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1. 发明授权

US4308171A Method of preparing di and poly chalcogenides of group VIIb by low temperature precipitation from nonaqueous solution and small crystallite size stoichiometric layered dichalcogenides of rhenium and technetium 失效
标题翻译：通过从非水溶液和小微晶尺寸的低温沉淀制备Ⅶb族二元和多元硫族化合物的方法铼和锝的化学计量分层二硫属元素
公开(公告)号：US4308171A
公开(公告)日：1981-12-29
申请号：US169425
申请日：1980-07-16
申请人： Martin B. Dines , Russell R. Chianelli , Theresa A. Pecoraro
发明人： Martin B. Dines , Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/04 , B01J27/057 , C01B19/00 , C01G45/00 , C01G47/00 , C01G55/00 , C01G99/00 , B01J31/32 , B01J27/02 , C01B17/00
CPC分类号： B82Y30/00 , B01J27/04 , B01J27/0573 , B01J27/0576 , C01B19/007 , C01G45/00 , C01G47/00 , C01G55/00 , C01G99/006 , C01P2002/02 , C01P2002/22 , C01P2002/60 , C01P2002/72 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/80 , Y10S65/15
摘要： Finely divided, small particle (0.1 micron or less) small crystallite (about 50 A.times.100 A or less) chalcogenides of manganese, rhenium and technetium are described. These compositions are prepared by mixing the absence of an aqueous solvent, a manganese, rhenium or technetium salt with a source of chalcogenide yielding a precipitate. The manganese, rhenium or technetium salt and the source of chalcogen can be mixed either neat or in the presence of a nonaqueous aprotic solvent. The precipitate which results before removal of the anion salt is a finely divided product. In the case of rhenium dichalcogenide the product possesses a layered structure. The anion salt may be removed by any technique common to the art, pumping under vacuum being one such technique, washing with a suitable solvent being another.A method is described for the preparation of di- and poly-chalcogenides of the formula MX.sub.y wherein M is a metal selected from the group consisting of mangangese, rhenium and technetium, X is a chalcogen selected from the group consisting of sulfur, selenium, tellurium and mixtures thereof, and y is a number ranging from about 1.5 to about 4, preferably about 2, comprising the low temperature, nonaqueous precipitation of said MX.sub.y compounds from mixtures of the salts of said manganese, rhenium and technetium. Said precipitation occurs in the absence of aqueous solvents. The process of the instant invention permits the preparation of materials uncontaminated by water, oxygen or hydrolysis products.
摘要翻译：描述了细小的微粒（0.1微米或更小）的微晶（约50个Ax100A或更少）的锰，铼和锝的硫属元素。这些组合物通过将不含水溶剂，锰，铼或锝盐与硫族化物源混合而制得，产生沉淀物。锰，铼或锝盐和硫族元素源可以纯净或非水质非质子溶剂的存在下混合。在除去阴离子盐之前产生的沉淀物是细分的产物。在铼二硫属元素化合物的情况下，产物具有层状结构。阴离子盐可以通过本领域常用的任何技术除去，在真空下泵送是一种这样的技术，用合适的溶剂洗涤另一种。描述了用于制备式MXy的二硫和多硫族化物的方法，其中M是选自下列物质的金属，其中M为选自由锰，铼和锝组成的组，X为选自硫，硒，碲的硫属元素 y为约1.5至约4，优选约2的数值，包括所述锰，铼和锝的盐的混合物的所述MXy化合物的低温非水沉淀。所述沉淀发生在不含水溶剂的情况下。本发明的方法允许制备未受水，氧或水解产物污染的物质。

2. 发明授权

US4368115A Catalysts comprising layered chalcogenides of group IVb-group VIIb prepared by a low temperature nonaqueous precipitate technique 失效
标题翻译：包含通过低温非水沉淀技术制备的IVb族VIIb族的层状硫族化物的催化剂
公开(公告)号：US4368115A
公开(公告)日：1983-01-11
申请号：US242640
申请日：1981-03-11
申请人： Russell R. Chianelli , Theresa A. Pecoraro , Martin B. Dines
发明人： Russell R. Chianelli , Theresa A. Pecoraro , Martin B. Dines
IPC分类号： B01J27/02 , B01J27/04 , B01J27/057 , C01B19/00 , C01G1/12 , C01G47/00 , C10G45/04 , C10G49/02 , C10G45/08
CPC分类号： C10G49/02 , B01J27/02 , B01J27/04 , B01J27/0573 , C01B19/007 , C01G1/12 , C01G47/00 , C10G45/04 , C01P2002/02 , C01P2002/60 , C01P2006/12 , C01P2006/60 , C01P2006/80
摘要： In processes for the catalytic treatment of hydrocarbon feedstream containing organic sulfur comprising contacting said feedstream with a catalyst for a time at a temperature and pressure sufficient to effect the desired catalytic change on the feedstream, the improvement comprising using as the catalyst a layered composition of the formula MX.sub.y wherein M is a transition metal selected from the group consisting of Group IVb, Vb, VIb, VIIb and uranium, X is a chalcogen selected from the group consisting of sulfur, selenium, tellurium, and mixtures thereof, y is a number ranging from about 1.5 to about 3. The catalyst is prepared by reacting neat or in the presence of a nonaqueous solvent a Group IVb to VIIb or uranium metal salt, and a source of sulfide, selenide or telluride ions, and mixing the reactants at temperatures below 400.degree. C. and at atmospheric pressures. The catalyst may be isolated by filtration and washing with excess solvent (when one is used) or by vacuum pumping any volatile coproduced anion salt. Preferably the chalcogenide is sulfur and y is about 1.5 to about 2.The catalytic processes which are benefited by the use therein of the above-described compositions are hydrodesulfurization, hydrodenitrogenation, hydroconversion and hydrogenation run in the presence of hydrogen or a hydrogen donor solvent.
摘要翻译：在含有有机硫的烃进料流的催化处理方法中，包括使所述原料流与催化剂在足以在进料流上实现所需催化变化的温度和压力下接触一段时间，所述改进包括使用作为催化剂的分层组合物式MXy其中M是选自IVb，Vb，VIb，VIIb和铀的过渡金属，X是选自硫，硒，碲及其混合物的硫族元素，y是一个范围约1.5至约3.催化剂通过纯的或在非水溶剂（IVb至VIIb族或铀金属盐）和硫化物，硒化物或碲化物离子源的存在下反应制备，并将反应物在低于 400℃，在大气压下。催化剂可以通过过滤和用过量溶剂（当使用一种溶剂）洗涤时或通过真空泵送任何挥发性共生的阴离子盐来分离。硫属化物优选为硫，y为约1.5至约2.通过在上述组合物中使用而受益的催化方法是在氢或氢供体溶剂的存在下进行加氢脱硫，加氢脱氮，加氢转化和氢化。

3. 发明授权

US4390514A Method of preparing chalocogenides of group VIII by low temperature precipitation from nonaqueous solution, the products produced by said method and their use as catalysts 失效
标题翻译：通过从非水溶液中低温沉淀制备Ⅷ族致化子的方法，所述方法生产的产物及其用作催化剂
公开(公告)号：US4390514A
公开(公告)日：1983-06-28
申请号：US206053
申请日：1980-11-12
申请人： Russell R. Chianelli , Theresa A. Pecoraro
发明人： Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/045 , B01J27/057 , C01B17/20 , C01B19/00 , C01G55/00 , C01G1/12
CPC分类号： B82Y30/00 , B01J27/045 , B01J27/0573 , B01J27/0576 , C01B17/20 , C01B19/007 , C01G55/00 , C01P2002/02 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/80 , Y10S505/81 , Y10S505/815
摘要： A method is described for the preparation of chalcogenides of ruthenium, rhodium, osmium and iridium transition metals of the Periodic Table of the Elements which comprises mixing in the absence of an aqueous solvent a Group VIII transition metal salt with a source of chalcognide, said chalcogenide being selected from the group consisting of sulfur, selenium, tellurium and mixtures thereof, yielding a precipitate of the formula MX.sub.y wherein M is selected from the group consisting of ruthenium, rhodium, and osmium and iridium, X is sulfur, selenium, tellurium and mixtures thereof and y is a number ranging from about 0.1 to about 3, preferably 0.1 to about 2.5. By the practice of the nonaqueous synthesis technique, Group VIII chalcogenides are prepared which are finely divided, have a high surface area, small particle size and small crystallite size which are also free of excess sulfur, water and/or hydrolysis products. Layered stoichiometric osmium disulfide is prepared by this technique. The precipitates may be cleaned of any anion salt coproduct by any technique common to the art.Compounds of the formula MX.sub.y thus prepared are superior sulfur-tolerant catalysts in catalytic processes, for example, hydrodesulfurization, hydrodenitrogenation, hydroconversion, hydrogenation.
摘要翻译：描述了用于制备元素周期表的钌，铑，锇和铱过渡金属的硫族化物的方法，该方法包括在不含水溶剂的情况下混合第VIII族过渡金属盐与硫族化合物源，所述硫族化物选自硫，硒，碲及其混合物，得到式MXy的沉淀物，其中M选自钌，铑，锇和铱，X是硫，硒，碲和混合物并且y是约0.1至约3，优选0.1至约2.5的数。通过非水合成技术的实践，制备了细分的，具有高表面积，小颗粒尺寸和小微晶尺寸的第VIII族硫属化物，其也不含过量的硫，水和/或水解产物。通过该技术制备分层化学计量的二硫化锇。通过本领域普通技术可以将沉淀物清除任何阴离子盐副产物。如此制备的式MXy的化合物是催化方法中优异的耐硫催化剂，例如加氢脱硫，加氢脱氮，加氢转化，氢化。

4. 发明授权

US4288422A Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts 失效
标题翻译：通过从水溶液中低温沉淀制备第Ⅷ族硫族化物的方法，所述方法生产的产物及其用作催化剂
公开(公告)号：US4288422A
公开(公告)日：1981-09-08
申请号：US160106
申请日：1980-06-16
申请人： Russell R. Chianelli , Theresa A. Pecoraro
发明人： Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/045 , B01J27/057 , C01B19/04 , C01G55/00 , C01G3/12
CPC分类号： C01B19/04 , B01J27/045 , B01J27/0573 , B01J27/0576 , B82Y30/00 , C01G55/00 , C01P2002/02 , C01P2002/22 , C01P2002/60 , C01P2002/77 , C01P2004/64 , C01P2006/12 , C01P2006/80 , Y10S505/81
摘要： A method is described for the preparation of chalcogenides of ruthenium, rhodium, osmium and iridium transition metals of the Periodic Table of the Elements which comprises mixing in the absence of an aqueous solvent a Group VIII transition metal salt with a source of chalcogenide, said chalcogenide being selected from the group consisting of sulfur, selenium, tellurium and mixtures thereof, yielding a precipitate of the formula MX.sub.y wherein M is selected from the group consisting of ruthenium, rhodium, osmium and iridium, X is sulfur, selenium, tellurium and mixtures thereof and y is a number ranging from about 0.1 to about 3, preferably 0.1 to about 2.5. By the practice of the nonaqueous synthesis technique, Group VIII chalcogenides are prepared which are finely divided, have a high surface area, small particle size and small crystallite size which are also free of excess sulfur, water and/or hydrolysis products. Layered stoichiometric osmium disulfide is prepared by this technique. The precipitates may be cleansed of any anion salt coproduct by any technique common to the art.Compounds of the formula MX.sub.y thus prepared are superior sulfur-tolerant catalysts in catalytic processes, for example, hydrodesulfurization, hydrodenitrogenation, hydroconversion, hydrogenation.
摘要翻译：描述了用于制备元素周期表的钌，铑，锇和铱过渡金属的硫族化物的方法，该方法包括在不存在含水溶剂的情况下混合第VIII族过渡金属盐与硫族化物源，所述硫族化物选自硫，硒，碲及其混合物，得到式MXy的沉淀物，其中M选自钌，铑，锇和铱，X是硫，硒，碲及其混合物 y为约0.1至约3，优选为0.1至约2.5的数。通过非水合成技术的实践，制备了细分的，具有高表面积，小颗粒尺寸和小微晶尺寸的第VIII族硫属化物，其也不含过量的硫，水和/或水解产物。通过该技术制备分层化学计量的二硫化锇。可以通过本领域普通技术将沉淀物清除任何阴离子盐副产物。如此制备的式MXy的化合物是催化方法中优异的耐硫催化剂，例如加氢脱硫，加氢脱氮，加氢转化，氢化。

5. 发明授权

US4528089A Hydrogenation processes using carbon-containing molybdenum and tungsten sulfide catalysts 失效
标题翻译：使用含碳钼和硫化钨催化剂的氢化方法
公开(公告)号：US4528089A
公开(公告)日：1985-07-09
申请号：US552403
申请日：1983-11-16
申请人： Theresa A. Pecoraro , Russell R. Chianelli
发明人： Theresa A. Pecoraro , Russell R. Chianelli
IPC分类号： B01J27/20 , C10G45/04
CPC分类号： B01J27/20 , C10G45/04
摘要： Sulfur and nitrogen-containing hydrocarbon feeds are upgraded by contacting said feed, at elevated temperature and in the presence of hydrogen, with a catalyst comprising a carbon-containing sulfide of a catalytic metal selected from the group consisting of tungsten, molybdenum and mixture thereof. In a preferred embodiment, these catalysts are promoted with certain transition metal sulfides such as cobalt sulfide. The catalyst may be preformed or formed in-situ in the feed or from catalyst precursor salts.
摘要翻译：通过使所述进料在升高的温度和在氢的存在下与包含选自钨，钼及其混合物的催化金属的含碳硫化物的催化剂接触来提高含硫和含氮烃进料。在优选的实施方案中，这些催化剂用某些过渡金属硫化物如硫化钴促进。催化剂可以在原料中或从催化剂前体盐中原位形成或形成。

6. 发明授权

US4508847A Carbon-containing molybdenum and tungsten sulfide catalysts 失效
标题翻译：含碳钼和硫化钨催化剂
公开(公告)号：US4508847A
公开(公告)日：1985-04-02
申请号：US552404
申请日：1983-11-16
申请人： Russell R. Chianelli , Theresa A. Pecoraro
发明人： Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/20 , B01J27/24 , C10G45/04 , B01J21/18 , B01J27/02
CPC分类号： B01J27/20 , B01J27/24 , C10G45/04
摘要： Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200.degree.-600.degree. C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity than conventional catalysts such as cobaltmolybdate on alumina.
摘要翻译：包含钼或钨的含碳硫化物的催化剂通过在硫，氢和烃，氨和铵取代的钼酸盐，硫钼酸盐，钨酸盐和硫代钨酸盐的存在下，在约200-600℃的温度下接触来制备这些催化剂可用于加氢处理反应。在优选的实施方案中，这些催化剂将被某些过渡金属硫化物如硫化钴促进，这导致催化剂比常规催化剂如氧化铝上的钼酸钼具有更大的活性。

7. 发明授权

US4826797A Carbon-containing molybdenum and tungsten sulfide catalysts 失效
标题翻译：含碳钼和硫化钨催化剂
公开(公告)号：US4826797A
公开(公告)日：1989-05-02
申请号：US929013
申请日：1986-11-10
申请人： Russell R. Chianelli , Theresa A. Pecoraro
发明人： Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/20 , B01J27/24 , C10G45/04 , B01J27/049 , B01J27/047 , B01J27/051
CPC分类号： B01J27/24 , B01J27/20 , C10G45/04
摘要： Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200.degree.-600.degree. C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity than conventional catalysts such as cobalt-molybdate on alumina.
摘要翻译：包含钼或钨的含碳硫化物的催化剂通过在硫，氢和烃，氨和铵取代的钼酸盐，硫钼酸盐，钨酸盐和硫代钨酸盐的存在下，在约200-600℃的温度下接触来制备这些催化剂可用于加氢处理反应。在优选的实施方案中，这些催化剂将被某些过渡金属硫化物（例如硫化钴）促进，这导致催化剂比诸如氧化铝上的钼酸钼等常规催化剂具有更大的活性。

8. 发明授权

US4795731A Transition metal sulfide promoted molybdenum or tungsten sulfide catalysts and their uses for hydroprocessing 失效
标题翻译：过渡金属硫化物促进了钼或硫化钨催化剂及其在加氢处理中的应用
公开(公告)号：US4795731A
公开(公告)日：1989-01-03
申请号：US123565
申请日：1987-11-19
申请人： Theresa A. Pecoraro , Allan Jacobson , Russell R. Chianelli
发明人： Theresa A. Pecoraro , Allan Jacobson , Russell R. Chianelli
IPC分类号： B01J27/049 , B01J27/051 , C10G45/08 , B01J27/047 , B01J31/18
CPC分类号： B01J27/0515 , B01J27/049 , C10G45/08
摘要： Hydrocarbon feeds are upgraded by contacting a feed, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst prepared by heating one or more catalyst precursors under oxygen-free conditions in the presence of sulfur at a temperature of at least about 150.degree. C. The catalyst precursors will be one or more compounds of the formula (ML) (Mo.sub.y W.sub.1-y S.sub.4) wherein M comprises one or more divalent promoter metals selected from the group consisting of Ni, Co, Zn, Cu and mixtures thereof, wherein y is any value ranging from 0 to 1 and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating, polydentate ligand.
摘要翻译：通过使进料在升高的温度和在氢的存在下使进料与通过在硫的存在下在无氧条件下加热一种或多种催化剂前体而制备的自促进催化剂来升级烃进料，所述催化剂前体在至少约催化剂前体将是一种或多种式（ML）的化合物（MoyW1-yS4），其中M包含一种或多种选自Ni，Co，Zn，Cu及其混合物的二价助催化剂金属，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体。

9. 发明授权

US4650563A Transition metal sulfide promoted molybdenum or tungsten sulfide catalysts and their uses for hydroprocessing 失效
标题翻译：过渡金属硫化物促进了钼或硫化钨催化剂及其在加氢处理中的应用
公开(公告)号：US4650563A
公开(公告)日：1987-03-17
申请号：US687535
申请日：1984-12-28
申请人： Allan J. Jacobson , Russell R. Chianelli , Theresa A. Pecoraro
发明人： Allan J. Jacobson , Russell R. Chianelli , Theresa A. Pecoraro
IPC分类号： B01J27/04 , B01J27/047 , B01J31/22 , B01J37/20 , C10G45/04 , C10G45/08 , C10G47/12 , C10G49/04 , C10G45/50 , C10G47/06
CPC分类号： B01J27/04 , B01J27/047 , B01J37/20 , C10G45/04 , C10G45/08
摘要： Hydrocarbon feeds are upgraded by contacting a feed, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst prepared by heating one or more catalyst precursors under oxygen-free conditions in the presence of sulfur at a temperature of at least about 150.degree. C. The catalyst precursors will be one or more compounds of the formula (ML)(Mo.sub.y W.sub.1-y S.sub.4) wherein M comprises one or more divalent promoter metals selected from the group consisting of Ni, Co, Zn, Cu and mixtures thereof, wherein y is any value ranging from 0 to 1 and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating, polydentate ligand.
摘要翻译：通过使进料在升高的温度和在氢的存在下使进料与通过在硫的存在下在无氧条件下加热一种或多种催化剂前体而制备的自促进催化剂来升级烃进料，所述催化剂前体在至少约催化剂前体将是一种或多种式（ML）的化合物（MoyW1-yS4），其中M包含一种或多种选自Ni，Co，Zn，Cu及其混合物的二价助催化剂金属，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体。

10. 发明授权

US4323480A Method of preparing di and poly chalcogenides of group IVb, Vb, molybdenum and tungsten transition metals by low temperature precipitation from non-aqueous solution and the product obtained by said method 失效
标题翻译：通过从非水溶液中低温沉淀制备ⅣB，Ⅴb，钼和钨过渡金属的二元和多元硫族化物的方法和通过所述方法获得的产物
公开(公告)号：US4323480A
公开(公告)日：1982-04-06
申请号：US151450
申请日：1980-05-19
申请人： Martin B. Dines , Russell R. Chianelli
发明人： Martin B. Dines , Russell R. Chianelli
IPC分类号： C01B19/00 , C01G1/12 , C01G23/00 , C01G31/00 , H01M4/58 , H01M6/16 , B01J27/02 , C01B17/00 , H01B1/06
CPC分类号： B82Y30/00 , C01B19/007 , C01G1/12 , C01G23/007 , C01G31/00 , H01M4/581 , H01M6/16 , C01P2002/02 , C01P2002/22 , C01P2002/60 , C01P2002/72 , C01P2002/82 , C01P2004/03 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/80 , H01M6/164 , H01M6/166
摘要： Finely divided, high surface area, small crystallite (0.1 micron or less) di- and poly-transition metal chalcogenides are prepared by mixing in the absence of an aqueous solvent a transition metal salt with a source of chalcogen yielding a precipitate. The salt and the chalcogen source can be mixed either neat or in the presence of a nonaqueous solvent. The precipitate which results before removal of the anion salt is a finely divided product.
摘要翻译：通过在不存在水性溶剂的情况下将过渡金属盐与硫原子源混合而制备出细分，高表面积，小微晶（0.1微米或更小）的二 - 和多 - 过渡金属硫族化物。盐和硫族元素源可以整齐地或在非水溶剂的存在下混合。在除去阴离子盐之前产生的沉淀物是细分的产物。

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