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1. 发明授权

US5654246A Methods of making composite ceramic articles having embedded filler 失效
标题翻译：制备具有嵌入填料的复合陶瓷制品的方法
公开(公告)号：US5654246A
公开(公告)日：1997-08-05
申请号：US451581
申请日：1995-05-26
申请人： Marc Stevens Newkirk , Harry Richard Zwicker , Andrew Willard Urquhart , John Peter Biel , Jack Andrew Kuszyk , Craig Barlow Shumaker , Harold Daniel Lesher , Terry Dennis Claar , Michael Kevork Aghajanian
发明人： Marc Stevens Newkirk , Harry Richard Zwicker , Andrew Willard Urquhart , John Peter Biel , Jack Andrew Kuszyk , Craig Barlow Shumaker , Harold Daniel Lesher , Terry Dennis Claar , Michael Kevork Aghajanian
IPC分类号： C04B35/65 , C04B41/87 , C04B38/00
CPC分类号： C04B35/652 , C04B41/87
摘要： A method of making self-supporting ceramic composite structures having filler embedded therein includes infiltrating a permeable mass of filler with polycrystalline material comprising an oxidation reaction product obtained by oxidation of a parent metal such as aluminum. The self-supporting ceramic composite structure optionally contains therein non-oxidized constituents of the parent metal. The structure is formed by placing a parent metal adjacent to a permeable filler and heating the assembly to melt the parent metal and provide a molten body of parent metal which is contacted with a suitable oxidant. Within a certain temperature region and optionally, aided by one or more dopants in or on the parent metal, molten parent metal will migrate through previously formed oxidation reaction product into contact with the oxidant, causing the oxidation reaction product to grow so as to embed the adjacent filler and provide the composite structure. The parent metal may be provided as a body of metal placed in contact with an exterior surface of the permeable mass. Alternatively, the parent metal may be placed adjacent to the filler material by admixing a plurality of discrete bodies of parent metal (e.g., particulate metal) into the permeable mass. In this embodiment, the growth of oxidation reaction product still embeds the adjacent filler material without substantial change in the size or shape of the permeable mass, but does not result in the creation of voids at the former locations of the bodies of parent metal.
摘要翻译：制造具有嵌入其中的填料的自支撑陶瓷复合结构的方法包括用包含通过母体金属如铝的氧化获得的氧化反应产物的多晶材料渗透可渗透的填料。自支撑陶瓷复合结构任选地含有母体金属的非氧化成分。该结构通过将母体金属放置在可渗透填料附近并加热该组件以熔化母体金属并提供与合适的氧化剂接触的母体金属熔融体而形成。在一定温度范围内，任选地，由母体金属中或母体金属上的一种或多种掺杂剂辅助，熔融母体金属将迁移通过预先形成的氧化反应产物与氧化剂接触，使氧化反应产物生长，从而嵌入相邻填料并提供复合结构。母金属可以设置为与可渗透物质的外表面接触的金属体。或者，母金属可以通过将多个离散的母体金属（例如，颗粒金属）的主体混合到可渗透物质中而邻近填充材料放置。在该实施方案中，氧化反应产物的生长仍然嵌入相邻的填充材料，而在渗透性物质的尺寸或形状上没有显着变化，但不会导致在母体金属体的原始位置产生空隙。

2. 发明授权

US07547849B2 Compositions useful in electronic circuitry type applications, patternable using amplified light, and methods and compositions relating thereto 失效
标题翻译：可用于电子电路类型应用的组合物，使用扩增光可图案化，以及与其相关的方法和组合物
公开(公告)号：US07547849B2
公开(公告)日：2009-06-16
申请号：US11153206
申请日：2005-06-15
申请人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Carl B. Wang , Brian C. Auman , Shane Fang
发明人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Carl B. Wang , Brian C. Auman , Shane Fang
IPC分类号： H05K1/00 , B32B3/00
CPC分类号： H05K3/185 , C23C18/02 , C23C18/1216 , C23C18/1233 , C23C18/1295 , C23C18/204 , Y10T428/24917 , Y10T428/25 , Y10T428/31511 , Y10T428/3154 , Y10T428/31725 , Y10T428/31786
摘要： A light-activatable polymer composition and polymer composite includes a polymer binder selected from epoxy resins, silica filled epoxy, bismaleimide resins, bismaleimide triazines, fluoropolymers, polyesters, polyphenylene oxide/polyphenylene ether resins, polybutadiene/polyisoprene crosslinkable resins (and copolymers), liquid crystal polymers, polyamides, cyanate esters, or combinations thereof, the polymer binder being present in an amount from 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 96, or 97 weight-percent of the total weight of the polymer composition; a spinel crystal filler present in an amount from 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 20, 25, 30, 35, 40, 45, 50, 55 and 60 weight-percent of the total weight of the polymer composition, and methods for making same are provided.
摘要翻译：可光活化的聚合物组合物和聚合物复合材料包括选自环氧树脂，二氧化硅填充的环氧树脂，双马来酰亚胺树脂，双马来酰亚胺三嗪，含氟聚合物，聚酯，聚苯醚/聚苯醚树脂，聚丁二烯/聚异戊二烯交联树脂（和共聚物），液体结晶聚合物，聚酰胺，氰酸酯或其组合，聚合物粘合剂的存在量为40,45,50,55,60,65,70,75,80,85,90,95,96或97重量 - 聚合物组合物的总重量; 存在量为3,4,5,6,7,8,9,10,11,12,13,14,15,20,25,30,35,40,45,50,55的尖晶石晶体填料和60重量％的聚合物组合物的总重量，以及制备其的方法。

3. 发明授权

US07598008B2 Methods for imaging regular patterns 有权
标题翻译：常规图案成像方法
公开(公告)号：US07598008B2
公开(公告)日：2009-10-06
申请号：US11045769
申请日：2005-01-28
申请人： Jonathan V. Caspar , Harry Richard Zwicker
发明人： Jonathan V. Caspar , Harry Richard Zwicker
IPC分类号： G02B5/20
CPC分类号： G02B5/201 , G02F1/133516 , G06K15/029 , G06K15/107 , G06K15/1261 , G06K2215/111
摘要： Methods for imaging regular patterns are provided. A multi-channel imaging head is configured in accordance with the repeat of a pre-determined regular pattern such that no swath boundaries appear within the visibly imaged features of the pattern. The imaged articles have reduced visible banding due to the elimination of swath boundaries in the imaged features.
摘要翻译：提供了规则图案成像的方法。多通道成像头根据预定的规则图案的重复来配置，使得在图案的可见成像的特征内没有出现条纹边界。成像的制品由于消除成像特征中的条纹边界而减少了可见条带。

4. 发明申请

US20090017309A1 COMPOSITIONS AND METHODS FOR CREATING ELECTRONIC CIRCUITRY 审中-公开
标题翻译：用于创建电子电路的组合物和方法
公开(公告)号：US20090017309A1
公开(公告)日：2009-01-15
申请号：US12169186
申请日：2008-07-08
申请人： YUEH-LING LEE , Shane Fang , Thomas Eugene Dueber , Richard A. Wessel , Harry Richard Zwicker
发明人： YUEH-LING LEE , Shane Fang , Thomas Eugene Dueber , Richard A. Wessel , Harry Richard Zwicker
IPC分类号： B32B15/092 , B32B15/00 , B05D3/06
CPC分类号： H05K1/0373 , H05K3/0032 , H05K3/184 , H05K3/185 , H05K3/28 , H05K2201/0209 , H05K2201/0236 , H05K2203/107 , Y10T428/31529 , Y10T428/3154 , Y10T428/31678
摘要： The present invention is directed to non-lithographic patterning by laser (or similar-type energy beam) ablation, where the ablation system ultimately results in circuitry features that are relative free from debris induced over-plating defects (debris relating to the ablation process) and fully additive plating induced over-plating defects. Compositions of the invention include a circuit board precursor having an insulating substrate and a cover layer. The insulating substrate is made from a dielectric material and also a metal oxide activatable filler. The cover layer can be sacrificial or non-sacrificial and is used to remediate unwanted debris arising from the ablation process.
摘要翻译：本发明涉及通过激光（或类似能量束）消融的非平版印刷图案，其中消融系统最终导致电路特征相对没有碎片诱导的过度电镀缺陷（与消融过程有关的碎片）和完全添加电镀引起的过度镀覆缺陷。本发明的组合物包括具有绝缘基板和覆盖层的电路板前体。绝缘基板由介电材料制成，也可由金属氧化物可活化填料制成。覆盖层可以是牺牲的或非牺牲的，并且用于修复由消融过程产生的不想要的碎屑。

5. 发明授权

US06958202B2 Donor element for adjusting the focus of an imaging laser 失效
标题翻译：用于调整成像激光焦点的供体元件
公开(公告)号：US06958202B2
公开(公告)日：2005-10-25
申请号：US10433869
申请日：2001-12-14
申请人： Richard Albert Coveleskie , Alan Lee Shobert , Gregory Charles Weed , Harry Richard Zwicker
发明人： Richard Albert Coveleskie , Alan Lee Shobert , Gregory Charles Weed , Harry Richard Zwicker
IPC分类号： B41M5/382 , B41M5/392 , B41M5/42 , B41M5/46 , G02B5/20 , G02B5/22 , G02F1/1335 , B41M5/40 , B41J2/475 , B41M5/38
CPC分类号： B41M5/42 , B41M5/38221 , G02B5/201 , G02B5/223 , G02F1/133516
摘要： A process for adjusting the energy of an imaging laser for element and thermally imageable elements suitable for this purpose are described. The process comprises the steps of: (a) providing an imaging unit having a non-imaging laser and an imaging laser, the non-imaging laser having a light detector which is in communication with the imaging laser, (b) contacting a receiver element with the thermally imageable element in the imaging unit, wherein the thermally imageable element comprises a light attenuated layer having a front surface and a back surface; (c) actuating the non-imaging laser to expose the thermally imageable element and the receiver element to an amount of light energy sufficient for the light detector to detect the amount of light reflected from the light attenuated layer of the thermally imageable element; and (d) actuating the imaging laser to focus the imaging laser in order to expose the thermally imageable element to an amount of light energy sufficient for imaging the thermally imageable element. The light attenuation is achieved by use of a light attenuating agent or by physically roughening a base element of the thermally imageable element.
摘要翻译：描述了用于调整用于适合于此目的的元件和可热成像元件的成像激光器的能量的方法。该方法包括以下步骤：（a）提供具有非成像激光和成像激光的成像单元，所述非成像激光器具有与成像激光器连通的光检测器，（b）使接收元件其中可成像单元中的可热成像元件，其中可热成像元件包括具有前表面和后表面的光衰减层; （c）致动所述非成像激光器以将所述可热成像元件和所述接收器元件暴露于足以使所述光检测器检测从所述可热成像元件的光衰减层反射的光量的量的光能量; 以及（d）致动成像激光器以聚焦成像激光器，以将可热成像元件暴露于足以对可热成像元件成像的光能量。光衰减通过使用光衰减剂或通过物理粗化可热成像元件的基底元件来实现。

6. 发明授权

US06881526B2 Receiver element for adjusting the focus of an imaging laser 失效
标题翻译：用于调整成像激光焦点的接收器元件
公开(公告)号：US06881526B2
公开(公告)日：2005-04-19
申请号：US10450757
申请日：2001-12-14
申请人： John E. Bobeck , Richard Albert Coveleskie , Jeffrey Jude Patricia , Alan Lee Shobert , Harvey Walter Taylor, Jr. , Harry Richard Zwicker
发明人： John E. Bobeck , Richard Albert Coveleskie , Jeffrey Jude Patricia , Alan Lee Shobert , Harvey Walter Taylor, Jr. , Harry Richard Zwicker
IPC分类号： B41J2/32 , B41M5/00 , B41M5/24 , B41M5/26 , B41M5/382 , B41M5/40 , B41M5/42 , B41M5/46 , B41M5/48 , G03F7/11 , G03F7/207 , G03F7/34 , G03F7/204
CPC分类号： B41M5/42 , B41M5/38207 , B41M5/38214 , B41M5/38221
摘要： A process for adjusting the energy of an imaging laser for imaging of a thermally imageable element including the steps of: (a) providing an imaging unit having a non-imaging laser and an imaging laser, the non-imaging laser having a light detector which is in communication with the imaging laser, (b) contacting a receiver element with the thermally imageable element in the imaging unit, wherein the receiver element comprises a light attenuating layer having a front surface and a back surface; (c) actuating the non-imaging laser to expose the thermally imageable element and the receiver element to an amount of light energy sufficient for the light detector to detect the amount of light reflected from the thermally imageable element and light attenuating layer of the receiver element; and (d) actuating the imaging laser to focus the imaging laser in order to expose the thermally imageable element to an amount of light energy sufficient for imaging the thermally imageable element.
摘要翻译：一种用于调整用于成像可热成像元件的成像激光器的能量的方法，包括以下步骤：（a）提供具有非成像激光器和成像激光器的成像单元，所述非成像激光器具有光检测器，与成像激光器通信，（b）使接收器元件与成像单元中的可热成像元件接触，其中接收器元件包括具有前表面和后表面的光衰减层; （c）致动非成像激光器以使可热成像元件和接收器元件暴露于足以使光检测器检测从可热成像元件和接收器元件的光衰减层反射的光量的光能量 ; 以及（d）致动成像激光器以聚焦成像激光器，以将可热成像元件暴露于足以对可热成像元件成像的光能量。

7. 发明授权

US07531204B2 Compositions useful in electronic circuitry type applications, patternable using amplified light, and methods and compositions relating thereto 失效
公开(公告)号：US07531204B2
公开(公告)日：2009-05-12
申请号：US11891129
申请日：2007-08-09
申请人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Carl B. Wang , Brian C. Auman , Shane Fang
发明人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Carl B. Wang , Brian C. Auman , Shane Fang
IPC分类号： B05D3/00
CPC分类号： H05K3/185 , C23C18/02 , C23C18/1216 , C23C18/1233 , C23C18/1295 , C23C18/204 , Y10T428/24917 , Y10T428/25 , Y10T428/31511 , Y10T428/3154 , Y10T428/31725 , Y10T428/31786
摘要： A light-activatable polymer composition and polymer composite includes a polymer binder selected from epoxy resins, silica filled epoxy, bismaleimide resins, bismaleimide triazines, fluoropolymers, polyesters, polyphenylene oxide/polyphenylene ether resins, polybutadiene/polyisoprene crosslinkable resins (and copolymers), liquid crystal polymers, polyamides, cyanate esters, or combinations thereof, the polymer binder being present in an amount from 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 96, or 97 weight-percent of the total weight of the polymer composition; a spinel crystal filler present in an amount from 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 20, 25, 30, 35, 40, 45, 50, 55 and 60 weight-percent of the total weight of the polymer composition, and methods for making same are provided.

8. 发明授权

US07504150B2 Polymer-based capacitor composites capable of being light-activated and receiving direct metalization, and methods and compositions related thereto 失效
标题翻译：能够被光活化并接受直接金属化的聚合物基电容器复合材料，以及与其相关的方法和组合物
公开(公告)号：US07504150B2
公开(公告)日：2009-03-17
申请号：US11153176
申请日：2005-06-15
申请人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Brian C. Auman
发明人： Yueh-Ling Lee , Meredith L. Dunbar , Harry Richard Zwicker , Brian C. Auman
IPC分类号： B32B27/20 , B32B15/08
CPC分类号： H01G4/20 , H01G4/14 , H05K1/0346 , H05K1/0373 , H05K1/162 , H05K3/185 , H05K2201/0154 , H05K2201/0209 , H05K2201/0355 , H05K2201/09309 , H05K2203/107 , Y10T428/25 , Y10T428/256 , Y10T428/26 , Y10T428/31529 , Y10T428/3154 , Y10T428/31681 , Y10T428/31721
摘要： The present invention relates generally to polymer composites having dispersed therein both useful spinel crystal fillers and ferroelectric (and/or paraelectric) fillers wherein the composite is both light activatable and can be used as a planar capacitor material. The light activation is typically employed via a laser beam (or other light emitting device) where the material has a pattern formed thereon. Electrodes are typically formed on the material's surface after patterning is complete via electroless metal plating. These composite polymers can be used as planar capacitors embedded in printed wiring boards or in integrated circuit packages.
摘要翻译：本发明一般涉及其中分散有有用的尖晶石晶体填料和铁电（和/或顺电）填料的聚合物复合材料，其中复合材料既可光活化又可用作平面电容器材料。通常通过激光束（或其他发光器件）使用光激活，其中材料具有形成在其上的图案。通过无电金属电镀完成图案化之后，电极通常形成在材料的表面上。这些复合聚合物可以用作嵌入印刷线路板或集成电路封装中的平面电容器。

9. 发明授权

US06890691B2 Backing layer of a donor element for adjusting the focus on an imaging laser 失效
标题翻译：用于调整成像激光器上的焦点的施主元件的背衬层
公开(公告)号：US06890691B2
公开(公告)日：2005-05-10
申请号：US10415400
申请日：2001-12-14
申请人： Richard Albert Coveleskie , Harry Richard Zwicker
发明人： Richard Albert Coveleskie , Harry Richard Zwicker
IPC分类号： B41J2/32 , B23K26/04 , B41J2/475 , B41J31/00 , B41J31/06 , B41M5/382 , B41M5/392 , B41M5/40 , B41M5/42 , B41M5/46 , G02B5/20 , G02B5/22 , G02F1/1335 , G03F9/00 , B41M5/38
CPC分类号： B41M5/42 , B23K26/04 , B41J2/4753 , B41M5/38221 , B41M5/426 , G02B5/201 , G02B5/223 , G02F1/133516
摘要： A process for adjusting the energy of an imaging laser for imaging of a thermally imageable element and thermally imageable elements suitable for this purpose are described. The process comprises the steps of: (a) providing an imaging unit having a non-imaging laser and an imaging laser, the non-imaging laser having a light detector which is in communication with the imaging laser; (b) contacting a receiver element with the thermally imageable element in the imaging unit, the thermally imageable element comprising a thermally imageable layer on a front side of a base element and a light attenuated layer on a back side of the base element comprising a light attenuating agent; (c) actuating the non-imaging laser to expose the thermally imageable element and the receiver element to an amount of light energy sufficient for the light detector to detect the amount of light reflected from the light attenuated layer of the thermally imageable element; and (d) actuating the imaging laser to focus the imaging laser in order to expose the thermally imageable element to an amount of light energy sufficient for imaging the thermally imageable element. The light attenuation is achieved by use of a light attenuating agent or by physically roughening a support.
摘要翻译：描述了用于调整用于成像可热成像元件的成像激光器的能量和适于该目的的可热成像元件的工艺。该方法包括以下步骤：（a）提供具有非成像激光和成像激光的成像单元，所述非成像激光器具有与成像激光器连通的光检测器; （b）使接收器元件与成像单元中的可热成像元件接触，所述可热成像元件包括在基底元件的前侧上的可热成像层和在所述基底元件的背面上的光衰减层，包括光衰减剂; （c）致动所述非成像激光器以将所述可热成像元件和所述接收器元件暴露于足以使所述光检测器检测从所述可热成像元件的光衰减层反射的光量的量的光能量; 以及（d）致动成像激光器以聚焦成像激光器，以将可热成像元件暴露于足以对可热成像元件成像的光能量。光衰减通过使用光衰减剂或通过物理上粗糙化支持物来实现。

10. 发明授权

US06645681B2 Color filter 失效
公开(公告)号：US06645681B2
公开(公告)日：2003-11-11
申请号：US10172100
申请日：2002-06-14
申请人： Gerald Donald Andrews , Jonathan V Casper , Richard Albert Coveleskie , Alan Lee Shobert , Gregory Charles Weed , Harry Richard Zwicker
发明人： Gerald Donald Andrews , Jonathan V Casper , Richard Albert Coveleskie , Alan Lee Shobert , Gregory Charles Weed , Harry Richard Zwicker
IPC分类号： G02B520
CPC分类号： B41M5/42 , B41M5/38221 , G02B5/223 , G02F1/133516
摘要： A process for adjusting the energy of an imaging laser for imaging of a thermally imageable element and thermally imageable elements suitable for this purpose are described, which is useful for color filters and liquid crystal display devices. The process comprises the steps of: (a) providing an imaging unit having a non-imaging laser and an imaging laser, the non-imaging laser having a light detector which is in communication with the imaging laser; (b) contacting a receiver element with the thermally imageable element in the imaging unit, wherein the thermally imageable element comprises a light attenuated layer having a front surface and a back surface; (c) actuating the non-imaging laser to expose the thermally imageable element and the receiver element to an amount of light energy sufficient for the light detector to detect the amount of light reflected from the light attenuated layer of the thermally imageable element; and (d) actuating the imaging laser to focus the imaging laser in order to expose the thermally imageable element to an amount of light energy sufficient for imaging the thermally imageable element. The light attenuation is achieved by use of a light attenuating agent or by physically roughening a base element of the thermally imageable element.

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