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1. 发明授权

US5723697A Catalytic oxidation of light alkanes in presence of a base 失效
标题翻译：在碱存在下催化氧化轻链烷烃
公开(公告)号：US5723697A
公开(公告)日：1998-03-03
申请号：US580918
申请日：1995-12-29
申请人： Manoj V. Bhinde , Thomas W. Bierl
发明人： Manoj V. Bhinde , Thomas W. Bierl
IPC分类号： B01J31/22 , C07B61/00 , C07C29/50 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/125
CPC分类号： C07C29/50
摘要： The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol.
摘要翻译：在金属 - 配体催化的烷烃部分氧化中，反应混合物中碱的存在导致持续的催化剂活性，并且在不存在碱的情况下与氧化相比转化率更高百分比，同时保持对所需氧化的令人满意的选择性，例如异丁烷氧化成异丁醇。

2. 发明授权

US06525232B1 Process and apparatus for endothermic reactions of organic compounds 失效
标题翻译：有机化合物吸热反应的方法和装置
公开(公告)号：US06525232B1
公开(公告)日：2003-02-25
申请号：US08278782
申请日：1994-07-22
申请人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
发明人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
IPC分类号： C07C5393
CPC分类号： B01J8/0453 , B01J23/755 , B01J23/866 , B01J27/1813 , B01J27/1815 , B01J29/24 , B01J29/63 , B01J37/0207 , B01J2208/00274 , C07B35/04 , C07C5/3335 , Y02P20/584 , C07C11/08
摘要： The invention provides process and apparatus for conducting an endothermic reaction of an organic compound in the presence of molecular hydrogen and of multicomponent solids. The process comprises contacting the compound with a solid catalyst for the endothermic reaction and a hydrogen oxidizing solid reagent intermixed with the solid catalyst. Organic products of the endothermic reaction are produced, with evolution of molecular hydrogen. The solid catalyst becomes gradually deactivated by formation of carbonaceous deposits thereon. The evolved hydrogen undergoes an exothermic reaction with the hydrogen oxidizing solid reagent to form a reduction product which comprises deactivated hydrogen oxidizing solid reagent. The deactivated solid catalyst is reactivated by combustion of carbonaceous deposits thereon and the deactivated hydrogen oxidizing solid reagent is reactivated by contacting the reagent with an oxidizing agent in the absence of substantial quantities of hydrogen and in the absence of substantial quantities of organic compounds other than those on the surface of the reagent. One embodiment of the invention provides apparatus in which an endothermic reaction is carried out in the presence of a fluidized bed of catalyst and in the presence of particles of granular hydrogen oxidizing solid reagent which move downwardly through the fluidized catalyst bed, and in which the solid catalyst and solid reagent are separated prior to reactivation thereof in separate reactivation zones.
摘要翻译：本发明提供了在分子氢和多组分固体存在下进行有机化合物的吸热反应的方法和装置。该方法包括使化合物与用于吸热反应的固体催化剂和与固体催化剂混合的氢氧化固体试剂接触。随着分子氢的发展，产生吸热反应的有机产物。固体催化剂通过在其上形成碳质沉积物而逐渐失活。放出的氢气经历与氢氧化固体试剂的放热反应，形成还原产物，其包含失活的氢氧化固体试剂。失活的固体催化剂通过其上的碳质沉积物的燃烧而再活化，并且通过在不存在大量氢气的情况下将试剂与氧化剂接触并且在不存在大量的除了那些之外的大量有机化合物的情况下，使失活的氢氧化固体试剂再活化在试剂的表面。本发明的一个实施方案提供了在催化剂流化床存在下和在向下移动通过流化催化剂床的颗粒氢氧化固体试剂存在下进行吸热反应的装置，其中固体催化剂和固体试剂在分离的再活化区域中再活化之前被分离。

3. 发明授权

US06872364B2 Apparatus for endothermic reactions of organic compounds 失效
标题翻译：有机化合物吸热反应装置
公开(公告)号：US06872364B2
公开(公告)日：2005-03-29
申请号：US10331367
申请日：2002-12-30
申请人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
发明人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
IPC分类号： B01J8/04 , B01J23/755 , B01J27/18 , C07B35/04 , C07C5/333 , F27B15/14 , C07C5/393
CPC分类号： B01J8/0453 , B01J23/755 , B01J23/866 , B01J27/1813 , B01J27/1815 , B01J29/24 , B01J29/63 , B01J37/0207 , B01J2208/00274 , C07B35/04 , C07C5/3335 , Y02P20/584 , C07C11/08
摘要： An apparatus for conducting an endothermic reaction of an organic' compound in the presence of molecular hydrogen and of multicomponent solids is described. The process of operating the apparatus comprises contacting the compound with a solid catalyst for the endothermic reaction and a hydrogen oxidizing solid reagent intermixed with the solid catalyst. Organic products of the endothermic reaction are produced, with evolution of molecular hydrogen. The solid catalyst becomes gradually deactivated by formation of carbonaceous deposits thereon. The evolved hydrogen undergoes an exothermic reaction with the hydrogen oxidizing solid reagent to form a reduction product which comprises deactivated hydrogen oxidizing solid reagent. The deactivated solid catalyst is reactivated by combustion of carbonaceous deposits thereon and the deactivated hydrogen oxidizing solid reagent is reactivated by contacting the reagent with an oxidizing agent in the absence of substantial quantities of hydrogen and in the absence of substantial quantities of organic compounds other than those on the surface of the reagent. The apparatus provides an endothermic reaction which is carried out in the presence of a fluidized bed of catalyst and in the presence of particles of granular hydrogen oxidizing solid reagent which move downwardly through the fluidized catalyst bed, and in which the solid catalyst and solid reagent are separated prior to reactivation thereof in separate reactivation zones.
摘要翻译：描述了在分子氢和多组分固体存在下进行有机化合物的吸热反应的装置。操作该装置的过程包括使化合物与用于吸热反应的固体催化剂和与固体催化剂混合的氢氧化固体试剂接触。随着分子氢的发展，产生吸热反应的有机产物。固体催化剂通过在其上形成碳质沉积物而逐渐失活。放出的氢气经历与氢氧化固体试剂的放热反应，形成还原产物，其包含失活的氢氧化固体试剂。失活的固体催化剂通过其上的碳质沉积物的燃烧而再活化，并且通过在不存在大量氢气的情况下将试剂与氧化剂接触并且在不存在大量的除了那些之外的大量有机化合物的情况下，使失活的氢氧化固体试剂再活化在试剂的表面。该装置提供吸热反应，其在催化剂的流化床存在下和在向下移动通过流化催化剂床的颗粒氢氧化固体试剂存在下进行，其中固体催化剂和固体试剂为在分离的再活化区域中再分离。

4. 发明授权

US4766261A Purification of fluorocarbons 失效
标题翻译：碳氟化合物的净化
公开(公告)号：US4766261A
公开(公告)日：1988-08-23
申请号：US805596
申请日：1985-12-10
申请人： Thomas W. Bierl
发明人： Thomas W. Bierl
IPC分类号： C07C17/395 , C07C17/38
CPC分类号： C07C17/395
摘要： Fluorocarbons are purified and toxicity substantially reduced by contact with a substantially dry, strongly basic and strongly nucleophilic alkali or alkaline earth metal compound, and separating the decomposition products which form.
摘要翻译：氟化碳被纯化，并且通过与基本上干燥，强碱性和强亲核性碱金属或碱土金属化合物接触并分离形成的分解产物而大大降低了毒性。

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