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1. 发明授权

US07547795B2 Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof 有权
标题翻译：含银催化剂，这种含银催化剂的制造及其用途
公开(公告)号：US07547795B2
公开(公告)日：2009-06-16
申请号：US11775100
申请日：2007-07-09
申请人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates , Paul Michael McAllister
发明人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates , Paul Michael McAllister
IPC分类号： C07D303/00 , C07D301/10 , C07D301/03 , B01J23/50
CPC分类号： B01J23/58 , B01J23/50 , B01J23/63 , B01J23/683 , B01J23/688 , B01J35/02 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J37/0203 , B01J37/0213 , C07D301/10
摘要： A high activity and high selectivity silver catalyst comprising silver and, optionally, one or more promoters supported on a suitable support material having the form of a shaped agglomerate. The structure of the shaped agglomerate is that of a hollow cylinder having a relatively small inside (bore) diameter. The catalyst is made by providing the shaped material of a particular geometry and incorporating the catalytic components therein. The catalyst is useful in the epoxidation of ethylene.
摘要翻译：一种高活性和高选择性的银催化剂，其包含银和任选的一种或多种支持在具有成形附聚物形式的合适载体材料上的助催化剂。成形附聚物的结构是具有相对较小的内径（孔）直径的中空圆柱体的结构。催化剂通过提供具有特定几何形状的成形材料并将其中的催化组分并入而制成。该催化剂可用于乙烯的环氧化。

2. 发明授权

US09346774B2 Process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine 有权
标题翻译：环氧化方法启动方法，生产环氧乙烷的方法，1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺
公开(公告)号：US09346774B2
公开(公告)日：2016-05-24
申请号：US12437172
申请日：2009-05-07
申请人： Marek Matusz , Paul Michael McAllister
发明人： Marek Matusz , Paul Michael McAllister
IPC分类号： C07D301/03 , C07D301/10
CPC分类号： C07D301/10 , Y02P20/142 , Y02P20/52
摘要： A process is provided for the start-up of an ethylene epoxidation process comprising: (a) contacting a catalyst bed comprising a high selectivity epoxidation catalyst with a feed comprising ethylene, oxygen and an organic chloride for a period of time until an increase of at least 1×10−5 mole-% of vinyl chloride (calculated as the moles of vinyl chloride relative to the total gas mixture), preferably 2×10−5 mole-% of vinyl chloride is detected in a reactor outlet gas or a recycle gas loop; and (b) subsequently adjusting the quantity of organic chloride in the feed to a value sufficient to produce ethylene oxide at a substantially optimum selectivity.
摘要翻译：提供了一种启动乙烯环氧化方法的方法，包括：（a）将包含高选择性环氧化催化剂的催化剂床与包含乙烯，氧气和有机氯化物的进料接触一段时间，直到增加在反应器出口气体或回收物中检测到最少1×10-5摩尔％的氯乙烯（以氯乙烯相对于总气体混合物的摩尔计算），优选2×10-5摩尔％的氯乙烯气回路和（b）随后将进料中的有机氯化物的量调节至足以以基本上最佳选择性产生环氧乙烷的值。

3. 发明授权

US08742147B2 Process for improving the selectivity of an EO catalyst 有权
标题翻译：提高EO催化剂选择性的方法
公开(公告)号：US08742147B2
公开(公告)日：2014-06-03
申请号：US13310273
申请日：2011-12-02
申请人： Wayne Errol Evans , Marek Matusz , Paul Michael McAllister
发明人： Wayne Errol Evans , Marek Matusz , Paul Michael McAllister
IPC分类号： C07D301/03 , C07C43/00 , C07C31/18 , C07C29/03
CPC分类号： C07D303/04 , Y02P20/142
摘要： The present invention relates to a process for improving the overall selectivity of an EO process for converting ethylene to ethylene oxide utilizing a highly selective EO silver catalyst containing a rhenium promoter wherein following normal operation a chloride strip of the chloride on the surface of the catalyst is conducted in order to remove a portion of the chlorides on the surface of the catalyst. The chloride strip involves the addition of certain saturated hydrocarbons to the feed. Following the chloride strip, the catalyst is optionally re-optimized.
摘要翻译：本发明涉及使用含有铼助催化剂的高度选择性的EO银催化剂来改善EO转化为环氧乙烷的EO方法的总体选择性的方法，其中在正常操作之后，催化剂表面上氯化物的氯化物条是进行以除去催化剂表面上的一部分氯化物。氯化物条包括向进料中加入某些饱和烃。在氯化带之后，任选地重新优化催化剂。

4. 发明授权

US10532989B2 Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine 有权
公开(公告)号：US10532989B2
公开(公告)日：2020-01-14
申请号：US12116905
申请日：2008-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07D301/10 , C07C213/04 , B01J23/68 , B01J27/188 , C07C68/04 , B01J23/00 , C07C29/10 , B01J27/055
摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst;the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; andthe total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 3.8 mmole/kg, relative to the weight of the catalyst;a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

5. 发明授权

US09527787B2 Process for the preparation of alkylene carbonate and/or alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和/或亚烷基二醇的方法
公开(公告)号：US09527787B2
公开(公告)日：2016-12-27
申请号：US13462490
申请日：2012-05-02
申请人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
发明人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
IPC分类号： B01J19/00 , C07C29/12 , B01D53/02 , B01D53/70 , C07C29/10
CPC分类号： C07C29/12 , B01D53/02 , B01D53/70 , B01D2253/112 , B01D2255/104 , B01D2257/2068 , C07C29/106 , Y02P20/154 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

6. 发明授权

US08937031B2 Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide 有权
标题翻译：环氧化催化剂，制备催化剂的方法以及生产烯烃氧化物的方法
公开(公告)号：US08937031B2
公开(公告)日：2015-01-20
申请号：US13581641
申请日：2011-02-24
申请人： John Robert Lockemeyer , Marek Matusz , Randall Clayton Yeates
发明人： John Robert Lockemeyer , Marek Matusz , Randall Clayton Yeates
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J27/047 , C07C213/04 , B01J27/051 , B01J27/188 , B01J27/19 , B01J35/10 , B01J37/02 , C07D301/10
CPC分类号： B01J27/051 , B01J27/047 , B01J27/188 , B01J27/19 , B01J35/108 , B01J35/1095 , B01J37/0201 , C07C213/04 , C07D301/10 , Y02P20/142 , C07C215/08
摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 μm, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 μm, and a water absorption of 10-80%.
摘要翻译：一种用于环氧化包含载体并在其上沉积有银，铼助催化剂，第一共助催化剂和第二共助催化剂的烯烃的催化剂; 其中沉积在载体上的铼助催化剂的量相对于催化剂的重量大于1mmol / kg; 第一共助催化剂选自硫，磷，硼及其混合物; 第二共助催化剂选自钨，钼，铬及其混合物; 沉积在载体上的第一助催化剂和第二助催化剂的总量相对于催化剂的重量为至多5.0mmol / kg; 并且其中所述载体具有单峰，双峰或多峰孔径分布，孔径为0.01-200μm，比表面积为0.03-10m 2 / g，孔体积为0.2-0.7cm 3 / g，其中中值孔径为0.1〜100μm，吸水率为10-80％。

7. 发明授权

US08921586B2 Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine 有权
标题翻译：制备烯烃氧化物，1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法
公开(公告)号：US08921586B2
公开(公告)日：2014-12-30
申请号：US12437258
申请日：2009-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07D301/10
CPC分类号： C07D301/10
摘要： A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, and a potassium promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the potassium promoter is deposited on the carrier in a quantity of at least 0.5 mmole/kg, relative to the weight of the catalyst; and the carrier contains water leachable potassium in a quantity of less than 55 parts per million by weight, relative to the weight of the carrier; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
摘要翻译：一种烯烃的环氧化方法，包括使包含烯烃，氧和二氧化碳的反应器进料与包含载体的催化剂接触，并沉积在载体上，银，铼促进剂和钾促进剂; 其中基于总环氧化反应器进料，二氧化碳以至多3摩尔％的量存在于反应器进料中; 相对于催化剂的重量，钾促进剂以至少0.5mmol / kg的量沉积在载体上; 载体含有相对于载体重量小于55重量份的水可浸出钾; 制备1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法。

8. 发明申请

US20090281345A1 PROCESS FOR THE PRODUCTION OF AN OLEFIN OXIDE, A 1,2-DIOL, A 1,2-DIOL ETHER, A 1,2-CARBONATE, OR AN ALKANOLAMINE 有权
标题翻译：生产氧化烯，1,2-二醇，1,2-二醇醚，1,2-二碳酸酯或烷醇胺的方法
公开(公告)号：US20090281345A1
公开(公告)日：2009-11-12
申请号：US12437258
申请日：2009-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07C29/48 , C07C69/96 , C07C41/02 , C07C209/68
CPC分类号： C07D301/10
摘要： A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, and a potassium promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the potassium promoter is deposited on the carrier in a quantity of at least 0.5 mmole/kg, relative to the weight of the catalyst; and the carrier contains water leachable potassium in a quantity of less than 55 parts per million by weight, relative to the weight of the carrier; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
摘要翻译：一种烯烃的环氧化方法，包括使包含烯烃，氧和二氧化碳的反应器进料与包含载体的催化剂接触，并沉积在载体上，银，铼促进剂和钾促进剂; 其中基于总环氧化反应器进料，二氧化碳以至多3摩尔％的量存在于反应器进料中; 相对于催化剂的重量，钾促进剂以至少0.5mmol / kg的量沉积在载体上; 载体含有相对于载体重量小于55重量份的水可浸出钾; 制备1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法。

9. 发明申请

US20090275764A1 OLEFIN EPOXIDATION PROCESS, A CATALYST FOR USE IN THE PROCESS, A CARRIER FOR USE IN PREPARING THE CATALYST, AND A PROCESS FOR PREPARING THE CARRIER 有权
标题翻译：烯烃环氧化方法，在该方法中使用的催化剂，用于制备催化剂的载体和用于制备载体的方法
公开(公告)号：US20090275764A1
公开(公告)日：2009-11-05
申请号：US12502850
申请日：2009-07-14
申请人： Randall Clayton YEATES , John Robert Lockemeyer , Marek Matusz
发明人： Randall Clayton YEATES , John Robert Lockemeyer , Marek Matusz
IPC分类号： C07D301/03 , B01J23/10 , C07C41/02 , C07C29/10
CPC分类号： B01J21/04 , B01J23/02 , B01J23/10 , B01J23/50 , B01J23/688 , B01J27/138 , B01J35/002 , C07C29/106 , C07D301/10 , Y02P20/142 , C07C31/20
摘要： A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.
摘要翻译：提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。还提供了使用该催化剂对烯烃进行环氧化的方法。还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

10. 发明授权

US08858893B2 Process for the preparation of an alkylene carbonate and an alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和亚烷基二醇的方法
公开(公告)号：US08858893B2
公开(公告)日：2014-10-14
申请号：US13591982
申请日：2012-08-22
申请人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
发明人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
IPC分类号： B01J8/00 , C07C29/12 , C07C29/10 , C07D301/10
CPC分类号： C07D301/10 , B01D2255/104 , B01D2255/2022 , B01D2255/2092 , B01D2257/2062 , B01D2259/40 , C07C29/106 , C07C29/12 , Y02C10/08 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an bromide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of bromide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含溴化羧化催化剂的羧化区; 以及一个或多个净化区，其含有能够减少包含循环气体的进料中的含溴化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和亚烷基二醇的方法。

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