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1. 发明授权

US06489518B1 Process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction 有权
$Process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction$
标题翻译：通过萃取，还原包含从异丙苯制备苯酚得到的高锅炉馏分的盐含量的方法
公开(公告)号：US06489518B1
公开(公告)日：2002-12-03
申请号：US09709353
申请日：2000-11-13
申请人： Manfred Weber , Markus Weber , Heinrich van Barneveld , Peter Bickert , Wilfried Jordan
发明人： Manfred Weber , Markus Weber , Heinrich van Barneveld , Peter Bickert , Wilfried Jordan
IPC分类号： C07C3768
CPC分类号： C07C37/72 , C07C39/04
摘要： A process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction, is claimed. In the preparation of phenol from cumene, not only phenol and acetone but also by-products such as dimethyl phenyl carbinol or acetophenone are formed in the cleavage of cumene hydroperoxide. In the work-up of the cleavage product phase by distillation, these by-products are obtained as a fraction which boils only at high temperatures. These fractions further comprise alkali metal in the form of salts as a result of the neutralization by means of aqueous sodium hydroxide after the acid catalyzed cleavage. The presence of salt in this phase makes the work-up of this phase considerably more difficult. The salt is usually removed from the fraction by extraction of the fraction with water. However, considerable problems can occur if the aqueous phase cannot be cleanly separated from the organic phase. According to the invention, not only water but also an organic liquid is added to the fractions comprising high boilers for the purposes of extraction. This aids and accelerates the subsequent phase separation. The organic liquid to be added to the fractions comprising high boilers can be removed again from the treated fractions by simple distillation. Furthermore, the process of the invention lowers the phenol content of the fractions comprising high boilers and phenol is recovered. Fractions comprising high boilers which have been treated according to the invention can be used as starting material for the production of carbon black.
摘要翻译：要求保护包含从异丙苯制备苯酚得到的高沸点馏分的馏分的盐含量的方法。在从异丙基苯制备苯酚时，在氢过氧化枯烯的裂解中不仅形成苯酚和丙酮，而且还产生二甲基苯基甲醇或苯乙酮等副产物。在通过蒸馏处理裂解产物相时，这些副产物作为仅在高温下沸腾的馏分获得。由于在酸催化裂解后通过氢氧化钠水溶液中和，这些级分还包含盐形式的碱金属。在这一阶段盐的存在使得这一阶段的后处理更加困难。盐通常通过用水萃取级分从馏分中除去。然而，如果水相不能与有机相清洁分离，则可能会发生相当大的问题。根据本发明，为了提取的目的，不仅将水，而且有机液体加入到包含高锅炉的馏分中。这有助于并加速随后的相分离。通过简单蒸馏，可以从经处理的馏分再次除去加入到包含高锅炉的馏分中的有机液体。此外，本发明的方法降低了包含高锅炉和苯酚的馏分的苯酚含量。根据本发明已经处理的包含高锅炉的馏分可以用作生产炭黑的起始原料。

2. 发明申请

US20070244346A1 PROCESS FOR REMOVAL OF HYDROXYACETONE FROM PHENOL 审中-公开
标题翻译：从苯酚中除去羟基酮的方法
公开(公告)号：US20070244346A1
公开(公告)日：2007-10-18
申请号：US11736531
申请日：2007-04-17
申请人： Otto Schnurr , Manfred Weber , Markus Weber
发明人： Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C39/04
摘要： The present invention relates to method for producing phenol which includes: a) oxidizing cumene to form an oxidation product containing cumene hydroperoxide; b) cleaving the oxidation product using an acidic catalyst to form a cleavage product containing phenol, acetone and impurities; c) neutralizing and washing the cleavage product with a basic aqueous medium to obtain a neutralized cleavage product; d) separating the neutralized cleavage product by at least one distillation step into at least a phenol containing fraction and an aqueous fraction comprising hydroxyacetone; e) treating the aqueous fraction with an oxidizing agent in presence of a base to obtain a basic aqueous medium reduced in hydroxyacetone; f) recycling at least a portion of the basic aqueous medium to the neutralizing and washing step c); and g) recovering phenol from the phenol containing fraction obtained in step d).
摘要翻译：本发明涉及苯酚的制备方法，其包括：a）氧化枯烯以形成含有氢过氧化枯烯的氧化产物; b）使用酸性催化剂切割氧化产物以形成含有苯酚，丙酮和杂质的裂解产物; c）用碱性水性介质中和洗涤裂解产物以获得中和的裂解产物; d）将中和的裂解产物通过至少一个蒸馏步骤分离成至少含苯酚的级分和包含羟基丙酮的含水级分; e）在碱的存在下用氧化剂处理含水部分以获得羟基丙酮中还原的碱性水性介质; f）将至少一部分碱性水性介质再循环到中和和洗涤步骤c）中; 和g）从在步骤d）中获得的含苯酚馏分中回收苯酚。

3. 发明申请

US20050034970A1 Process for the preparation of phenolic compounds, for separating phenol from cleavage product mixtures, and an apparatus 有权
标题翻译：酚类化合物的制备方法，用于从分离产物混合物中分离苯酚和设备
公开(公告)号：US20050034970A1
公开(公告)日：2005-02-17
申请号：US10888533
申请日：2004-07-09
申请人： Christoph Schwarz , Markus Weber , Manfred Weber
发明人： Christoph Schwarz , Markus Weber , Manfred Weber
IPC分类号： B01D3/14 , B01D3/32 , C07C37/08 , C07C37/74 , C07C39/04 , C07C45/53 , C07C45/82 , B01D3/00 , B01D3/02 , C07C27/26 , C07C29/74
CPC分类号： C07C45/82 , B01D3/146 , B01D3/322 , C07C37/08 , C07C37/74 , C07C45/53 , C07C49/17 , C07C49/08 , C07C39/04
摘要： To improve energy efficiency of prior art processes while preserving the standards of quality and total yield of desired end products, a process for the preparation of phenolic compounds is proposed. The process of the invention comprises working-up of the cleavage product mixtures by distillation, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by feeding the cleavage product mixture to the side of a distillation column, removing a first fraction comprising the ketone at the top of the distillation column, removing a second fraction comprising the phenolic compound at the bottom of the distillation column, and removing a third fraction comprising unreacted the alkylaryl compound and the hydroxy ketone, and water, as side stream, whereby the side stream take-off is situated above the feed of cleavage product mixture to the distillation column, characterized by removing heat from the distillation column, whereby the heat take-off is situated above the side stream take-off of the third fraction, and a process for separating phenol from cleavage product mixtures, wherein the cleavage product mixture prior feeding into the distillation column, is preheated to a temperature of above 70° C. at standard pressure, preferably to a temperature of above 100° C., more preferably to a temperature between 110° C. and 180° C., most preferred to a temperature of about 140° C. to 146° C., and an apparatus suitable therefore.
摘要翻译：为了提高现有技术工艺的能量效率，同时保持所需最终产品的质量和总产量的标准，提出了制备酚类化合物的方法。本发明的方法包括通过蒸馏处理裂解产物混合物，其包括在单一蒸馏步骤中将裂解产物混合物分解成至少三个级分，将裂解产物混合物加入到蒸馏塔的侧面，除去在蒸馏塔顶部包含酮的第一馏分，在蒸馏塔的底部除去包含酚类化合物的第二级分，并除去包含未反应的烷基芳基化合物和羟基酮的第三馏分和水作为侧流，由此侧流起飞位于裂解产物混合物的进料到蒸馏塔的上方，其特征在于从蒸馏塔除去热量，由此该热量取出位于第三馏分的侧流起飞之上以及从裂解产物混合物中分离苯酚的方法，其中先前加入的裂解产物混合物蒸馏塔在标准压力下预热至高于70℃的温度，优选至高于100℃的温度，更优选至110℃至180℃的温度，最优选为温度为约140℃至146℃，因此适用的装置。

4. 发明授权

US07626060B2 Process for the preparation of phenolic compounds, for separating phenol from cleavage product mixtures, and an apparatus 有权
标题翻译：酚类化合物的制备方法，用于从分离产物混合物中分离苯酚和设备
公开(公告)号：US07626060B2
公开(公告)日：2009-12-01
申请号：US10888533
申请日：2004-07-09
申请人： Christoph Schwarz , Markus Weber , Manfred Weber
发明人： Christoph Schwarz , Markus Weber , Manfred Weber
IPC分类号： C07C37/00 , C07C37/68
CPC分类号： C07C45/82 , B01D3/146 , B01D3/322 , C07C37/08 , C07C37/74 , C07C45/53 , C07C49/17 , C07C49/08 , C07C39/04
摘要： To improve energy efficiency of prior art processes while preserving the standards of quality and total yield of desired end products, a process for the preparation of phenolic compounds is proposed. The process of the invention comprises working-up of the cleavage product mixtures by distillation, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by feeding the cleavage product mixture to the side of a distillation column, removing a first fraction comprising the ketone at the top of the distillation column, removing a second fraction comprising the phenolic compound at the bottom of the distillation column, and removing a third fraction comprising unreacted the alkylaryl compound and the hydroxy ketone, and water, as side stream, whereby the side stream take-off is situated above the feed of cleavage product mixture to the distillation column, characterized by removing heat from the distillation column, whereby the heat take-off is situated above the side stream take-off of the third fraction, and a process for separating phenol from cleavage product mixtures, wherein the cleavage product mixture prior feeding into the distillation column, is preheated to a temperature of above 70° C. at standard pressure, preferably to a temperature of above 100° C., more preferably to a temperature between 110° C. and 180° C., most preferred to a temperature of about 140° C. to 146° C., and an apparatus suitable therefore.
摘要翻译：为了提高现有技术工艺的能量效率，同时保持所需最终产品的质量和总产量的标准，提出了制备酚类化合物的方法。本发明的方法包括通过蒸馏处理裂解产物混合物，其包括在单一蒸馏步骤中将裂解产物混合物分解成至少三个级分，通过将裂解产物混合物加入到蒸馏塔的侧面，除去在蒸馏塔顶部包含酮的第一馏分，在蒸馏塔的底部除去包含酚类化合物的第二级分，并除去包含未反应的烷基芳基化合物和羟基酮的第三馏分和水作为侧流，由此侧流起飞位于裂解产物混合物的进料到蒸馏塔的上方，其特征在于从蒸馏塔除去热量，由此该热量取出位于第三馏分的侧流起飞之上以及从裂解产物混合物中分离苯酚的方法，其中先前加入的裂解产物混合物蒸馏塔在标准压力下预热至高于70℃的温度，优选至高于100℃的温度，更优选至110℃至180℃的温度，最优选为温度为约140℃至146℃，因此适用的装置。

5. 发明申请

US20070244345A1 PROCESS FOR TREATING PHENOL 有权
标题翻译：处理酚醛的方法
公开(公告)号：US20070244345A1
公开(公告)日：2007-10-18
申请号：US11736507
申请日：2007-04-17
申请人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
发明人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/82 , C07C37/68
CPC分类号： C07C37/74 , C07C37/08 , C07C37/685 , C07C37/70 , C07C37/82 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C39/04
摘要： The present invention relates to a continuous method for treating a crude phenol stream comprising methylbenzofuran and hydroxyacetone by passing the crude phenol stream through at least two reactors connected in series the reactors containing an acidic ion exchange resin, whereby the temperature in successive reactors decreases in flow direction of the phenol stream so that the temperature in the first reactor in flow direction of the phenol stream is between 100° C. and 200° C. and the temperature in the last reactor in flow direction of the phenol stream is between 50° C. and 90° C. without a thermal separation step between any of two successive reactors and to the use of this method in a process for making phenol.
摘要翻译：本发明涉及通过使粗苯酚流通过串联连接的含有酸性离子交换树脂的反应器的至少两个反应器来处理包含甲基苯并呋喃和羟基丙酮的粗苯酚流的连续方法，由此连续反应器中的温度降低流动苯酚流的方向，使得苯酚流的流动方向上的第一反应器中的温度在100℃和200℃之间，并且最后的反应器中苯酚流的流动方向的温度为50℃ 和90℃，在两个连续的反应器中的任一个之间没有热分离步骤，并且在制备苯酚的方法中使用该方法。

6. 发明授权

US07544845B2 Process for treating phenol 有权
标题翻译：苯酚处理方法
公开(公告)号：US07544845B2
公开(公告)日：2009-06-09
申请号：US11736507
申请日：2007-04-17
申请人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
发明人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/00
CPC分类号： C07C37/74 , C07C37/08 , C07C37/685 , C07C37/70 , C07C37/82 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C39/04
摘要： The present invention relates to a continuous method for treating a crude phenol stream comprising methylbenzofuran and hydroxyacetone by passing the crude phenol stream through at least two reactors connected in series the reactors containing an acidic ion exchange resin, whereby the temperature in successive reactors decreases in flow direction of the phenol stream so that the temperature in the first reactor in flow direction of the phenol stream is between 100° C. and 200° C. and the temperature in the last reactor in flow direction of the phenol stream is between 50° C. and 90° C. without a thermal separation step between any of two successive reactors and to the use of this method in a process for making phenol.
摘要翻译：本发明涉及通过使粗苯酚流通过串联连接的含有酸性离子交换树脂的反应器的至少两个反应器来处理包含甲基苯并呋喃和羟基丙酮的粗苯酚流的连续方法，由此连续反应器中的温度降低流动苯酚流的方向，使得苯酚流的流动方向上的第一反应器中的温度在100℃和200℃之间，并且最后的反应器中苯酚流的流动方向的温度为50℃ 和90℃，在两个连续的反应器中的任一个之间没有热分离步骤，并且在制备苯酚的方法中使用该方法。

7. 发明授权

US09155571B2 Minimally invasive interspinous process spacer implants and methods 有权
标题翻译：微创棘突间隔植入物和方法
公开(公告)号：US09155571B2
公开(公告)日：2015-10-13
申请号：US12940125
申请日：2010-11-05
申请人： Daniel Thommen , Markus Weber , Jacques Teisen , Markus Kraft , Florian Kaufmann , Markus Hunziker , Felix Aschmann , Stefan Saladin , Martin Oswald , Roman Randegger
发明人： Daniel Thommen , Markus Weber , Jacques Teisen , Markus Kraft , Florian Kaufmann , Markus Hunziker , Felix Aschmann , Stefan Saladin , Martin Oswald , Roman Randegger
IPC分类号： A61F2/44 , A61B17/70 , A61B19/00 , A61B17/00
CPC分类号： A61B17/7065 , A61B17/7076 , A61B90/39 , A61B2017/00292 , A61B2017/00557 , A61B2017/00867
摘要： An interspinous process spacer for implantation in an interspinous space between a superior spinous process and an inferior spinous process includes a balloon-like body, a first deployable protrusion and a second deployable protrusion. The body has a distal end, a proximal end and a longitudinal axis extending between the proximal and distal ends. The spacer is arrangeable in an unexpanded configuration and an expanded configuration. The first deployable protrusion is mounted proximate the proximal end and the second deployable protrusion is mounted proximate the distal end. The first and second deployable protrusions are oriented generally parallel to the longitudinal axis in the unexpanded configuration and generally perpendicular to the longitudinal axis in the expanded configuration.
摘要翻译：用于植入在上棘突和下棘之间棘突间的棘突间间隔件包括球状体，第一展开突起和第二展开突起。主体具有在近端和远端之间延伸的远端，近端和纵向轴线。间隔件可布置在未膨胀构型和扩展构型中。第一可展开的突起被安装在近端附近，并且第二可展开突起被安装在远端附近。第一和第二可展开突起在未膨胀构造中大体上平行于纵向轴线定向并且在扩展构型中大致垂直于纵向轴线定向。

8. 发明授权

US09045743B2 Stabilization of thermolysin in aqueous solution 有权
标题翻译：溶菌酶在水溶液中的稳定化
公开(公告)号：US09045743B2
公开(公告)日：2015-06-02
申请号：US13488824
申请日：2012-06-05
申请人： Werner Hoelke , Johann-Peter Thalhofer , Antje Liehre , Markus Weber
发明人： Werner Hoelke , Johann-Peter Thalhofer , Antje Liehre , Markus Weber
IPC分类号： C12N9/54 , C12N9/96
CPC分类号： C12N9/54 , C12N9/96 , C12Y304/24027
摘要： The present invention deals with the proteolytic enzyme thermolysin which tends to be unstable in aqueous solution. The invention provides methods and compositions to enhance the stability of dissolved thermolysin in aqueous solution. Thermolysin, crude thermolysin or a lyophilizate containing thermolysin and one or more salts, is contacted with an aqueous buffer with a low salt concentration and a first solution is formed. Subsequently, a further salt in solid form is added and dissociated, thereby forming a second solution comprising thermolysin in a stabilized form.
摘要翻译：本发明涉及在水溶液中趋于不稳定的蛋白水解酶嗜热溶菌酶。本发明提供了增加溶解的嗜热溶菌酶在水溶液中的稳定性的方法和组合物。将嗜热菌蛋白酶，粗嗜热菌蛋白酶或含有嗜热菌蛋白酶和一种或多种盐的冻干物与低盐浓度的水性缓冲液接触，形成第一溶液。随后，加入固体形式的另外的盐并解离，由此形成稳定形式的包含嗜热菌蛋白酶的第二溶液。

9. 发明授权

US08841481B2 Use of foam bodies in oxidation reactors for preparing unsaturated aldehydes or carboxylic acids 有权
标题翻译：在氧化反应器中使用泡沫体制备不饱和醛或羧酸
公开(公告)号：US08841481B2
公开(公告)日：2014-09-23
申请号：US13060599
申请日：2009-07-29
申请人： Horst-Werner Zanthoff , Nicole Brausch , Franz-Felix Kuppinger , Jorg Sauer , Andreas Sabbagh , Dennis Fruhling , Markus Weber , Oliver Becker
发明人： Horst-Werner Zanthoff , Nicole Brausch , Franz-Felix Kuppinger , Jorg Sauer , Andreas Sabbagh , Dennis Fruhling , Markus Weber , Oliver Becker
IPC分类号： C07C45/35 , C07C57/04 , B01J37/02 , C07C5/333 , C07C51/25 , B01J23/00 , B01J19/24 , B01J35/04 , B01J8/06 , B01J23/888
CPC分类号： B01J8/067 , B01J19/249 , B01J23/002 , B01J23/8885 , B01J35/04 , B01J37/0219 , B01J37/0225 , B01J2208/00221 , B01J2208/025 , B01J2219/00006 , B01J2219/0004 , B01J2219/2453 , B01J2219/2479 , B01J2219/2481 , B01J2523/00 , C07C5/333 , C07C45/35 , C07C51/252 , Y02P20/52 , C07C11/06 , C07C47/22 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： The present invention relates to a process for preparing unsaturated aldehydes or unsaturated carboxylic acids by heterogeneous catalytic gas phase oxidation of unsaturated or saturated hydrocarbons, comprising the process steps of: i) providing a gas mixture comprising a saturated hydrocarbon and catalytically dehydrogenating the saturated hydrocarbon in the gas phase to obtain a gas mixture comprising an unsaturated hydrocarbon in a dehydrogenation reactor having a dehydrogenation catalyst material; or ii) providing a gas mixture comprising oxygen and an unsaturated hydrocarbon; iii) catalytically oxidizing the unsaturated hydrocarbon obtained in process step i) or provided in process step ii) in the gas phase to obtain a gas mixture comprising an unsaturated aldehyde in a first oxidation reactor having a first oxidation catalyst material; wherein at least one of the reactors selected from the dehydrogenation reactor, the first oxidation reactor and the second oxidation reactor comprises at least one foam body.
摘要翻译：本发明涉及通过不饱和烃或饱和烃的非均相催化气相氧化制备不饱和醛或不饱和羧酸的方法，包括以下工艺步骤：i）提供包含饱和烃的气体混合物并将饱和烃催化脱氢在具有脱氢催化剂材料的脱氢反应器中获得包含不饱和烃的气体混合物; 或ii）提供包含氧和不饱和烃的气体混合物; iii）在工艺步骤i）中获得或在工艺步骤ii）中提供的不饱和烃催化氧化以在具有第一氧化催化剂材料的第一氧化反应器中获得包含不饱和醛的气体混合物; 其中选自脱氢反应器，第一氧化反应器和第二氧化反应器的反应器中的至少一个包括至少一个泡沫体。

10. 发明授权

US08614164B2 Iron- and copper-comprising heterogeneous catalyst and process for preparing olefins by reacting carbon monoxide with hydrogen 失效
标题翻译：含铁和铜的非均相催化剂和通过一氧化碳与氢气反应制备烯烃的方法
公开(公告)号：US08614164B2
公开(公告)日：2013-12-24
申请号：US12939281
申请日：2010-11-04
申请人： Jochen Steiner , Kerem Bay , Vera Werner , Jürgen Amann , Stefan Bunzel , Claudia Moβbacher , Joachim Müller , Ekkehard Schwab , Markus Weber
发明人： Jochen Steiner , Kerem Bay , Vera Werner , Jürgen Amann , Stefan Bunzel , Claudia Moβbacher , Joachim Müller , Ekkehard Schwab , Markus Weber
IPC分类号： B01J23/58 , C07C27/00 , B01J23/70 , B01J23/72 , B01J23/74
CPC分类号： B01J23/745 , B01J23/002 , B01J23/005 , B01J23/72 , B01J23/78 , B01J35/023 , B01J37/0201 , B01J37/086 , B01J37/14 , B01J37/18 , B01J2523/00 , C07C1/044 , C07C2523/04 , C07C2523/72 , C07C2523/745 , C07C2523/885 , C10G2/332 , C10G2400/20 , C07C11/02 , B01J2523/17 , B01J2523/842
摘要： Iron- and copper-containing heterogeneous catalyst, and a process for producing it, including the following steps: thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles; treatment of carbonyl iron powder with hydrogen, resulting in the metallic spherical primary particles at least partly agglomerating; surface oxidation of the iron particles to form iron oxide; contacting the particles with an aqueous solution of a copper compound; drying in the presence of oxygen and subsequent calcination in the absence of oxygen, resulting in oxygen-comprising copper compounds on the particles; and finally reaction of these with the iron oxide to form a mixed oxide of the formula CuxFe3-xO4, where 0
摘要翻译：含铁和铜的非均相催化剂及其制备方法，包括以下步骤：将五羰基气态铁热分解，得到具有球形初级颗粒的羰基铁粉; 用氢气处理羰基铁粉末，导致金属球形初级颗粒至少部分凝聚; 铁颗粒的表面氧化形成氧化铁; 使所述颗粒与铜化合物的水溶液接触; 在氧气存在下干燥，随后在不存在氧气下进行煅烧，导致颗粒上含氧的铜化合物; 最后使它们与氧化铁反应形成式CuxFe3-xO4的混合氧化物，其中0

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