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    • 1. 发明授权
    • Double attachment reactive dyes having alkyl- or alkenylsulfonyl and
alkyl- or alkenylsulfonylalkyl groups
    • 具有烷基或烯基磺酰基和烷基 - 或烯基磺酰基烷基的双连接活性染料
    • US5210187A
    • 1993-05-11
    • US865744
    • 1992-04-09
    • Manfred PatschUwe NahrFriedrich WirsingJoerg L. JessenKlaus PandlClaus MarschnerMatthias Dust
    • Manfred PatschUwe NahrFriedrich WirsingJoerg L. JessenKlaus PandlClaus MarschnerMatthias Dust
    • C07C317/14C07C317/32C09B62/02C09B62/44C09B62/503
    • C09B62/4403C07C317/14C07C317/32C09B62/02C09B62/503
    • Double attachment reactive dyes have the formula ##STR1## where U.sup.1 is C.sub.1 -C.sub.4 -alkyl, phenyl, C.sub.2 -C.sub.10 -alkenyl or the radical ##STR2## where Q.sup.1 and Q.sup.2 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl and Q.sup.3 is a group which is detachable under alkaline reaction conditions,Z is the radical ##STR3## where each Q.sup.4 is independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl which may be substituted by cyano, U.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, C.sub.2 -C.sub.10 -alkenyl or the radical ##STR4## where Q.sup.5 and Q.sup.6 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl and Q.sup.7 is a group which is detachable under alkaline reaction conditions, and w is 0, 1 or 2,t is 0, 1 or 2,v is 1 or 2 and X and L are each as defined in the description, with the proviso that at least one of the two radicals U.sup.1 and U.sup.2 is not C.sub.1 -C.sub.4 -alkyl or phenyl, and are prepared from benzyl compounds of the formula ##STR5## where A is nitro or amino and U.sup.1, Z and t are each as defined above. The reactive dyes are useful for dyeing hydroxyl-containing fibers such as cotton and wool and provide high yields and high wet fastness.
    • 双连接活性染料具有式“IMAGE”,其中U1是C1-C4-烷基,苯基,C2-C10-烯基或基团,其中Q1和Q2各自独立地是氢或C1-C4-烷基, Q3是在碱性反应条件下可分离的基团,Z是基团,其中每个Q 4独立于可被氰基取代的另一个氢或C 1 -C 4 - 烷基,U 2是C 1 -C 4 - 烷基,苯基 ,C 2 -C 10 - 烯基或基团,其中Q 5和Q 6各自独立地为氢或C 1 -C 4 - 烷基,Q 7为在碱性反应条件下可分离的基团,w为0,1或2 ,t为0,1或2,v为1或2,X和L各自如说明书中所定义,条件是两个基团U1和U2中的至少一个不是C 1 -C 4 - 烷基或苯基, 并且由式为“IMAGE”的苄基化合物制备,其中A是硝基或氨基,并且U1,Z和t各自如上所定义。 活性染料可用于染色含有羟基的纤维如棉和羊毛,并提供高产率和高耐湿牢度。