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1. 发明授权

US5218083A Polyimides prepared from 3,5-diaminobenzotrifluoride 失效
标题翻译：由3,5-二氨基三氟甲苯制备的聚酰亚胺
公开(公告)号：US5218083A
公开(公告)日：1993-06-08
申请号：US429574
申请日：1989-10-31
申请人： Margaret K. Gerber , Terry L. St. Clair , J. Richard Pratt , Anne K. St. Clair
发明人： Margaret K. Gerber , Terry L. St. Clair , J. Richard Pratt , Anne K. St. Clair
IPC分类号： C08G73/10
CPC分类号： C08G73/1085 , C08G73/1039 , C08G73/106 , C08G73/1064
摘要： High performance, thermooxidatively stable polyimides are prepared by reacting aromatic diamines with pendant trifluoromethyl groups and dianhydrides in an amide solvent to form a poly(amic acid), followed by cyclizing the poly(amic acid) to form the corresponding polyimide, which has the following general structure: ##STR1##
摘要翻译：通过使芳族二胺与侧基三氟甲基和二酐在酰胺溶剂中反应形成聚（酰胺酸）制备高性能，热氧化稳定的聚酰亚胺，然后使聚（酰胺酸）环化形成相应的聚酰亚胺，其具有以下一般结构：其中R是任何芳族或取代的芳族基团，Ar是任何芳族或取代的芳族基团，n APPROX 10-100。

2. 发明授权

US5093453A Aromatic polyimides containing a dimethylsilane-linked dianhydride 失效
标题翻译：含有二甲基硅烷的二酐的芳族聚酰亚胺
公开(公告)号：US5093453A
公开(公告)日：1992-03-03
申请号：US449210
申请日：1989-12-12
申请人： Anne K. St. Clair , Terry L. St. Clair , J. Richard Pratt
发明人： Anne K. St. Clair , Terry L. St. Clair , J. Richard Pratt
IPC分类号： C08G73/10
CPC分类号： C08G73/106
摘要： A high-temperature stable, optically transparent, low dielectric aromatic polyimide is prepared by chemically combining equimolar quantities of an aromatic dianhydride reactant and an aromatic diamine reactant, which are selected so that one reactant contains at least one Si(CH.sub.3).sub.2 group in its molecular structure, and the other reactant contains at least one --CH.sub.3 group in its molecular structure. The reactants are chemically combined in a solvent medium to form a solution of a high molecular weight polyamic acid, which is then converted to the corresponding polyimide.
摘要翻译：通过化学组合等摩尔量的芳族二酐反应物和芳族二胺反应物来制备高温稳定的光学透明低介电芳族聚酰亚胺，其选择为使得一种反应物在其中含有至少一个Si（CH 3）2基团分子结构，另一反应物在其分子结构中含有至少一个-CH 3基团。将反应物在溶剂介质中化学组合以形成高分子量聚酰胺酸的溶液，然后将其转化为相应的聚酰亚胺。

3. 发明授权

US5428102A Low dielectric polyimides 失效
标题翻译：低介电聚酰亚胺
公开(公告)号：US5428102A
公开(公告)日：1995-06-27
申请号：US237712
申请日：1994-05-02
申请人： Anne K. St. Clair , Terry L. St. Clair , William P. Winfree
发明人： Anne K. St. Clair , Terry L. St. Clair , William P. Winfree
IPC分类号： C08G73/10 , C08L79/08
CPC分类号： C08G73/1007
摘要： A series of polyimides based on the dianhydride of 1,4-bis(3,4-dicarboxyphenoxy)benzene (HQDEA) or on 2,2-bis[4(3-aminophenoxy)phenyl]hexafluoropropane (3-BDAF) are evolved from high molecular weight polyamic acid solutions yielding flexible free-standing films and coatings in the fully imidized form which have a dielectric constant in the range of 2.5 to 3.1 at 10 GHz.
摘要翻译：一系列基于1,4-双（3,4-二羧基苯氧基）苯（HQDEA）二酐或2,2-双[4-（3-氨基苯氧基）苯基]六氟丙烷（3-BDAF）的二酰亚胺衍生自高分子量聚酰胺酸溶液产生柔性自立膜和完全酰亚胺化形式的涂层，其在10GHz下的介电常数范围为2.5至3.1。

4. 发明授权

US5338826A Structures from low dielectric polyimides 失效
标题翻译：低介电聚酰亚胺的结构
公开(公告)号：US5338826A
公开(公告)日：1994-08-16
申请号：US954108
申请日：1992-09-28
申请人： Anne K. St. Clair , Terry L. St. Clair , William P. Winfree
发明人： Anne K. St. Clair , Terry L. St. Clair , William P. Winfree
IPC分类号： C08G73/10 , B05D5/06 , B32B27/00
CPC分类号： C08G73/1007 , Y10T428/31681 , Y10T428/31721
摘要： A structure which is effective as an electrical insulator or as a transmitter-receiver of electromagnetic energy is prepared by providing a suitable substrate and covering the substrate with an adhering layer of a low dielectric, high temperature, linear aromatic polyimide. This polyimide is prepared by:(1) selecting aromatic diamine and aromatic dianhydride reactants to meet at least two of the following three conditions:(a) a reactant must have minimal permanent or inducible electrical dipolar characteristics as a result of the presence of pendant or bridging groups therein;(b) a reactant must impart a high degree of free volume to the polymer caused by inefficient chain packing therein in the solid state as a result of the presence of pendant or bridging groups therein; and(c) a reactant must have fluorine atoms chemically attached thereto; and(2) chemically combining equimolar quantities of the aromatic diamine and aromatic dianhydride reactants in a solvent to form a high molecular weight polyamic acid solution, and converting the high molecular weight polyamic acid to the corresponding low dielectric, high temperature linear aromatic polyimide.
摘要翻译：作为电绝缘体或作为电磁能的发射器 - 接收器有效的结构通过提供合适的衬底并用低电介质，高温线性芳族聚酰亚胺的粘附层覆盖衬底来制备。该聚酰亚胺通过以下方法制备：（1）选择芳族二胺和芳族二酐反应物以满足以下三个条件中的至少两个：（a）反应物必须具有最小的永久或可诱导的电偶极特性，这是由于存在侧基或桥接基团; （b）由于在其中存在侧基或桥连基团，反应物必须赋予聚合物在固态中由于无效的链填料而导致的高度的自由体积; 和（c）反应物必须具有化学连接的氟原子; 和（2）将等摩尔量的芳族二胺和芳族二酐反应物在溶剂中化学组合以形成高分子量聚酰胺酸溶液，并将高分子量聚酰胺酸转化为相应的低电介质，高温线性芳族聚酰亚胺。

5. 发明授权

US4543295A High temperature polyimide film laminates and process for preparation thereof 失效
标题翻译：高温聚酰亚胺薄膜层压板及其制备方法
公开(公告)号：US4543295A
公开(公告)日：1985-09-24
申请号：US663840
申请日：1984-10-24
申请人： Anne K. St. Clair , Terry L. St. Clair
发明人： Anne K. St. Clair , Terry L. St. Clair
IPC分类号： B32B27/34 , H05K1/00 , H05K3/38 , B32B15/08
CPC分类号： H05K3/386 , B32B27/34 , H05K1/0393 , H05K2201/0154 , H05K2201/0355 , H05K2203/0759 , Y10T428/31681 , Y10T428/31721
摘要： High temperature polyimide film laminates and a process for fabricating large-area, void-free polyimide laminate structures wherein multiple-ply polyimide film laminates may be constructed without decreasing the individual film strength and wherein layers of metal foil may be laminated between polyimide film layers to yield a flexible high temperature resistant structure having capabilities for use as flexible electric circuits, in aerospace applications, and the like.
摘要翻译：高温聚酰亚胺薄膜层压板和制造大面积无空隙的聚酰亚胺层压结构体的方法，其中可以构造多层聚酰亚胺薄膜叠层体而不降低单独的薄膜强度，并且其中金属箔层可以层压在聚酰亚胺薄膜层之间产生具有用作柔性电路，航空航天应用等的能力的柔性耐高温结构。

6. 发明授权

US4497935A Elastomer toughened polyimide adhesives 失效
标题翻译：弹性体强化聚酰亚胺粘合剂
公开(公告)号：US4497935A
公开(公告)日：1985-02-05
申请号：US461788
申请日：1983-01-28
申请人： Anne K. St. Clair , Terry L. St. Clair
发明人： Anne K. St. Clair , Terry L. St. Clair
IPC分类号： C08G73/10 , C08G73/12 , C08L79/08 , C08F283/04 , C08F283/12 , C08G77/32
CPC分类号： C08G73/122 , C08G73/1003 , C08G73/101 , C08G73/1028 , C08L79/08
摘要： A rubber-toughened addition-type polyimide composition having excellent high temperature bonding characteristics in the fully cured state and improved peel strength and adhesive fracture resistance physical property characteristics is disclosed. The process for making the improved adhesive involves preparing the rubber-containing amic acid prepolymer by chemically reacting an amine-terminated elastomer and an aromatic diamine with an aromatic dianhydride with which a reactive chain stopper anhydride has been mixed, and utilizing solvent or mixture of solvents for the reaction.
摘要翻译：公开了一种在完全固化状态下具有优异的高温粘合特性并提高剥离强度和耐粘连断裂性物理特性的橡胶增韧加成型聚酰亚胺组合物。制造改进的粘合剂的方法包括通过使胺封端的弹性体和芳族二胺与已经混合反应性链终止酐的芳族二酐化学反应并使用溶剂或溶剂混合物来制备含橡胶的酰胺酸预聚物为了反应。

7. 发明授权

US4389504A Elastomer toughened polyimide adhesives 失效
公开(公告)号：US4389504A
公开(公告)日：1983-06-21
申请号：US308201
申请日：1981-10-02
申请人： Anne K. St. Clair , Terry L. St. Clair
发明人： Anne K. St. Clair , Terry L. St. Clair
IPC分类号： C08G73/10 , C08G73/12 , C08L79/08 , C08K5/20
CPC分类号： C08G73/1003 , C08G73/101 , C08G73/1028 , C08G73/122 , C08L79/08
摘要： A rubber-toughened addition-type polyimide composition having excellent high temperature bonding characteristics in the fully cured state and improved peel strength and adhesive fracture resistance physical property characteristics is disclosed. The process for making the improved adhesive involves preparing the rubber-containing amic acid prepolymer by chemically reacting an amine-terminated elastomer and an aromatic diamine with an aromatic dianhydride with which a reactive chain stopper anhydride has been mixed, and utilizing solvent or mixture of solvents for the reaction.

8. 发明授权

US4284461A Aluminum ion-containing polyimide adhesives 失效
标题翻译：含铝离子的聚酰亚胺粘合剂
公开(公告)号：US4284461A
公开(公告)日：1981-08-18
申请号：US92142
申请日：1979-11-07
申请人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch , Anne K. St. Clair , Larry T. Taylor , Terry L. St. Clair
发明人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch , Anne K. St. Clair , Larry T. Taylor , Terry L. St. Clair
IPC分类号： C08K5/00 , H05K3/38 , C08G69/28
CPC分类号： C08K5/0091 , H05K3/386
摘要： A method for preparing an aluminum ion-filled polyimide adhesive wherein a meta-oriented aromatic diamine is reacted with an aromatic dianhydride and an aluminum compound in the presence of a water or lower alkanol miscible ether solvent to produce an intermediate polyamic acid; and thereafter converting the polyamic acid to the thermally stable, metal ion-filled polyimide by heating in the temperature range of 300.degree. C. to produce a flexible, high temperature adhesive.
摘要翻译：一种制备铝离子填充的聚酰亚胺粘合剂的方法，其中将间位取向的芳族二胺与芳族二酐和铝化合物在水或低级链烷醇可混溶的醚溶剂的存在下反应以产生中间体聚酰胺酸; 然后通过在300℃的温度范围内加热将聚酰胺酸转化成热稳定的金属离子填充的聚酰亚胺，以产生柔性的高温粘合剂。

9. 发明授权

US5220070A 1,3-diamino-5-pentafluorosulfanylbenzene 失效
标题翻译： 1,3-二氨基-5-五氟硫烷基苯
公开(公告)号：US5220070A
公开(公告)日：1993-06-15
申请号：US755207
申请日：1991-09-05
申请人： Terry L. St. Clair , Anne K. St. Clair , Joseph S. Thrasher
发明人： Terry L. St. Clair , Anne K. St. Clair , Joseph S. Thrasher
IPC分类号： B01D71/46 , B01D71/56 , B01D71/64 , C07C381/00 , C08G59/50 , C08G73/10 , H01B3/30 , H01B3/40
CPC分类号： B01D71/46 , B01D71/56 , B01D71/64 , C07C381/00 , C08G59/5033 , C08G59/504 , C08G73/10 , C08G73/1064 , C08G73/1067 , C08G73/1071 , H01B3/306 , H01B3/40 , Y10T428/31721
摘要： A process was developed to prepare 1,3-diamino-5-pentafluorosulfanylbenzene. This process involved two steps: preparing the dinitro compound, 1,3-dinitro-5-pentafluorosulfanylbenzene, and reducing this compound to form the corresponding diamine. This diamine was reacted with various dianhydrides, diacidchlorides, and epoxy resins to form polyimides, polyamides, and crosslinked epoxies. These polymers were used to prepare semi-permeable membranes, wire coatings, and films.
摘要翻译：开发了制备1,3-二氨基-5-五氟硫烷基苯的方法。该方法包括两步：制备二硝基化合物，1,3-二硝基-5-五氟硫烷基苯，还原该化合物以形成相应的二胺。该二胺与各种二酐，二酰氯和环氧树脂反应形成聚酰亚胺，聚酰胺和交联环氧树脂。这些聚合物用于制备半透膜，电线涂层和膜。

10. 发明授权

US4603061A Process for preparing highly optically transparent/colorless aromatic polyimide film 失效
标题翻译：高光学透明/无色芳族聚酰亚胺薄膜的制备方法
公开(公告)号：US4603061A
公开(公告)日：1986-07-29
申请号：US643589
申请日：1984-08-23
申请人： Anne K. St. Clair , Terry L. St. Clair
发明人： Anne K. St. Clair , Terry L. St. Clair
IPC分类号： C08J5/18 , B05D5/06 , B32B27/00
CPC分类号： C08J5/18 , C08J2379/08 , Y10T428/265 , Y10T428/31721
摘要： An aromatic condensation polyimide film that is approximately 90% transparent at 500 nm, useful for thermal protective coatings and the like and the process for preparing same are disclosed. An essential feature of the invention for achieving maximum optical transparency films requires utilizing recrystallized and/or sublimated specific aromatic diamines and dianhydride monomers and introducing bulky electron-withdrawing groups and separator groups into the polymer molecular structure. The incorporation of bulky electron-withdrawing groups in the diamine portion of the polymer structure serves to reduce the formation of inter-chain and intra-chain charge transfer complexes which normally cause large absorptions in the UV-visible range. Incorporation of separator atoms into either the diamine or dianhydride monomers serves to reduce the amount of conjugation and inter-and intra-chain electronic interactions and thereby lessen charge transfer complex formation.
摘要翻译：公开了一种在500nm下约为90％透明度的用于热保护涂层等的芳族缩合聚酰亚胺膜及其制备方法。实现最大光学透明膜的本发明的一个基本特征需要使用重结晶和/或升华的特定芳族二胺和二酐单体，并将大体积的吸电子基团和隔离剂基团引入到聚合物分子结构中。在聚合物结构的二胺部分中引入大体积的吸电子基团用于减少通常在UV-可见光范围内引起大吸收的链间和链内电荷转移络合物的形成。将分离器原子并入二胺或二酐单体中用于减少共轭量和链内和链内电子相互作用的量，从而减少电荷转移络合物的形成。

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