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    • 7. 发明申请
    • Solid-State Polymerization of a Liquid Crystalline Polymer
    • 液晶聚合物的固态聚合
    • US20130053533A1
    • 2013-02-28
    • US13594912
    • 2012-08-27
    • Kamlesh P. NairSteven D. Gray
    • Kamlesh P. NairSteven D. Gray
    • C08G63/80C08G63/685
    • C09K19/22C08K5/20C09K19/3086C09K19/322C09K19/3444C09K19/48C09K2019/0481
    • A method for forming a high molecular weight thermotropic liquid crystalline polymer is provided. The method includes melt polymerizing two or more monomers in the presence of a unique aromatic amide oligomer to form a prepolymer, and then solid-state polymerizing the prepolymer to achieve a target molecular weight. The present inventors have discovered that a unique aromatic amide oligomer can be employed to help increase the “low shear” complex viscosity of the resulting solid-state polymerized composition. This allows for the attainment of higher than conventional “low shear” complex viscosity values and/or a substantial reduction in the solid-state polymerization time needed to achieve a target complex viscosity. In addition, the oligomeric flow aid can also accelerate the extent to which the “high shear” melt viscosity is increased during solid-state polymerization, which may also contribute to a substantial reduction in the solid-state polymerization time needed to achieve a certain molecular weight.
    • 提供了形成高分子量热致液晶聚合物的方法。 该方法包括在独特的芳族酰胺低聚物存在下熔融聚合两种或更多种单体以形成预聚物,然后使预聚物固相聚合以达到目标分子量。 本发明人已经发现,可以使用独特的芳族酰胺低聚物来帮助提高所得固态聚合组合物的低剪切复合物粘度。 这允许达到高于常规低剪切复合物粘度值和/或实现目标复合物粘度所需的固态聚合时间的显着降低。 此外,低聚流动助剂还可以加速在固态聚合期间高剪切熔体粘度增加的程度,这也可能导致实现一定分子量所需的固态聚合时间的显着降低。
    • 8. 发明申请
    • Method for Minimizing Process Disruptions During Formation of a Liquid Crystalline Polymer
    • 在液晶聚合物形成期间最小化工艺中断的方法
    • US20130053531A1
    • 2013-02-28
    • US13594903
    • 2012-08-27
    • Kamlesh P. NairSteven D. Gray
    • Kamlesh P. NairSteven D. Gray
    • C08G63/80
    • C09K19/22C08K5/20C09K19/3086C09K19/322C09K19/3444C09K19/48C09K2019/0481C08L67/03
    • A method for lowering melt viscosity of a liquid crystalline polymer as it is formed in a reactor vessel. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains two or more precursor monomers (e.g., acetylated or non-acetylated). The reaction mixture is heated to an elevated temperature under agitation to initiate formation of the polymer. After a certain period of time, an aromatic amide oligomer is added to the reaction mixture. Among other things, the present inventors have discovered that such an oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. This minimizes the likelihood of “freeze off” of the polymer within the reactor vessel and limits the impact of process disruptions on the production of the liquid crystalline polymer.
    • 液晶聚合物在反应器容器中形成时的熔融粘度降低的方法。 更具体地,反应混合物最初被供应到含有两种或更多种前体单体(例如乙酰化或非乙酰化)的反应器容器中。 在搅拌下将反应混合物加热至高温以引发聚合物的形成。 经过一段时间后,向反应混合物中加入芳香族酰胺低聚物。 其中,本发明人发现,通过改变分子间聚合物链的相互作用,这样的低聚物可以作为流动助剂,从而降低聚合物基体在剪切下的总粘度。 这最小化在反应器容器内冻结聚合物的可能性,并限制了工艺中断对液晶聚合物生产的影响。