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    • 5. 发明申请
    • STABILIZER MIXTURE
    • 稳定剂混合物
    • US20100160502A1
    • 2010-06-24
    • US12160724
    • 2007-01-12
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • C08K5/3435
    • C08K5/3435C07B63/04C07D211/58C08K5/34C08K2201/014C08L23/12C08L2201/08C09D7/48C09K15/20C09K15/30
    • Suitable stabilizers for organic material are a mixture comprising A. at least one oligomeric compound, comprising repeat units of the formula (I), in which the meanings of the symbols are as follows: R1 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5-C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula —CR′═CH—CO—OR″, where R′ is hydrogen, C1-C6-alkyl or a radical of the formula —CO—OR″, and R″ is C1-C18-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl, or tolyl; R2 is a mixture composed of C14-C28-alkyl groups, where two of these alkyl groups whose number of carbon atoms is not permitted to differ by more than two respectively make up at least 30% of this mixture; R3 and R4, independently of one another, are C1-C6-alkyl; and B. at least one compound of the formula (II) or (III) where the meanings of the symbols and indices are as follows: n and m, independently of one another, are a natural number from 2 to 22, and R1, R3 and R4, independently of one another, have the meanings given in formula (I).
    • 用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物,其包含式(I)的重复单元,其中符号的含义如下:R 1是氢,C 1 -C 6 - 烷基,甲酰基, C 2 -C 6 - 烷酰基,C 1 -C 12 - 烷氧基,C 5 -C 6 - 环烷氧基,氰基甲基,2-羟基乙基,苄基或式-CR'≡CH-CO-OR的基团,其中R'是氢,C1- C6烷基或式-CO-OR基团,R“为C1-C18-烷基,C5-C8-环烷基,C7-C18-芳烷基,苯基或甲苯基; R2是由C14-C28-烷基组成的混合物,其中不允许两个以上碳原子数不同的这些烷基中的两个分别构成该混合物的至少30% R 3和R 4彼此独立地为C 1 -C 6 - 烷基; 和B.至少一种式(II)或(III)的化合物,其中符号和指数的含义如下:n和m彼此独立地是2至22的自然数,并且R 1, R 3和R 4彼此独立地具有式(I)中给出的含义。
    • 6. 发明授权
    • Use of isoindolinone derivatives as stabilizers for organic materials
    • 异吲哚啉酮衍生物作为有机材料的稳定剂的使用
    • US06210657B1
    • 2001-04-03
    • US09207624
    • 1998-12-09
    • Thorsten HabeckSylke HaremzaHubert TrauthVolker SchehlmannHorst Westenfelder
    • Thorsten HabeckSylke HaremzaHubert TrauthVolker SchehlmannHorst Westenfelder
    • A61K742
    • A61K31/4035C08K5/3417C09D7/48C09K15/30Y10S514/844Y10S514/97Y10S514/972
    • Isoindolinone derivatives of the formula I, in which the variables have the following meanings: R1 is hydrogen, COOR4, COR4, CONR4R5, CN, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, aryl or heteroaryl, substituted or unsubstituted; R1 and R2 together are C7-C10-bicycloalkyl or C7-C10-bicycloalkenyl; R3 is hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl or heteroaryl, substituted or unsubstituted, substituents which confer solubility in water, selected from the group consisting of carboxylate, sulfonate or ammonium radicals; R4 and R5 independently of one another are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl; aryl or heteroaryl, substituted or unsubstituted; are used as stabilizers for organic materials.
    • 式I的异吲哚啉酮衍生物,其中变量具有以下含义:R1是氢,COOR4,COR4,CONR4R5,CN,C1-C20-烷基,C2-C10-烯基,C3-C10-环烷基,C3-C10- 环烯基,芳基或杂芳基,取代或未取代的; R1和R2一起是C7-C10-双环烷基或C7-C10-双环烯基; R3是氢,C1-C20-烷基,C2-C10-烯基,C3-C10-环烷基,C3 -C 10 - 环烯基,C 1 -C 12 - 烷氧基,C 1 -C 20 - 烷氧基羰基,C 1 -C 12 - 烷基氨基,C 1 -C 12 - 二烷基氨基,芳基或杂芳基,取代或未取代的赋予水溶性的取代基, 羧酸酯,磺酸酯或铵基; R 4和R 5彼此独立地是氢,C 1 -C 20 - 烷基,C 2 -C 10 - 烯基,C 3 -C 10 - 环烷基,C 3 -C 10 - 环烯基; 芳基或杂芳基,取代或未取代的;被用作有机材料的稳定剂。
    • 9. 发明授权
    • N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine
derivatives
    • N-(β-羰基 - 和β-氰基乙烯基)-2,2,6,6-四甲基 - 哌啶衍生物
    • US5434202A
    • 1995-07-18
    • US244209
    • 1994-06-03
    • Alfred KrauseAlexander AumuellerHubert Trauth
    • Alfred KrauseAlexander AumuellerHubert Trauth
    • C07D211/46C07D211/54C07D211/58C07D401/04C07D405/06C07D409/06C08K5/3432C08K5/3435
    • C07D211/58C07D211/46C08K5/3435
    • N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.
    • PCT No.PCT / EP92 / 02733 Sec。 371日期:1994年6月3日 102(e)日期1994年6月3日PCT提交1992年11月27日PCT公布。 出版物WO93 / 11109 日期:6月10日,1993.N-(β-羰基 - 和β-氰基乙酰基)-2,2,6,6-四甲基哌啶衍生物,其中R1是COOR3,COR4,CONR4R5或CN,R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢,R 3是氢,C 1 -C 8 - 烷基,C 5 -C 8 - 环烷基,C 3 -C 5 - 烯基或苯基,其可以被C1-C4- 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷氧基羰基,卤素,羟基,苯氧基,苯基,甲苯基或二甲苯基,R 4和R 5各自为氢,C 1 -C 12烷基,C 5 -C 8环烷基或苯基, - 被C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷氧基羰基,卤素,羟基,苯氧基,苯基,甲苯基或二甲苯基三取代,n为1-4,各个n的X和A定义 在规范中。