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    • 4. 发明申请
    • Amino Alkoxy-Modified Silsesquioxane Adhesives For Improved Metal Adhesion And Metal Adhesion Retention To Cured Rubber
    • 用于改善金属粘附性和固化橡胶金属粘附保持性的氨基烷氧基改性倍半硅氧烷粘合剂
    • US20120077922A1
    • 2012-03-29
    • US13174129
    • 2011-06-30
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • C08K3/08
    • C08K3/08C08G77/26C08K5/544C09J183/08C08L21/00
    • Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.
    • 还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷(氨基AMS)和/或氨基共-MSMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂,用于将线粘附到橡胶原料上。 氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用,并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂,例如但不限于钴,树脂 和高硫含量。 特别地,使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能,以获得足够的粘合,其耐受在时间上的劣化,特别是电阻 热老化和/或热氧化老化,特别是在水存在下的腐蚀。 与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比,含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。
    • 7. 发明授权
    • Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
    • 氨基烷氧基改性的倍半硅氧烷粘合剂,用于改善金属粘附和金属粘附保持固化橡胶
    • US08642691B2
    • 2014-02-04
    • US13174129
    • 2011-06-30
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • William L. HergenrotherWalter TomaszewskiAshley HiltonMichael HayesJames H. PawlowTerrence E. HoganZhong-Ren Chen
    • C08K3/08B60C1/00
    • C08K3/08C08G77/26C08K5/544C09J183/08C08L21/00
    • Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.
    • 还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷(氨基AMS)和/或氨基辅AMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂,用于将线粘附到橡胶原料上。 氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用,并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂,例如但不限于钴,树脂 和高硫含量。 特别地,使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能,以获得足够的粘合,其耐受在时间上的劣化,特别是电阻 热老化和/或热氧化老化,特别是在水存在下的腐蚀。 与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比,含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。