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    • 2. 发明授权
    • Adhesive active finish for reinforcing members and related methods
    • 用于加强件的粘合剂活性成分及相关方法
    • US4847360A
    • 1989-07-11
    • US209673
    • 1988-06-21
    • William L. HergenrotherMario N. DeTrano
    • William L. HergenrotherMario N. DeTrano
    • C08J5/06
    • C08J5/06C08J2321/00
    • Adhesive active finish compositions for synthetic reinforcing members to bond the latter to vulcanizable rubber and reinforcing members for vulcanizable rubber. The adhesive composition comprises a water soluble epoxy compound, from about 20 to 100 parts by weight of a trialkanolamine having from 3 to about 15 carbon atoms and from about 0 to 80 parts by weight of a polyol co-curative having from 2 to about 15 carbon atoms and having at least 2 primary hydroxyls per molecule, wherein the stoichiometric ratio of hydroxyl groups to epoxy groups from the water soluble epoxy compound ranges from about 1:0.7 to 1:0.0003. A method of reinforcing articles of vulcanizable rubber with fibrous members includes the steps of applying to the fibrous member a first coating of the adhesive active finish; applying a second coating comprising resorcinol, formaldehyde and a rubber latex over the first coating; embedding the coated fibrous member in the vulcanizable rubber and, vulcanizing the rubber. Synthetic reinforcing yarns containing the adhesive active finish and a method for their production are also disclosed.
    • 用于合成增强构件的粘合剂活性成分组合物将其粘合到可硫化橡胶和用于可硫化橡胶的增强构件。 粘合剂组合物包含水溶性环氧化合物,约20至100重量份的具有3至约15个碳原子的三烷醇胺和约0至80重量份的具有2至约15个碳原子的多元醇共固化剂 碳原子并且每个分子具有至少2个伯羟基,其中来自水溶性环氧化合物的羟基与环氧基的化学计量比范围为约1:0.7至1:0.003。 用纤维构件加固可硫化橡胶制品的方法包括以下步骤:向纤维构件施加粘合剂活性涂饰的第一涂层; 在第一涂层上施加包含间苯二酚,甲醛和橡胶胶乳的第二涂层; 将涂覆的纤维构件嵌入可硫化橡胶中并硫化橡胶。 还公开了含有粘合剂活性涂料的合成增强纱线及其生产方法。
    • 10. 发明申请
    • Amino Alkoxy-Modified Silsesquioxane Adhesives For Improved Metal Adhesion And Metal Adhesion Retention To Cured Rubber
    • 用于改善金属粘附性和固化橡胶金属粘附保持性的氨基烷氧基改性倍半硅氧烷粘合剂
    • US20120077922A1
    • 2012-03-29
    • US13174129
    • 2011-06-30
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • C08K3/08
    • C08K3/08C08G77/26C08K5/544C09J183/08C08L21/00
    • Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.
    • 还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷(氨基AMS)和/或氨基共-MSMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂,用于将线粘附到橡胶原料上。 氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用,并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂,例如但不限于钴,树脂 和高硫含量。 特别地,使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能,以获得足够的粘合,其耐受在时间上的劣化,特别是电阻 热老化和/或热氧化老化,特别是在水存在下的腐蚀。 与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比,含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。