁酯以及不饱和羧酸的烷基酯或不饱和二羧酸的二烷基酯，选自不饱和二羧酸的二烷基酯的不饱和羧酸的烷基酯和其它可自由基聚合的单体A5的酯A4，以及随后的加成的第二单体混合物B和在第二阶段进一步聚合，混合物B包含对应于A1的烯属不饱和单体B1，对应于A4的酯B2和对应于A5的单体B3，随后加入具有肼或酰肼基团的化合物C.

4. 发明授权

US5596065A Water-dilutable urethane resins, process for the preparation, and the use thereof 失效
标题翻译：水可稀释的聚氨酯树脂，制备方法及其用途
公开(公告)号：US5596065A
公开(公告)日：1997-01-21
申请号：US506761
申请日：1995-07-26
申请人： Martin Gerlitz , Rami-Raimund Awad , Thomas Fraydl
发明人： Martin Gerlitz , Rami-Raimund Awad , Thomas Fraydl
IPC分类号： C07C275/60 , C08G18/81 , C08G18/10
CPC分类号： C08G18/815 , C07C275/60 , C08G18/8175
摘要： Process for the preparation of water-dilutable urethane resins and use of the so produced urethane resins, for example, as binders for coating materials which can be crosslinked by free-radical polymerization.
摘要翻译：用于制备水可稀释聚氨酯树脂的方法和使用如此制备的聚氨酯树脂，例如作为可通过自由基聚合交联的涂料的粘合剂。

5. 发明授权

US08546479B2 Aqueous binders for coatings with improved gloss 有权
标题翻译：用于具有改善光泽度的涂层的水性粘合剂
公开(公告)号：US08546479B2
公开(公告)日：2013-10-01
申请号：US12293091
申请日：2007-03-04
申请人： Johann Billiani , Karl Rossmann , Rami-Raimund Awad , Thomas Fraydl , Ingo Kriessmann
发明人： Johann Billiani , Karl Rossmann , Rami-Raimund Awad , Thomas Fraydl , Ingo Kriessmann
IPC分类号： C08G18/67
CPC分类号： C09D133/066 , C08F212/08 , C08F220/06 , C08F220/18
摘要： A water-reducible mixture of (meth)acrylic copolymers having a hydroxyl number of from 40 mg/g to 250 mg/g, an acid number of from 15 mg/g to 80 mg/g, a weight average molar mass Mw from 9 kg/mol to 40 kg/mol and a glass transition temperature Tg from −40° C. to 80° C., based on polymerised monomers comprising at least one alkyl ester A of an olefinically un-saturated carboxylic acid having from 1 to 8 carbon atoms in the alkyl group, at least one hydroxy functional alkyl ester B of an olefinically unsaturated carboxylic acid, at least one aliphatic compound C that has both hydroxy and carboxyl functionalities, or which is a lactone or a cyclic lactone, at least one vinyl monomer D which does not comprise a moiety derived from an olefinically unsaturated carboxylic acid, at least one olefinically unsaturated carboxylic acid E, a process for its preparation, and a method of use thereof in the preparation of paints.
摘要翻译：具有羟值为40mg / g至250mg / g，酸值为15mg / g至80mg / g，重量平均摩尔质量Mw为9的（甲基）丙烯酸共聚物的水可稀释混合物 kg / mol至40kg / mol，玻璃化转变温度Tg为-40℃至80℃，基于包含至少一种具有1至8个的烯属不饱和羧酸的烷基酯A的聚合单体烷基中的碳原子，烯属不饱和羧酸的至少一种羟基官能的烷基酯B，至少一种具有羟基和羧基官能团的脂肪族化合物C，或者是内酯或环状内酯，至少一种乙烯基单体D，其不包含衍生自烯属不饱和羧酸的部分，至少一种烯属不饱和羧酸E，其制备方法及其在制备涂料中的用途。

6. 发明授权

US06265461B1 High-solids, radiation-curable water-soluble combinations of polyester resins 有权
标题翻译：高固体，可辐射固化的聚酯树脂的水溶性组合
公开(公告)号：US06265461B1
公开(公告)日：2001-07-24
申请号：US09383091
申请日：1999-08-25
申请人： Edmund Urbano , Ulrike Kuttler , Martin Gerlitz , Rami-Raimund Awad
发明人： Edmund Urbano , Ulrike Kuttler , Martin Gerlitz , Rami-Raimund Awad
IPC分类号： C09D16707
CPC分类号： C09D167/07 , C08G63/21 , C08L67/00
摘要： Radiation curable polyester composition AB, capable of forming solutions or dispersions in water of high solid content which can be produced by mixing or pre-condensing a water soluble, radiation-curable emulsifying resin A which contains ester and acid groups and has an acid number from 20 to 300 mg/g and water-insoluble, radiation-curable polymer B containing ester and/or ether groups, wherein resin A is a reaction product of an alkoxylated polyol A1 having at least 3 hydroxyl groups and 3 to 10 oxyalkylene units per molecule, these oxyalkylene units containing 2 to 4 carbon atoms each, with an &agr;, &bgr;-unsaturated carboxylic acid A2 having each a free carboxyl group per molecule, and a carboxylic acid A3 which is at least tri-functional and wherein polymer B is a reaction product of aliphatic, linear, branched or cyclic alcohols B1 with compounds B2, selected from alkylene oxides B21, dicarboxylic acids B22 and aliphatic lactones B23 having 4 to 12 carbon atoms as well as compounds B3 selected from &agr;,&bgr;-unsaturated carboxylic acids with 1 to 2 carboxyl groups in the molecule, aqueous coating compositions made therefrom, and a method of using these for coating of heat-sensitive substrates.
摘要翻译：可辐射固化的聚酯组合物AB，其能够在高固含量的水中形成溶液或分散体，其可通过将含有酯和酸基团并具有酸值的水溶性可辐射固化的乳化树脂A混合或预冷凝来制备 20至300mg / g和含有酯和/或醚基团的水不溶性可辐射固化聚合物B，其中树脂A是每分子具有至少3个羟基和3至10个氧化烯单元的烷氧基化多元醇A1的反应产物，各自含有2至4个碳原子的这些氧化烯单元与每分子具有游离羧基的α，β-不饱和羧酸A2和至少三官能的羧酸A3，其中聚合物B是反应脂肪族，直链，支链或环状醇B1与化合物B2的选自烯化氧B21，二羧酸B22和碳原子数4〜12的脂肪族内酯B23以及组合物 ds B3选自分子中具有1至2个羧基的α，β-不饱和羧酸，由其制备的水性涂料组合物，以及使用它们来涂覆热敏性基材的方法。

7. 发明授权

US4996250A Water-dilutable air-drying protective coating compositions 失效
标题翻译：水可稀释风干保护涂料组合物
公开(公告)号：US4996250A
公开(公告)日：1991-02-26
申请号：US400787
申请日：1989-08-30
申请人： Rami-Raimund Awad , Gert Dworak , Bertram Zuckert , Walter Weger
发明人： Rami-Raimund Awad , Gert Dworak , Bertram Zuckert , Walter Weger
IPC分类号： C09D157/00 , C09D167/08
CPC分类号： C09D167/08 , C09D157/00 , Y10T428/31587 , Y10T428/31855 , Y10T428/31938
摘要： The invention relates to water-dilutable, air-drying protective coating compositions based on a combination of select water-dilutable alkyd resins with aqueous polymer dispersions and maleinized oils or fatty acids. The products are used with or without pigments, extenders and/or paint adjuvants or additives, depending on the particular end application, as air-drying protective coating compositions for wood and metal substrates, particularly for brushing lacquers and wood varnishes.
摘要翻译：本发明涉及基于选择性水可稀释醇酸树脂与聚合物水分散体和马来酸化油或脂肪酸的组合的可水稀释的空气干燥保护涂料组合物。根据特定的最终用途，产品与或不与颜料，增量剂和/或油漆助剂或添加剂一起用作木材和金属基材的空气干燥保护涂料组合物，特别是用于刷漆和木材清漆。

8. 发明授权

US07728054B2 Binding agents for radiation-cured aqueous paints 失效
标题翻译：辐射固化水性涂料的结合剂
公开(公告)号：US07728054B2
公开(公告)日：2010-06-01
申请号：US10568239
申请日：2004-08-20
申请人： Florian Lunzer , Rami-Raimund Awad
发明人： Florian Lunzer , Rami-Raimund Awad
IPC分类号： C08L63/10 , C08L63/00 , C08G18/00 , C08G18/72
CPC分类号： C08G18/675 , C08G18/8175 , C09D175/16
摘要： The invention relates to binding agents for radiation-cured aqueous paints, said agents containing reaction products ABCDE composed of A epoxy compounds with at least two epoxy groups per molecule, B unsaturated fatty acids, C olefinically unsaturated monomers, D compounds containing unsaturated aliphatic hydroxyl groups and E multi-functional isocyanates, whereby the compounds C are always directly bonded to the compounds B, the compounds D are always directly bonded to the compounds E and the compounds A are always directly bonded to the compounds B. The invention also relates to methods for producing said binding agents and to the use thereof.
摘要翻译：本发明涉及用于辐射固化的水性涂料的粘合剂，所述试剂含有由每分子具有至少两个环氧基的A环氧化合物组成的反应产物ABCDE，B不饱和脂肪酸，C烯属不饱和单体，含有不饱和脂族羟基的D化合物和E多官能异氰酸酯，其中化合物C总是直接键合到化合物B上，化合物D总是直接与化合物E结合，化合物A总是直接与化合物B结合。本发明还涉及方法用于生产所述粘合剂及其用途。

9. 发明申请

US20060210722A1 Radiation-hardening unsaturated polyester urethane resin 审中-公开
标题翻译：辐射硬化不饱和聚酯聚氨酯树脂
公开(公告)号：US20060210722A1
公开(公告)日：2006-09-21
申请号：US10568472
申请日：2004-08-20
申请人： Florian Lunzer , Rami-Raimund Awad
发明人： Florian Lunzer , Rami-Raimund Awad
IPC分类号： B05D3/00 , C08G18/00
CPC分类号： C09D175/16 , C08G18/8175
摘要： The invention relates to a coating agent, comprising reactive thinner (D), radiation-hardening unsaturated polyester urethane resins (ABC) with components derived from a polyester (A), multifunctional isocyanates (B) and olefinic unsaturated monomers (C) with hydroxy groups, methods for production and use thereof for coating substrates.
摘要翻译：本发明涉及包含反应性稀释剂（D），具有衍生自聚酯（A）的成分的辐射硬化不饱和聚酯聚氨酯树脂（ABC）），多官能异氰酸酯（B）和具有羟基的烯属不饱和单体（C），其制造方法和用于涂覆基材的方法。

10. 发明申请

US20050287302A1 Aqueous non-ionically stabilized epoxy resins 失效
标题翻译：水性非离子稳定化环氧树脂
公开(公告)号：US20050287302A1
公开(公告)日：2005-12-29
申请号：US10531090
申请日：2003-10-17
申请人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
发明人： Rami-Raimund Awad , Florian Lunzer , Martin Gerlitz
IPC分类号： C08F299/02 , C08G18/67 , C08G59/16 , C08L63/10 , C08L75/14 , C09D163/10 , C09D175/14 , B05D3/02 , C08L63/00
CPC分类号： C08G18/675 , C08F299/026 , C08G59/1461 , C08L63/10 , C08L75/14 , C09D163/10 , C09D175/14 , C08L2666/20 , C08L2666/22
摘要： Aqueous radiation curable binders comprising non-ionically stabilised epoxy resins ABC, characterised in that they comprise building blocks of epoxy resins A modified with polyethylene glycol, of epoxy resins B that are free from polyethylene glycol, and of olefinically unsaturated acids C, and that at least 50% of all reaction products derived from the epoxy resins A and B comprise at least one ester group formed by reaction of a terminal epoxy group with an olefinically unsaturated acid C, a process for their preparation, and use thereof as coating composition
摘要翻译：包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂，其特征在于它们包含不含聚乙二醇的环氧树脂B和不饱和C的环氧树脂A和聚乙二醇改性的结构单元，衍生自环氧树脂A和B的所有反应产物的至少50％包含由末端环氧基与烯属不饱和酸C反应形成的至少一个酯基，其制备方法及其用作涂料组合物

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