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1. 发明申请

US20100160502A1 STABILIZER MIXTURE 审中-公开
标题翻译：稳定剂混合物
公开(公告)号：US20100160502A1
公开(公告)日：2010-06-24
申请号：US12160724
申请日：2007-01-12
申请人： Simon Schambony , Alban Glaser , Hubert Trauth , Manfred Appel , Sylke Haremza
发明人： Simon Schambony , Alban Glaser , Hubert Trauth , Manfred Appel , Sylke Haremza
IPC分类号： C08K5/3435
CPC分类号： C08K5/3435 , C07B63/04 , C07D211/58 , C08K5/34 , C08K2201/014 , C08L23/12 , C08L2201/08 , C09D7/48 , C09K15/20 , C09K15/30
摘要： Suitable stabilizers for organic material are a mixture comprising A. at least one oligomeric compound, comprising repeat units of the formula (I), in which the meanings of the symbols are as follows: R1 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5-C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula —CR′═CH—CO—OR″, where R′ is hydrogen, C1-C6-alkyl or a radical of the formula —CO—OR″, and R″ is C1-C18-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl, or tolyl; R2 is a mixture composed of C14-C28-alkyl groups, where two of these alkyl groups whose number of carbon atoms is not permitted to differ by more than two respectively make up at least 30% of this mixture; R3 and R4, independently of one another, are C1-C6-alkyl; and B. at least one compound of the formula (II) or (III) where the meanings of the symbols and indices are as follows: n and m, independently of one another, are a natural number from 2 to 22, and R1, R3 and R4, independently of one another, have the meanings given in formula (I).
摘要翻译：用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物，其包含式（I）的重复单元，其中符号的含义如下：R 1是氢，C 1 -C 6 - 烷基，甲酰基， C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 -C 6 - 环烷氧基，氰基甲基，2-羟基乙基，苄基或式-CR'≡CH-CO-OR的基团，其中R'是氢，C1- C6烷基或式-CO-OR基团，R“为C1-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基; R2是由C14-C28-烷基组成的混合物，其中不允许两个以上碳原子数不同的这些烷基中的两个分别构成该混合物的至少30％ R 3和R 4彼此独立地为C 1 -C 6 - 烷基; 和B.至少一种式（II）或（III）的化合物，其中符号和指数的含义如下：n和m彼此独立地是2至22的自然数，并且R 1， R 3和R 4彼此独立地具有式（I）中给出的含义。

2. 发明授权

US08377192B2 Stabilisers for inanimate organic materials 有权
标题翻译：无机有机材料稳定剂
公开(公告)号：US08377192B2
公开(公告)日：2013-02-19
申请号：US13060705
申请日：2009-08-14
申请人： Alban Glaser , Sylke Haremza , Simon Schambony
发明人： Alban Glaser , Sylke Haremza , Simon Schambony
IPC分类号： C09D7/12 , C08K5/3435 , C07D401/12 , C07D211/56
CPC分类号： C07D211/94
摘要： The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
摘要翻译：本发明涉及包含一个或多个通式（I）的基团的空间位阻胺的用途，用于稳定无生命的有机材料，更特别的是塑料或涂料，其中R 1和R 2各自独立地或不同地是H， C 1 -C 20烷基，C 3 -C 15环烷基，芳基，杂芳基或杂环，R 4，R 5，R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基，或R 4和R 6或R 5和R 7一起是四亚甲基或五亚甲基，R 3为芳基或杂芳基。本发明还涉及稳定无生命的有机材料，特别是塑料或涂料的方法。本发明另外提供的是包含一个或多个通式（I）的基团的空间位阻胺。本发明另外提供的是包含选定的空间位阻胺的材料。

3. 发明申请

US20120059095A1 HIGH MOLECULAR WEIGHT NONPOLAR BENZOTRIAZOLES 有权
标题翻译：高分子量非金属苯并噻唑
公开(公告)号：US20120059095A1
公开(公告)日：2012-03-08
申请号：US13266609
申请日：2010-05-11
申请人： Sylke Haremza , Andrea Misske , Simon Schambony , Alban Glaser
发明人： Sylke Haremza , Andrea Misske , Simon Schambony , Alban Glaser
IPC分类号： C08K5/3475 , C08K5/3492 , C07D249/20 , C08L35/00
CPC分类号： C08K5/3475 , C07D249/20 , C07D401/14 , C08F8/00
摘要： The present invention relates to the use of certain benzotriazole derivatives of the general formula (I) where B is an optionally substituted 2-(2-hydroxyphenyl)-2H-benzotriazole group, n is an integer from the range from 3 to 20 and A is an n-valent organic radical, as UV absorber or stabilizer in inanimate organic materials. Furthermore, the invention relates to methods of stabilizing inanimate organic materials, in particular plastics, against the effect of light using specific benzotriazole derivatives. Further subject matters of the invention are certain benzotriazole derivatives and inanimate organic materials comprising certain benzotriazole derivatives.
摘要翻译：本发明涉及通式（I）的某些苯并三唑衍生物的用途，其中B为任选取代的2-（2-羟基苯基）-2H-苯并三唑基，n为3-20的整数，A为是一种n价有机基团，作为无机材料中的紫外线吸收剂或稳定剂。此外，本发明涉及使用特定的苯并三唑衍生物来稳定无生命的有机材料，特别是塑料的方法。本发明的其它主题是某些苯并三唑衍生物和包含某些苯并三唑衍生物的无生命有机材料。

4. 发明授权

US09034955B2 High molecular weight nonpolar benzotriazoles 有权
标题翻译：高分子量非极性苯并三唑
公开(公告)号：US09034955B2
公开(公告)日：2015-05-19
申请号：US13266609
申请日：2010-05-11
申请人： Sylke Haremza , Andrea Misske , Simon Schambony , Alban Glaser
发明人： Sylke Haremza , Andrea Misske , Simon Schambony , Alban Glaser
IPC分类号： C08K5/00 , C08F8/00 , C07D293/00 , C08K5/3475 , C07D249/20 , C07D401/14
CPC分类号： C08K5/3475 , C07D249/20 , C07D401/14 , C08F8/00
摘要： The present invention relates to the use of certain benzotriazole derivatives of the general formula (I) where B is an optionally substituted 2-(2-hydroxyphenyl)-2H-benzotriazole group, n is an integer from the range from 3 to 20 and A is an n-valent organic radical, as UV absorber or stabilizer in inanimate organic materials. Furthermore, the invention relates to methods of stabilizing inanimate organic materials, in particular plastics, against the effect of light using specific benzotriazole derivatives. Further subject matters of the invention are certain benzotriazole derivatives and inanimate organic materials comprising certain benzotriazole derivatives.
摘要翻译：本发明涉及通式（I）的某些苯并三唑衍生物的用途，其中B为任选取代的2-（2-羟基苯基）-2H-苯并三唑基，n为3-20的整数，A为是一种n价有机基团，作为无机材料中的紫外线吸收剂或稳定剂。此外，本发明涉及使用特定的苯并三唑衍生物来稳定无生命的有机材料，特别是塑料的方法。本发明的其它主题是某些苯并三唑衍生物和包含某些苯并三唑衍生物的无生命有机材料。

5. 发明申请

US20110214590A1 STABILISERS FOR INANIMATE ORGANIC MATERIALS 有权
标题翻译：用于有机材料的稳定剂
公开(公告)号：US20110214590A1
公开(公告)日：2011-09-08
申请号：US13060705
申请日：2009-08-14
申请人： Alban Glaser , Sylke Haremza , Simon Schambony
发明人： Alban Glaser , Sylke Haremza , Simon Schambony
IPC分类号： C09D7/12 , C08K5/3435 , C07D401/12 , C07D401/04 , C07D211/56
CPC分类号： C07D211/94
摘要： The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
摘要翻译：本发明涉及包含一个或多个通式（I）的基团的空间位阻胺的用途，用于稳定无生命的有机材料，更特别的是塑料或涂料，其中R 1和R 2各自独立地或不同地是H， C 1 -C 20烷基，C 3 -C 15环烷基，芳基，杂芳基或杂环，R 4，R 5，R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基，或R 4和R 6或R 5和R 7一起是四亚甲基或五亚甲基，R 3为芳基或杂芳基。本发明还涉及稳定无生命的有机材料，特别是塑料或涂料的方法。本发明另外提供的是包含一个或多个通式（I）的基团的空间位阻胺。本发明另外提供的是包含选定的空间位阻胺的材料。

6. 发明授权

US06214929B1 Stabilized polymer dispersions or polymer solutions, and prepared polymers obtainable therefrom 失效
标题翻译：稳定的聚合物分散体或聚合物溶液，以及由其获得的制备的聚合物
公开(公告)号：US06214929B1
公开(公告)日：2001-04-10
申请号：US09265704
申请日：1999-03-10
申请人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Joachim Pakusch , Heinrich Sack
发明人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Joachim Pakusch , Heinrich Sack
IPC分类号： C08K500
CPC分类号： C08K5/005 , C09D7/48 , C09J11/06
摘要： A polymer is obtained by removing the medium from a polymer dispersion or polymer solution containing at least one polymeric phase and at least one stabilizer suitable to protect against the damaging effect of light, heat and/or oxidation.
摘要翻译：通过从包含至少一个聚合物相和至少一种适于防止光，热和/或氧化的破坏作用的至少一种稳定剂的聚合物分散体或聚合物溶液中除去介质来获得聚合物。

7. 发明授权

US06737527B2 4-formylamino-N-methylpiperidine derivatives, the use thereof as stabilizers and organic material stabilized therewith 有权
标题翻译： 4-甲酰氨基-N-甲基哌啶衍生物，其作为稳定剂的用途和用其稳定的有机物质
公开(公告)号：US06737527B2
公开(公告)日：2004-05-18
申请号：US10239213
申请日：2002-09-27
申请人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Alexander Aumüller
发明人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Alexander Aumüller
IPC分类号： C07D21158
CPC分类号： C07D211/58 , C08K5/3435 , C09D7/48
摘要： The present invention relates to 4-formylamino-N-methylpiperidine derivatives of the formula (I) where the variables are as defined in the Description, to a process for preparing these piperidine derivatives, to the use of these piperidine derivatives of the invention, or prepared according to the invention, for stabilizing organic material, in particular for stabilizing plastics or coating materials, and also to the use of these piperidine derivatives of the invention, or prepared according to the invention, as light stabilizers or stabilizers for wood surfaces. The present invention further relates to stabilized organic material which comprises these piperidine derivatives of the invention or prepared according to the invention.
摘要翻译：本发明涉及式（I）的4-甲酰基氨基-N-甲基哌啶衍生物，其中变量如说明书中所定义，涉及制备这些哌啶衍生物的方法，使用本发明的这些哌啶衍生物，或根据本发明制备的，用于稳定有机材料，特别是用于稳定塑料或涂层材料，以及本发明的这些哌啶衍生物或根据本发明制备的用作木材表面的光稳定剂或稳定剂的用途。本发明还涉及包含本发明的或根据本发明制备的这些哌啶衍生物的稳定的有机材料。

8. 发明授权

US06908956B2 Stabilizer composition 失效
标题翻译：稳定剂组成
公开(公告)号：US06908956B2
公开(公告)日：2005-06-21
申请号：US10181439
申请日：2001-01-31
申请人： Heinz Friedrich Sutoris , Sylke Haremza , Hubert Trauth , Erik Hofmann , Manfred Appel
发明人： Heinz Friedrich Sutoris , Sylke Haremza , Hubert Trauth , Erik Hofmann , Manfred Appel
IPC分类号： C08K5/00 , C08K5/34 , C08K5/3435 , C08K5/56 , C08L23/00 , C08L25/04 , C08L101/00 , C09K15/20 , C09K15/22 , C09K15/30 , C09K15/32 , C08K5/357 , C08K5/3415 , C08K5/3462 , C08K5/3477 , C08K5/3492
CPC分类号： C08K5/0091 , C08K5/34 , C08K5/3435 , C09K15/30 , C09K15/326
摘要： A description is given of a stabilizer composition comprising A) at least one nitrogen compound having a molecular weight of at least 150, selected from a secondary amine in which all substituents positioned α to the amine nitrogen atom are different than hydrogen, or, derived from the secondary amine, a tertiary amine, hydroxylamine, alkoxyamine or amide; and B) at least one iron compound. The stabilizer composition optionally comprises nitroxyl radicals. It is suitable for stabilizing nonliving organic material, especially polyolefins or homopolymers or copolymers of styrene, against the effects of light, heat or oxygen.
摘要翻译：给出了一种稳定剂组合物的描述，其包括A）至少一种分子量至少为150的氮化合物，其选自仲胺，其中所有位于胺氮原子的α-取代基不同于氢，或衍生自仲胺，叔胺，羟胺，烷氧基胺或酰胺; 和B）至少一种铁化合物。稳定剂组合物任选地包含硝酰基。适用于稳定非活性有机材料，尤其是聚苯乙烯的聚烯烃或苯乙烯的均聚物或共聚物与光，热或氧的作用。

9. 发明授权

US08747804B2 Modified zinc oxide particles 有权
标题翻译：改性氧化锌颗粒
公开(公告)号：US08747804B2
公开(公告)日：2014-06-10
申请号：US13054636
申请日：2009-07-14
申请人： Andrey Karpov , Hartmut Hibst , Simon Schambony , Richard Riggs , Sylke Haremza
发明人： Andrey Karpov , Hartmut Hibst , Simon Schambony , Richard Riggs , Sylke Haremza
IPC分类号： C01G9/02
CPC分类号： C09C1/043 , C01G9/02 , C01P2002/84
摘要： Process for the preparation of modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and, if appropriate after the precipitation of a precipitation product, the polar solvent is removed and a residue is obtained, where the residue is taken up in a nonpolar solvent, surface-active substances are added, optionally further effect substances are added and then the modified ZnO particles are separated off from further by-products. Materials such as plastics, coatings or paints comprising modified ZnO particles. Methods for the incorporation of modified ZnO particles into materials, where the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions. Use of modified ZnO particles for protecting material against the effect of light, heat, oxygen or free radicals, as catalysts, for semiconductive films or cosmetic applications.
摘要翻译：制备其中将锌盐和碱在极性溶剂中混合的改性ZnO颗粒的制备方法，并且如果适当，在析出产物沉淀后，除去极性溶剂，得到残留物，其中残留物被在非极性溶剂中加入表面活性物质，任选地添加另外的效果物质，然后将改性的ZnO颗粒与进一步的副产物分离。诸如塑料，涂料或包含改性ZnO颗粒的涂料的材料。将改性的ZnO颗粒引入到材料中的方法，其中将改性的ZnO颗粒以分散体或悬浮液的形式引入材料中。使用改性ZnO颗粒来保护材料免受光，热，氧或自由基作为半导体膜或化妆品应用的催化剂的影响。

10. 发明申请

US20110130273A1 MODIFIED ZINC OXIDE PARTICLES 有权
标题翻译：改性氧化锌颗粒
公开(公告)号：US20110130273A1
公开(公告)日：2011-06-02
申请号：US13054636
申请日：2009-07-14
申请人： Andrey Karpov , Hartmut Hibst , Simon Schambony , Richard Riggs , Sylke Haremza
发明人： Andrey Karpov , Hartmut Hibst , Simon Schambony , Richard Riggs , Sylke Haremza
IPC分类号： C07F3/06 , B01J23/06 , C09K15/32
CPC分类号： C09C1/043 , C01G9/02 , C01P2002/84
摘要： Process for the preparation of modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and, if appropriate after the precipitation of a precipitation product, the polar solvent is removed and a residue is obtained, where the residue is taken up in a nonpolar solvent, surface-active substances are added, optionally further effect substances are added and then the modified ZnO particles are separated off from further by-products. Materials such as plastics, coatings or paints comprising modified ZnO particles. Methods for the incorporation of modified ZnO particles into materials, where the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions. Use of modified ZnO particles for protecting material against the effect of light, heat, oxygen or free radicals, as catalysts, for semiconductive films or cosmetic applications.
摘要翻译：制备其中将锌盐和碱在极性溶剂中混合的改性ZnO颗粒的制备方法，并且如果适当，在析出产物沉淀后，除去极性溶剂，得到残留物，其中残留物被在非极性溶剂中加入表面活性物质，任选地添加另外的效果物质，然后将改性的ZnO颗粒与进一步的副产物分离。诸如塑料，涂料或包含改性ZnO颗粒的涂料的材料。将改性的ZnO颗粒引入到材料中的方法，其中将改性的ZnO颗粒以分散体或悬浮液的形式引入材料中。使用改性ZnO颗粒来保护材料免受光，热，氧或自由基作为半导体膜或化妆品应用的催化剂的影响。

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