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1. 发明申请

US20100252820A1 LIGHT EMITTING CU (I) COMPLEXES 有权
标题翻译：发光CU（I）复合物
公开(公告)号：US20100252820A1
公开(公告)日：2010-10-07
申请号：US12663769
申请日：2008-06-13
申请人： Luisa De Cola , Yinghui Sun , Franz Schwarzenbach , Roger Pretot
发明人： Luisa De Cola , Yinghui Sun , Franz Schwarzenbach , Roger Pretot
IPC分类号： H01L51/54 , H01L51/56 , C07F1/08 , C07D401/04
CPC分类号： C07F9/5045 , C07D401/04 , C07F1/005 , C09K11/06 , C09K2211/188 , H01L51/0091 , H01L51/5012 , H01L51/5048
摘要： Electroneutral metal complexes of the formula L Cu A, wherein L stands for an, especially bidentate, neutral ligand and A stands for an, especially bidentate, monoanionic ligand binding to Cu by at least one heteroatom selected from N, P, S; or wherein the ligands L and A with the above features are interconnected by at least one chemical bond to form one common tetradentate ligand; or protonated or alkylated forms or salts thereof show good light emitting efficiency in electroluminescent applications.
摘要翻译：式L Cu A的电子中间体金属络合物，其中L代表特别是二齿的中性配体，A代表通过至少一个选自N，P，S的杂原子与Cu结合的特别是二齿的单阴离子配体; 或其中具有上述特征的配体L和A通过至少一个化学键相互连接以形成一个共同的四齿配体; 或质子化或烷基化形式或其盐在电致发光应用中显示出良好的发光效率。

2. 发明申请

US20090062560A1 Electroluminescent Metal Complexes With Triazoles 有权
标题翻译：电子发光金属配合物与三唑
公开(公告)号：US20090062560A1
公开(公告)日：2009-03-05
申请号：US12086646
申请日：2006-12-18
申请人： Roger Pretot , Roman Kolly , Thomas Schafer , Paul Adriaan Van Der Schaaf
发明人： Roger Pretot , Roman Kolly , Thomas Schafer , Paul Adriaan Van Der Schaaf
IPC分类号： C07F17/02
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14
摘要： Disclosed are electroluminescent metal complexes with triazoles of the formula (I), where n1 is an integer of 1 to 3, m1 and m2 each are an integer 0, 1 or 2, M1 is a metal with an atomic weight of greater than 40, L1 is a monodentate ligand or a bidentate ligand, L2 is a monodentate ligand, Q2 stands for an organic bridging group completing, together with the bonding carbon atoms of the triazole ring, an annellated, carbocyclic or heterocyclic, non-aromatic ring, which optionally may be substituted, Q3 represents a group of forming a condensed aromatic, or heteroaromatic ring, which can optionally be substituted, as well as new intermediates for the preparation of these complexes, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：公开了具有式（I）的三唑的电致发光金属络合物，其中n1为1〜3的整数，m1和m2各自为整数0,1或2，M1为原子量大于40的金属， L1是单齿配体或二齿配体，L2是单齿配体，Q2表示完全有机桥基，连同三唑环的键合碳原子，环状的，碳环或杂环的非芳香环，其任选地可以被取代，Q3表示形成稠合芳族或可以任意被取代的杂芳环的基团，以及用于制备这些络合物的新中间体，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED）作为氧敏感指标，作为生物测定中的磷光指示剂，以及作为催化剂。

3. 发明申请

US20080015355A1 Electroluminescent Metal Complexes With Triazoles And Benzotriazoles 有权
标题翻译：电致发光金属配合物与三唑和苯并三唑
公开(公告)号：US20080015355A1
公开(公告)日：2008-01-17
申请号：US11629573
申请日：2005-06-20
申请人： Thomas Schafer , Kristina Bardon , Beat Schmidhalter , Roger Pretot
发明人： Thomas Schafer , Kristina Bardon , Beat Schmidhalter , Roger Pretot
IPC分类号： C07F15/00 , C07D249/18 , G09G3/30
CPC分类号： H01L51/0084 , C09K11/06 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/5012
摘要： This invention relates to electroluminescent metal complexes with triazoles and benzotriazoles, respectively of the formula (I) a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及分别具有式（I）的三唑和苯并三唑的电致发光金属络合物，其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指标，作为生物测定中的磷光指标，并作为催化剂。

4. 发明申请

US20110086454A1 DIBENZOFURANE POLYMERS FOR ELECTROLUMINISCENT DEVICES 有权
标题翻译：用于电致发光器件的二苯并呋喃聚合物
公开(公告)号：US20110086454A1
公开(公告)日：2011-04-14
申请号：US12994887
申请日：2009-05-19
申请人： Natalia Chebotareva , Roger Pretot , Paul Adriaan Van Der Schaaf , Annemarie Wolleb , Heinz Wolleb
发明人： Natalia Chebotareva , Roger Pretot , Paul Adriaan Van Der Schaaf , Annemarie Wolleb , Heinz Wolleb
IPC分类号： H01L51/40 , C08F124/00 , C08F130/04 , C07D307/91 , C07F7/08 , C07F9/655 , C07F7/30 , C09K11/06
CPC分类号： C09K11/02 , C07D307/91 , C09K2211/145 , H01L51/004 , H01L51/0073 , H01L51/5012 , H05B33/20
摘要： Disclosed are electroluminescent materials comprising a homopolymer based on recurring structural units of the formula (I) wherein R9, R9′ R9″, R11, R13′ R14, R11′, R13′, R14′ independently are H or an organic substituent, where at least one of R9, R9′ R9″, R11, R13 R14, R11′, R13′, R14′ comprises a group R10 of the formula —(Sp)x10-[PG′]
摘要翻译：公开了包含基于式（I）的重复结构单元的均聚物的电致发光材料，其中R 9，R 9'R 9“，R 11，R 13'R 14，R 11'，R 13'，R 14'独立地为H或有机取代基， R9，R9'R9“，R11，R13R14，R11'，R13'，R14'中的至少一个包含式 - （Sp）x10- [PG'] <其中Sp为二价有机间隔基的基团R10，PG '是衍生自可聚合基团的基团，x10为0或1，具有如权利要求1中所定义的取代基和间隔基。还公开了一类新型聚合物以及用于其制备的单体。均聚物有利地用作进一步包含发光组分的器件中的主体材料，发光组分通常选自磷光金属络合物和荧光掺杂剂。

5. 发明申请

US20050096406A1 Reactive diluents and alkyd resin coating compositions 审中-公开
标题翻译：活性稀释剂和醇酸树脂涂料组合物
公开(公告)号：US20050096406A1
公开(公告)日：2005-05-05
申请号：US10504239
申请日：2003-02-25
申请人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
发明人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
IPC分类号： C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C09D4/00 , C09D5/00 , C09D7/00 , C09D7/12 , C09D11/02 , C09D11/10 , C09D167/08 , C08G2/00
CPC分类号： C09D11/101 , C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C07C2601/08 , C07C2602/22 , C09D167/08
摘要： The invention relates to new reactive diluents of the formulae (Ia, Ib, Ic, Id, Ie) and to an alkyd coating composition comprising them. In a preferred embodiment R1 and R2 are hydrogen; R3 is (meth)acryloyloxy-methyl or phenyl para substituted by vinyl, R4 is phenyl or phenyl para substituted by vinyl or (meth)acryloyloxy; or a substituted phenyl residue of the formula —C6H4CH2—W, wherein W is (meth)acryloyloxy, or an aliphatic residue of the formula —CH2—Y-A, wherein Y is a bond, O—C1-C12alkylene, wherein the alkylene linker is linear or branched and may be interrupted once or more than once by oxygen, A is hydroxy, C1-C6alkoxy, acetoxy, (meth)acryloyloxy, or a phthalate- or maleate-residue; R5 is hydrogen; n is 1; X is —(CH2)—. The invention further relates to a solvent-based or water-based alkyd coating composition comprising 0.3 to 10 wt. % of a mono-, bis- or trisacylphosphinoxide photoinitiator, especially Irgacure 819.
摘要翻译：本发明涉及式（Ia，Ib，Ic，Id，Ie）的新型反应性稀释剂和包含它们的醇酸树脂涂料组合物。在优选的实施方案中，R 1和R 2是氢; R 3是（甲基）丙烯酰氧基 - 甲基或被乙烯基取代的对苯基，R 4是苯基或被乙烯基或（甲基）丙烯酰氧基取代的对苯基; 或式-C 6 H 2 CH 2 -W的取代的苯基，其中W是（甲基）丙烯酰氧基或脂族基式-CH 2 -YA的残基，其中Y是一个键，OC 1 -C 12亚烷基，其中亚烷基接头是直链的或分支，并且可以被氧中断一次或多于一次，A是羟基，C 1 -C 6烷氧基，乙酰氧基，（甲基）丙烯酰氧基或邻苯二甲酸酯 - 或马来酸盐残基; R 5是氢; n为1; X是 - （CH 2） - 。本发明还涉及一种溶剂型或水性醇酸涂料组合物，其包含0.3至10wt。％的单，双或三酰基次膦酰基光引发剂，特别是Irgacure 819。

6. 发明授权

US08685541B2 Dibenzofurane polymers for electroluminiscent devices 有权
标题翻译：用于电致发光器件的二苯并呋喃聚合物
公开(公告)号：US08685541B2
公开(公告)日：2014-04-01
申请号：US12994887
申请日：2009-05-19
申请人： Natalia Chebotareva , Roger Pretot , Paul Adriaan Van Der Schaaf , Annemarie Wolleb , Heinz Wolleb
发明人： Natalia Chebotareva , Roger Pretot , Paul Adriaan Van Der Schaaf , Annemarie Wolleb , Heinz Wolleb
IPC分类号： H01L51/54
CPC分类号： C09K11/02 , C07D307/91 , C09K2211/145 , H01L51/004 , H01L51/0073 , H01L51/5012 , H05B33/20
摘要： Disclosed are electroluminescent materials comprising a homopolymer based on recurring structural units of the formula (I) wherein R9, R9′ R9″, R11, R13 R14, R11′, R13′, R14′ independently are H or an organic substituent, where at least one of R9, R9′ R9″, R11, R13 R14, R11′, R13′, R14′ comprises a group R10 of the formula —(Sp)x10-[PG′]
摘要翻译：公开了包含基于式（I）的重复结构单元的均聚物的电致发光材料，其中R9，R9'R9“，R11，R13R14，R11'，R13'，R14'独立地为H或有机取代基，其中至少其中R 9，R 9'R 9“，R 11，R 13 R 14，R 11'，R 13'，R 14'中的一个包括式 - （Sp）x10- [PG']其中Sp为二价有机间隔基，是衍生自可聚合基团的基团，x10为0或1，具有如权利要求1所定义的取代基和间隔基。还公开了一类新型聚合物以及其制备用单体。均聚物有利地用作进一步包含发光组分的器件中的主体材料，发光组分通常选自磷光金属络合物和荧光掺杂剂。

7. 发明申请

US20130228771A1 SEMICONDUCTOR STRUCTURE AND METHOD FOR ITS PRODUCTION 审中-公开
标题翻译：半导体结构及其生产方法
公开(公告)号：US20130228771A1
公开(公告)日：2013-09-05
申请号：US13988392
申请日：2011-12-19
申请人： Tero Mustonen , Roger Pretot , Tomi Hassinen
发明人： Tero Mustonen , Roger Pretot , Tomi Hassinen
IPC分类号： H01L51/05
CPC分类号： H01L51/057 , C09B57/004 , C09B69/109 , H01L51/0036 , H01L51/0043 , H01L51/0508
摘要： The present invention relates to a semiconductor structure and a method for its production, the semiconductor structure comprising at least one conductor region 9 and at least two semiconductor regions (30,40), which semiconductor regions are partly separated by the at least one conductor region. The at least one conductor region comprises openings (22) extending between the semiconductor regions which are partly separated by the respective conductor region. The semiconductor regions comprise at least one organic semiconductor material having a specific HOMO energy level, in particular a DPP polymer. The conductor region comprises a conductive material having a specific work function, said combination of specific energy level and work function allowing for a simple preparation of the conductive region. The invention further relates to a method for providing such a semiconductor structure.
摘要翻译：半导体结构及其制造方法技术领域本发明涉及半导体结构及其制造方法，所述半导体结构包括至少一个导体区域9和至少两个半导体区域（30,40），所述半导体区域被所述至少一个导体区域。至少一个导体区域包括在由相应的导体区域部分分开的半导体区域之间延伸的开口（22）。半导体区域包括至少一种具有特定HOMO能级的有机半导体材料，特别是DPP聚合物。导体区域包括具有特定功函数的导电材料，比能量水平和功函数的组合允许简单地制备导电区域。本发明还涉及一种用于提供这种半导体结构的方法。

8. 发明申请

US20090253930A1 Manufacture of Esters 有权
标题翻译：酯类制造
公开(公告)号：US20090253930A1
公开(公告)日：2009-10-08
申请号：US12084752
申请日：2006-11-09
申请人： John Colin Dunn , Dinesh Mistry , Martin Gower , Roger Pretot , Markus Schmid
发明人： John Colin Dunn , Dinesh Mistry , Martin Gower , Roger Pretot , Markus Schmid
IPC分类号： C07C229/00
CPC分类号： C07C213/06 , Y02P20/127 , C07C219/08
摘要： The invention relates to a process in which a compound R1COOR3 (I) is made by a transesterification reaction of an ester compound R1COOR2 (II) with an alcohol R3OH (III) in the presence of a transesterification catalyst, wherein R1 is H or C1-4 alkyl or CH2═CR4—; R2 is C1-4 alkyl; R3 is selected from the group consisting of alkyl having at least 4 carbon atoms, cycloalkyl having at least 5 carbon atoms, aryl, aralkyl, alkaryl and amino alkyl; and R4 is —H or —C1-4 alkyl, wherein alcohol R2OH (IV) is formed as a byproduct and in which said byproduct (IV) is removed by distillation in the presence of an entrainer, in which the entrainer is a compound that suppresses the formation of an azeotrope between compound (II) and byproduct (IV). The process can be useful in the preparation of esters such as dimethyl amino ethyl(meth)acrylate. The invention also provides a method of separating alcohols and esters. In a further form of the invention a process of preparing esters by a transesterification process is provided in which the transesterification catalyst is homogenous.
摘要翻译：本发明涉及在酯交换催化剂存在下，通过酯化合物R1COOR2（II）与醇R3OH（Ⅲ）的酯交换反应制备化合物R1COOR3（Ⅰ）的方法，其中R1是H或C1- 4烷基或CH2-CR4-; R2是C1-4烷基; R 3选自具有至少4个碳原子的烷基，具有至少5个碳原子的环烷基，芳基，芳烷基，烷芳基和氨基烷基; R4是-H或-C1-4烷基，其中醇R2OH（Ⅳ）作为副产物形成，其中所述副产物（Ⅳ）在夹带剂存在下通过蒸馏除去，其中夹带剂是一种化合物，抑制化合物（II）和副产物（IV）之间的共沸物的形成。该方法可用于制备酯如二甲基氨基乙基（甲基）丙烯酸酯。本发明还提供了分离醇和酯的方法。在本发明的另一种形式中，提供了通过酯交换方法制备酯的方法，其中酯交换催化剂是均匀的。

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