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    • 2. 发明授权
    • Temperature matched retardation layer
    • 温度匹配延迟层
    • US6088077A
    • 2000-07-11
    • US099507
    • 1998-06-18
    • Paulus Pieter De WitStephen James PickenAndre SteenbergenMartin Bosma
    • Paulus Pieter De WitStephen James PickenAndre SteenbergenMartin Bosma
    • C08G65/22C08G65/26C09K19/38G02B5/30G02F1/1335G02F1/13363C09K19/52F21V9/00G02F1/1337
    • C09K19/388C08G65/22C08G65/2606G02B5/3016G02F1/13363G02F2202/08G02F2203/21G02F2413/15
    • The invention is directed to a liquid crystalline display comprising a display cell containing liquid crystalline material and a retardation layer. The retardation layer comprises a, preferably slightly cross-linked, high-molecular weight material layer and a substrate, wherein the high-molecular weight material has a nematic phase above its Tg and a dynamic viscosity at the working temperature of at least 100 Pa.s. The difference of the Tc of the high-molecular weight material and the Tc of the low-molecular weight material of the display cell (TC.sub.cell) is in the range of -30.degree. C. to +30.degree. C., preferably in the range of -20.degree. C. to +20.degree. C., and more preferably in the range of -10.degree. C. to +10.degree. C.; and the Tg of the high-molecular weight liquid crystalline material is lower than 50.degree. C. It was found that if high-molecular weight material is used with a Tc comparable with that of the, preferably low-molecular weight, liquid crystalline material of the active cell, the temperature dependency of the retardation value of the retardation layer is comparable with that of the active cell. Thus, the retardation value of the retardation layer is comparable with that of the active cell within the temperature range in which displays are used. It was further found that by cross-linking of the high molecular weight liquid crystalline material, the retardation layers according to the invention become less susceptible to pinhole forming and unwanted variation of the twist, and have improved mechanical stability.
    • 本发明涉及一种液晶显示器,其包含含有液晶材料和延迟层的显示单元。 延迟层包括优选轻微交联的高分子量材料层和基底,其中高分子量材料具有高于其Tg的向列相和在至少100Pa的工作温度下的动态粘度。 s。 高分子量材料的Tc和显示电池(TCcell)的低分子量材料的Tc的差在-30℃至+ 30℃的范围内,优选在 -20℃至+ 20℃,更优选在-10℃至+ 10℃的范围内。 并且高分子量液晶材料的Tg低于50℃。已经发现,如果使用高分子量材料,其Tc与优选低分子量液晶材料的Tc相当, 活性单元,延迟层的延迟值的温度依赖性与活性单元的温度相关。 因此,在使用显示器的温度范围内,延迟层的延迟值与活性电池的延迟值相当。 进一步发现,通过高分子量液晶材料的交联,根据本发明的延迟层变得不易受到针孔形成和扭曲的不期望的变化的影响,并且具有改善的机械稳定性。