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    • 2. 发明授权
    • Benzimidazole-2-carboxanilides
    • 苯并咪唑-2-甲酰苯胺
    • US4981975A
    • 1991-01-01
    • US392300
    • 1989-08-11
    • Peter SpangPeter NeumannHubert Trauth
    • Peter SpangPeter NeumannHubert Trauth
    • C07D235/24C07D405/06C07D405/12C08K5/3442C08K5/3447C09D5/00C09D7/12C09K3/00
    • C07D235/24C07D405/06C08K5/3447
    • Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are each H, Cl, alkyl, alkoxy, unsubstitued or alkyl- or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 are each H, uninterrupted or --O-- interrupted alkyl or alkoxy, unsubstituted or alkyl- or alkoxy-substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy hydroxyalkyl, hydroxyalkoxy, alkylcarbonylamino, alkanoyloxy, benzoylamino or benzoyloxy, X is alkylene, n is 1 or 2 and where--if n is 1--R.sup.5 is Cl, --OR.sup.6 or --NR.sup.7 R.sup.8 or--if n is 2--R.sup.5 is --O--R.sup.12 --O-- or --N(R.sup.9)--R.sup.13 --N(R.sup.9)-- where R.sup.6 is H, unsubstituted, OH-- or alkanoyloxy-substituted alkyl whose carbon chain may be interrupted by --O-- or --N(R.sup.9)--, cycloalkyl, alkenyl, phenylalkyl, phenoxyethyl, hydroxy alkyl, phenylhydroxyalkyl or glycidyl, R.sup.7 and R.sup.8 are H, alkyl, cycloalkyl, phenyl, naphthyl, alkenyl, phenylalkyl, hydroxyalkyl or --NR.sup.7 R.sup.8, a saturated 5- or 6- membered heterocycle, R.sup.9 is alkyl, cycloalkyl, alkenyl, phenyl, naphthyl or phenylalkyl, R.sup.12 is alkylene, alkenylene, cyclohexylene, oxaalkylene and R.sup.13 is alkylene, oxaalkylene, diphenylenemethane or dicyclohexylenemethane or --N(R.sup.9)--R.sup.13 --N(R.sup.9)-- is piperazinylene, are excellent light stabilizers for organic materials such as polymers and coating binders.
    • 式(I)的苯并咪唑化合物酰胺(I)其中R 1和R 2各自为H,Cl,烷基,烷氧基,未取代或烷基或烷氧基取代的苯基或苯基烷基,R 3和R 4各自为H,不间断或-O - 中间的烷基或烷氧基,未取代的或烷基 - 或烷氧基取代的苯基,苯基烷基,苯氧基,苯基烷氧基羟烷基,羟基烷氧基,烷基羰基氨基,烷酰氧基,苯甲酰氨基或苯甲酰氧基,X是亚烷基,n是1或2,其中如果n是1- R5是Cl,-OR6或-NR7R8,或 - 如果n是2-R5是-O-R12-O-或-N(R9)-R13-N(R9) - ,其中R6是H,未取代的OH-或烷酰氧基 其中碳链可以被-O-或-N(R 9) - ,环烷基,烯基,苯基烷基,苯氧基乙基,羟基烷基,苯基羟基烷基或缩水甘油基间隔的取代烷基,R7和R8是H,烷基,环烷基,苯基,萘基, 烯基,苯基烷基,羟基烷基或-NR 7 R 8,饱和的5-或6-元杂环,R 9为烷基,环烷基,烯基,苯基,萘基或苯基烷基,R 12为亚烷基, 烯,亚环己基,氧杂亚烷基和R 13是亚烷基,氧杂亚烷基,二苯基甲烷或二环己基甲烷或-N(R 9)-R 13 -N(R 9) - 是亚哌啶基,是有机材料如聚合物和涂料粘合剂的优异的光稳定剂。
    • 5. 发明授权
    • Benzimidazole-2-carboxanilides
    • 苯并咪唑-2-甲酰苯胺
    • US4985566A
    • 1991-01-15
    • US525049
    • 1990-05-18
    • Peter SpangPeter NeumannHubert Trauth
    • Peter SpangPeter NeumannHubert Trauth
    • C07D235/24C07D405/06C07D405/12C08K5/3442C08K5/3447C09D5/00C09D7/12C09K3/00
    • C07D235/24C07D405/06C08K5/3447
    • Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are each H, Cl, alkyl, alkoxy, unsubstituted or alkyl-- or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 are each H, uninterrupted or --O-- interrupted alkyl or alkoxy, unsubstituted or alkyl-- or alkoxy-substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy, hydroxyalkyl, hydroxyalkoxy, alkylcarbonylamino, alkanoyloxy, benzoylamino or benzoyloxy, X is alkylene, n is 1 or 2 and where--if n is 1--R.sup.5 is Cl, --OR.sup.6 or --NR.sup.4 R.sup.8 or--if n is 2--R.sup.5 is --O--R.sup.12 --O-- or --N(R.sup.9)--R.sup.13 --N(R.sup.9 --where R.sup.6 is H, unsubstituted, OH-- or alkanoyloxy-substituted alkyl whose carbon chain may be interrupted by --O-- or --N(R.sup.9)--, cycloalkyl, alkenyl, phenylalkyl, phenoxyethyl, hydroxy alkyl, phenylhydroxyalkyl or glycidyl, R.sup.7 and R.sup.8 are H, alkyl, cycloalkyl, phenyl, naphthyl, alkenyl, phenylalkyl, hydroxyalkyl or --NR.sup.7 R.sup.8, a saturated 5- or 6-membered heterocycle, R.sup.9 is alkyl, cycloalkyl, alkenyl, phenyl, naphthyl or phenylalkyl, R.sup.12 is alkylene, alkenylene, cyclohexylene, oxaalkylene and R.sup.13 is alkylene, oxaalkylene, diphenylenemethane or dicyclohexylenemethane or --N(R.sup.9)--R.sup.13 --N(R.sup.9)- is piperazinylene, are excellent light stabilizers for organic materials such as polymers and coating binders.
    • 6. 发明授权
    • 2,6-polyalkylpiperidine-substituted benzimidazole-2-carboxanilides and
their use for stabilizing organic material
    • 2,6-二烷基哌啶取代的苯并咪唑-2-羧酰苯胺及其用于稳定有机物质的用途
    • US4940742A
    • 1990-07-10
    • US392598
    • 1989-08-11
    • Alexander AumuellerPeter SpangPeter NeumannHubert Trauth
    • Alexander AumuellerPeter SpangPeter NeumannHubert Trauth
    • C07D401/12C08K5/3442C08K5/3447C09D7/12
    • C07D401/12
    • Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, chlorine, bromine, alkyl, alkoxy, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 independently of one another are each hydrogen, alkyl, alkyl which is interrupted by one or more oxygen atoms, alkoxy, alkoxy which is interrupted by one or more oxygen atoms, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl, phenylalkoxy, alkanoylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 0, 1, 2, 3, 4 or 5, X is oxygen, ##STR2## R.sup.5 is hydrogen, alkyl, phenylalkyl, cyanomethyl, aminoethyl, hydroxyethyl, alkylcarbonyl or benzoyl, R.sup.6 is hydrogen, alkyl, phenylalkyl or phennyl and m is from 2 to 8, and the acid addition salts and hydrates of these compounds are stabilizers for organic material, in particular for plastics, such as polyethylene, polypropylene and polyamide.
    • 其中R 1和R 2彼此独立地为氢,氯,溴,烷基,烷氧基,未取代或烷基取代或烷氧基取代的苯基或苯基烷基,R3和R4独立地为(I)的苯并咪唑化合物酰胺 另一个为氢,烷基,被一个或多个氧原子间隔的烷基,烷氧基,被一个或多个氧原子间隔的烷氧基,未取代的或烷基取代的或烷氧基取代的苯基,苯基烷氧基,烷酰基氨基,苯甲酰氨基, 烷酰氧基或苯甲酰氧基,n为0,1,2,3,4或5,X为氧,R 5为氢,烷基,苯基烷基,氰基甲基,氨基乙基,羟基乙基,烷基羰基或苯甲酰基 R6为氢,烷基,苯基烷基或苯基,m为2-8,并且这些化合物的酸加成盐和水合物是有机材料的稳定剂,特别是用于塑料如聚乙烯,聚丙烯和聚酰胺的稳定剂。
    • 9. 发明授权
    • Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials
    • 双酚(3.3.1)壬烷衍生物,用于稳定有机物质
    • US4943391A
    • 1990-07-24
    • US286295
    • 1988-12-10
    • Alexander AumuellerPeter NeumannHubert Trauth
    • Alexander AumuellerPeter NeumannHubert Trauth
    • C07D471/08C08K5/34C08K5/3412C08K5/3442C09D7/12C09K15/18
    • C07D471/08
    • Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.
    • 双环[3.3.1]通式(I)的壬烷衍生物其中n是1至70的整数,R 1是氢,R 2是氢或羟基,或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基,该苯基或萘基各自可被1,2或3个C 1 -C 12烷基,C 1 -C 12烷氧基,氯,溴,氟,三氟甲基或氰基取代 在2或3个取代基的情况下,这些取代基相同或不同,A和B各自独立地为化学键,C 1 -C 22 - 亚烷基,亚环烷基,其中m和o分别为 1至20,R 10为氢,C 1 -C 22 - 烷基,C 5 -C 12 - 环烷基,C 7 -C 18 - 苯基烷基,苯基或C 2 -C 22 - 氰基烷基,M为式 A不仅通过氮原子而且通过碳原子,并且R 11,R 12,R 13和R 14各自独立地为C 1 -C 4 - 烷基,或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基,R 5是氢,氰基,羟基,R 15是氢,C 1 -C 22 - 烷基,C 5 -C 12 - 环烷基,C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时,-MB-R 5为式(VI)的基团,其中R 16为C 1 -C 4 - 烷基,R 17为氢,C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基,在塑料方面具有非常好的稳定性,是无色的,与有机聚合物高度相容并且对热分解是稳定的。