专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

US20120071690A1 PRODUCTION OF FORMAMIDES 审中-公开
标题翻译：生产生物
公开(公告)号：US20120071690A1
公开(公告)日：2012-03-22
申请号：US13234549
申请日：2011-09-16
申请人： Marek Pazicky , Thomas Schaub , Ansgar Gereon Altenhoff , Donata Maria Fries , Rocco Paciello
发明人： Marek Pazicky , Thomas Schaub , Ansgar Gereon Altenhoff , Donata Maria Fries , Rocco Paciello
IPC分类号： C07C231/10
CPC分类号： C07C231/02 , C07C233/03
摘要： A process is proposed for production of formamides by reaction of carbon dioxide with hydrogen in a hydrogenation reactor I in the presence of a catalyst comprising an element from group 8, 9 or 10 of the periodic table, a tertiary amine comprising at least 6 carbon atoms per molecule, and also a polar solvent, to form formic acid-amine adducts as intermediates, which are subsequently reacted with ammonia or amines in a reactor to obtain a two-phase liquid reaction effluent from which the liquid phase enriched with the formamides is distillatively separated to recover the formamide.
摘要翻译：提出了在含有元素周期表第8,9或10族的元素的催化剂存在下，在氢化反应器I中使二氧化碳与氢气反应制备甲酰胺的方法，包含至少6个碳原子的叔胺每分子以及极性溶剂，以形成作为中间体的甲酸 - 胺加合物，随后在反应器中与氨或胺反应以获得两相液体反应流出物，富含甲酰胺的液相从中蒸馏出分离以回收甲酰胺。

2. 发明申请

US20120022290A1 Process for Preparing Formic Acid by Reaction of Carbon Dioxide with Hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US20120022290A1
公开(公告)日：2012-01-26
申请号：US13171928
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15
CPC分类号： C07C51/44 , C07C51/15 , C07C51/48 , C07C53/02
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output (3) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase (4) and the lower phase.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子的极性溶剂和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中后处理通过加入水进行加氢反应器（I）的输出（3），以增加催化剂在上相（4）和下相之间的分配系数。

3. 发明授权

US08877965B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08877965B2
公开(公告)日：2014-11-04
申请号：US13171928
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15 , C07F15/00 , C07C53/00 , C07C51/44 , C07C51/48
CPC分类号： C07C51/44 , C07C51/15 , C07C51/48 , C07C53/02
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output (3) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase (4) and the lower phase.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子的极性溶剂和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中后处理通过加入水进行加氢反应器（I）的输出（3），以增加催化剂在上相（4）和下相之间的分配系数。

4. 发明授权

US08791297B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08791297B2
公开(公告)日：2014-07-29
申请号：US13172123
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/44 , C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
CPC分类号： C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output (3) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream (13) from the work-up is used as selective solvent for the catalyst, is proposed.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子，以及包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和极性溶剂的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，具有后处理提出了在多个工艺步骤中，来自加氢反应器（I）的输出物（3）的来自后处理的含叔胺的物流（13）用作催化剂的选择性溶剂。

5. 发明申请

US20130012739A1 PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20130012739A1
公开(公告)日：2013-01-10
申请号：US13542791
申请日：2012-07-06
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
IPC分类号： C07C51/15
CPC分类号： C07C51/44 , C07C51/48 , C07C51/487 , C07C53/02
摘要： A process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.
摘要翻译：在含有元素周期表第8,9或10族元素的催化剂存在下，在氢化反应器中使二氧化碳与氢反应制备甲酸的方法，叔胺和极性溶剂以形成甲酸 - 胺加成物随后被热分解成甲酸和叔胺。

6. 发明申请

US20120157711A1 PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20120157711A1
公开(公告)日：2012-06-21
申请号：US13330974
申请日：2011-12-20
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Petra Deckert , Peter Bassler
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Petra Deckert , Peter Bassler
IPC分类号： C07C53/02
CPC分类号： C07C51/412 , C07C51/02 , C07C51/41 , C07C51/44 , C07C51/48 , C07C53/02 , C07C53/06
摘要： The present invention relates to a process for preparing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where a tertiary amine having a boiling point which is at least 5° C. higher than that of formic acid is used and a reaction mixture comprising the polar solvent, the formic acid/amine adducts, the tertiary amine and the catalyst is formed in the reaction in the hydrogenation reactor (I) and is discharged from the reactor as output (3).
摘要翻译：本发明涉及一种通过使二氧化碳（1）与氢（2）在氢化反应器（I）中在含有周期表第8,9或10族元素的催化剂存在下反应来制备甲酸的方法，每分子含有至少12个碳原子的叔胺和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中第三使用沸点比甲酸高至少5℃的胺，并且在反应中形成包含极性溶剂，甲酸/胺加合物，叔胺和催化剂的反应混合物氢化反应器（I），并作为输出（3）从反应器排出。

7. 发明申请

US20110319658A1 PROCESS FOR PREPARING FORMIC ACID BY REACTION OF CARBON DIOXIDE WITH HYDROGEN 有权
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20110319658A1
公开(公告)日：2011-12-29
申请号：US13172123
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15
CPC分类号： C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output (3) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream (13) from the work-up is used as selective solvent for the catalyst, is proposed.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子，以及包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和极性溶剂的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，具有后处理提出了在多个工艺步骤中，来自加氢反应器（I）的输出物（3）的来自后处理的含叔胺的物流（13）用作催化剂的选择性溶剂。

8. 发明授权

US08703994B2 Process for preparing formamides and formic esters 失效
标题翻译：甲酰胺和甲酸酯的制备方法
公开(公告)号：US08703994B2
公开(公告)日：2014-04-22
申请号：US13559011
申请日：2012-07-26
申请人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
发明人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
IPC分类号： C07C69/02 , C07C67/00 , C07C233/00
CPC分类号： C07C231/10 , C07C67/36 , C07C233/03 , C07C69/06
摘要： A process for preparing carboxylic acid derivatives of the formula H—(C═O)—R, R is OR1 or NR2R3, R1 is optionally substituted C1-C15-alkyl, C5-C10-cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are C1-C15-alkyl, C1-C6-alkoxy, C5-C10-cycloalkyl or C5-C10-aryl; R2 and R3 are independently hydrogen or optionally substituted C1-C15-alkyl, C5-C10 cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are selected from the group consisting of C1-C15-alkyl, C5-C10-cycloalkyl and C5-C10-aryl or R2 and R3 together with the nitrogen atom form a five- or six-membered ring which optionally comprises one or more heteroatoms selected from O, S and N and bearing the substituent R4, R4 is hydrogen or C1-C6-alkyl; by reacting a reaction mixture comprising carbon dioxide, hydrogen and an alcohol of the formula R1—OH or an amine of the formula NHR2R3 in the presence of a catalyst comprising gold at a pressure from 0.2 to 30 MPa and a temperature from 20 to 200° C. in a hydrogenation reactor.
摘要翻译：制备式H-（C = O）-R的羧酸衍生物的方法，R是OR 1或NR 2 R 3，R 1是任选取代的C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基，C 5 -C 10 - 杂环基， C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基是C 1 -C 15 - 烷基，C 1 -C 6 - 烷氧基，C 5 -C 10 - 环烷基或C 5 -C 10 - 芳基; R 2和R 3独立地为氢或任选取代的C 1 -C 15 - 烷基，C 5 -C 10环烷基，C 5 -C 10 - 杂环基，C 5 -C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基选自C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基和C 5 -C 10 - 芳基或R 2和R 3与氮原子一起形成五元或六元环，其任选地包含一个或多个选自O，S和N的杂原子并带有取代基R4 R4是氢或C1-C6-烷基; 在包含金的催化剂的存在下，在0.2〜30MPa的压力和20〜200℃的温度下，使包含二氧化碳，氢气和式R 1 -OH的醇或式NHR 2 R 3的胺的反应混合物反应， C.在氢化反应器中。

9. 发明申请

US20130102807A1 PROCESS FOR PREPARING FORMAMIDES AND FORMIC ESTERS 失效
标题翻译：制备形式和形式的方法
公开(公告)号：US20130102807A1
公开(公告)日：2013-04-25
申请号：US13559011
申请日：2012-07-26
申请人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
发明人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
IPC分类号： C07C231/10 , C07C67/36
CPC分类号： C07C231/10 , C07C67/36 , C07C233/03 , C07C69/06
摘要： A process for preparing carboxylic acid derivatives of the formula H—(C═O)—R, R is OR1 or NR2R3, R1 is optionally substituted C1-C15-alkyl, C5-C10-cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are C1-C15-alkyl, C1-C6-alkoxy, C5-C10-cycloalkyl or C5-C10-aryl; R2 and R3 are independently hydrogen or optionally substituted C1-C15-alkyl, C5-C10 cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are selected from the group consisting of C1-C15-alkyl, C5-C10-cycloalkyl and C5-C10-aryl or R2 and R3 together with the nitrogen atom form a five- or six-membered ring which optionally comprises one or more heteroatoms selected from O, S and N and bearing the substituent R4, R4 is hydrogen or C1-C6-alkyl; by reacting a reaction mixture comprising carbon dioxide, hydrogen and an alcohol of the formula R1—OH or an amine of the formula NHR2R3 in the presence of a catalyst comprising gold at a pressure from 0.2 to 30 MPa and a temperature from 20 to 200° C. in a hydrogenation reactor.
摘要翻译：制备式H-（C = O）-R，R的羧酸衍生物的方法是OR 1或NR 2 R 3，R 1是任选取代的C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基，C 5 -C 10 - 杂环基， C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基是C 1 -C 15 - 烷基，C 1 -C 6 - 烷氧基，C 5 -C 10 - 环烷基或C 5 -C 10 - 芳基; R 2和R 3独立地为氢或任选取代的C 1 -C 15 - 烷基，C 5 -C 10环烷基，C 5 -C 10 - 杂环基，C 5 -C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基选自C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基和C 5 -C 10 - 芳基或R 2和R 3与氮原子一起形成五元或六元环，其任选地包含一个或多个选自O，S和N的杂原子并带有取代基R4 R4是氢或C1-C6-烷基; 在包含金的催化剂的存在下，在0.2〜30MPa的压力和20〜200℃的温度下，使包含二氧化碳，氢和式R 1 -OH的醇或式NHR 2 R 3的胺的反应混合物反应， C.在氢化反应器中。

10. 发明申请

US20130090496A1 PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20130090496A1
公开(公告)日：2013-04-11
申请号：US13646161
申请日：2012-10-05
申请人： Thomas Schaub , Oliver Bey , Anton Meier , Donata Maria Fries , Randolf Hugo
发明人： Thomas Schaub , Oliver Bey , Anton Meier , Donata Maria Fries , Randolf Hugo
IPC分类号： C07C51/15
CPC分类号： C07C51/02 , C07C51/41 , C07C53/06 , C07C53/02
摘要： The invention relates to a process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.
摘要翻译：本发明涉及在含有元素周期表第8,9或10族元素，叔胺和极性溶剂的催化剂存在下，在氢化反应器中使二氧化碳与氢反应制备甲酸的方法，以形成随后将甲酸 - 胺加合物热分解成甲酸和叔胺。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式