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1. 发明授权

US4059626A Trifluoroethylanilines 失效
标题翻译：三氟乙基苯胺
公开(公告)号：US4059626A
公开(公告)日：1977-11-22
申请号：US562063
申请日：1975-03-26
申请人： Louis Foulletier , Jacques Pierre Edmond Pechmeze , Robert Frederic Michel Sureau
发明人： Louis Foulletier , Jacques Pierre Edmond Pechmeze , Robert Frederic Michel Sureau
IPC分类号： C07C211/52 , A61K31/135 , C07C20060101 , C07C67/00 , C07C209/00 , C09B29/00 , C07C87/52 , C07C87/56 , C07C91/44 , C07C93/14
CPC分类号： C07C205/12
摘要： Compound of the formula: ##STR1## in which the nucleus A is unsubstituted or substituted by one or two nitro, amino, alkyl, alkoxy, chlorine or bromine and the alkyl and alkoxy each contain up to two carbon atoms capable of being used as intermediate products for preparing dyestuffs, pharmaceutical products or phytopharmaceutical products.
摘要翻译：下式的化合物：其中核A未被取代或被一个或两个硝基，氨基，烷基，烷氧基，氯或溴取代，并且烷基和烷氧基各自含有最多两个可用作中间体的碳原子制备染料，药品或植物药品的产品。

2. 发明授权

US4876406A Process for gaseous phase fluorination of aliphatic chlorinated or chlorofluorinated hydrocarbons 失效
标题翻译：脂肪族氯化或氯氟化烃的气相氟化方法
公开(公告)号：US4876406A
公开(公告)日：1989-10-24
申请号：US669404
申请日：1984-11-08
申请人： Louis Foulletier
发明人： Louis Foulletier
IPC分类号： B01J23/26 , B01J27/18 , B01J27/188 , B01J35/10 , C07B61/00 , C07C17/00 , C07C17/20 , C07C19/08 , C07C19/10 , C07C19/12 , C07C67/00
CPC分类号： B01J27/18 , B01J23/26 , B01J35/0026 , B01J35/1019 , B01J35/1061 , B01J35/108 , C07C17/206
摘要： This invention relates to improved catalysts for gaseous phase fluoridation of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts comprise chromium salts or oxides complexed with aluminum phosphate and are characterized by a total specific surface area greater than about 200 m.sup.2 /g, but less than about 1000 m.sup.2 /g a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g, but less than about 150 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g. but less than about 60 m.sup.2 /g. This invention also relates to gaseous phase fluoridation processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.
摘要翻译：本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。催化剂包括与磷酸铝络合的铬盐或氧化物，其特征在于总共比表面积大于约200m 2 / g，但小于约1000m 2 / ga的孔的表面积为40至50，半径大于约5 m 2 / g，但小于约150m 2 / g，大于或等于250的孔的表面积大约在2m 2 / g以上。但小于约60m2 / g。本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

3. 发明授权

US4474895A Catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons 失效
标题翻译：用于脂族氯化和氯氟化烃气相氟化的催化剂
公开(公告)号：US4474895A
公开(公告)日：1984-10-02
申请号：US324414
申请日：1981-11-24
申请人： Louis Foulletier
发明人： Louis Foulletier
IPC分类号： B01J21/18 , B01J23/26 , B01J35/10 , B01J37/26 , C07B61/00 , C07C17/00 , C07C17/20 , C07C19/08 , C07C19/10 , C07C19/12 , C07C45/63 , C07C67/00 , B01J27/12
CPC分类号： B01J35/10 , B01J21/18 , B01J23/26 , C07C17/206 , C07C45/63 , B01J35/1028 , B01J35/1061
摘要： This invention relates to improved catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts are characterized by an active carbon support having a total specific surface area greater than about 1000 m.sup.2 /g but less than about 2000 m.sup.2 /g, a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g but less than about 15 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g but less than about 6 m.sup.2 /g, which has been impregnated with an aqueous chromium trioxide solution and dried. This invention also relates to gaseous phase fluorination processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.
摘要翻译：本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。催化剂的特征在于具有大于约1000m 2 / g但小于约2000m 2 / g的总比表面积的活性炭载体，半径在约5m 2 / g以上的孔的表面积为40至50，但是小于约15m 2 / g，大于或等于250的孔的表面积大于约2m 2 / g但小于约6m 2 / g，其已用三氧化铬水溶液浸渍并干燥。本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

4. 发明授权

US4069158A Fire extinguishing compositions 失效
标题翻译：灭火组合物
公开(公告)号：US4069158A
公开(公告)日：1978-01-17
申请号：US678929
申请日：1976-04-21
申请人： Rene Bertocchio , Louis Foulletier
发明人： Rene Bertocchio , Louis Foulletier
IPC分类号： A62D1/00 , A62D1/02 , A62C1/00 , B01F17/30
CPC分类号： A62D1/0085 , A62D1/0042 , A62D1/0064 , Y10S516/06
摘要： Aqueous fire-extinguishing compositions comprising a mixture of (1) a nonionic surface-active agent, (2) a amphoteric surface active agent and (3) a fluorinated cationic surface active agent containing as a part of the molecule an aromatic radical.
摘要翻译：水性灭火组合物，其包含（1）非离子表面活性剂，（2）两性表面活性剂和（3）作为分子的一部分含有芳香族基团的氟化阳离子表面活性剂的混合物。

5. 发明授权

US4610829A Polyfluorinated sulphonic acids and their derivatives 失效
标题翻译：多氟磺酸及其衍生物
公开(公告)号：US4610829A
公开(公告)日：1986-09-09
申请号：US966508
申请日：1978-12-04
申请人： Jean-Pierre Lalu , Louis Foulletier
发明人： Jean-Pierre Lalu , Louis Foulletier
IPC分类号： C07B45/02 , C07C309/06 , C11D1/00 , C23F11/16 , C07C143/70
CPC分类号： C07C309/06 , C07B45/02 , C11D1/004 , C23F11/16 , Y10S516/03
摘要： New products and compositions of matter complying with the general formula:[C.sub.n F.sub.2n+1 --CH.sub.2 --.sub.b SO.sub.2 --Z].sub.d Mwherein: C.sub.n F.sub.2n+1 represents a straight or ramified branched perfluorinated chain: n represents a whole number between 1 and 20, b is a whole number between 2 and 20, preferably equal to 2 or 4, Z represents a chlorine, bromine or an oxygen atom (when Z is a chlorine or a bromine atom, M is nothing and d is equal to 1), when Z is an oxygen atom: M is a hydrogen atom in which case, d is equal to 1, M is a metal of the Groups I.sub.A, II.sub.A, I.sub.B, II.sub.B, VIII of the periodic table, the ammonium radical, the aluminum or the lead radical, and in which case d represents the valence of this metal and methods for preparing new products as illustrated by the following representative reactions.
摘要翻译：新产品和符合以下通式的物质组成：[CnF2n + 1-CH2-bSO2-Z] dM其中：CnF2n + 1表示直链或支链支化全氟链：n表示1〜20的整数，b表示 2〜20的整数，优选2或4，Z表示氯，溴或氧原子（当Z为氯或溴原子时，M为无，d为1），当Z为氧原子：M是氢原子，在这种情况下，d等于1，M是元素周期表中IA，IIA，IB，IIB，VIII族的金属，铵基，铝或铅自由基，并且在这种情况下，d表示该金属的化合价和制备新产品的方法，如以下代表性反应所示。

6. 发明授权

US3941705A Fire extinguishing compositions containing fluorinated surfactants 失效
标题翻译：含氟表面活性剂的灭火组合物
公开(公告)号：US3941705A
公开(公告)日：1976-03-02
申请号：US559565
申请日：1975-03-18
申请人： Louis Foulletier , Rene Bertocchio
发明人： Louis Foulletier , Rene Bertocchio
IPC分类号： A62D1/02 , A62D1/00
CPC分类号： A62D1/0085 , Y10S516/06
摘要： A surface-active fluorinated composition characterized by the association therein of from 35% to about 60% of at least one surface-active ampholyte compound of the formula ##EQU1## wherein n is an integer between 1 and 20, a is a number between 2 and 10, R.sub.1 is an atom of hydrogen or an alkyl radical containing from 1 to 6 atoms of carbon, R.sub.2 and R.sub.3 are alkyl radicals containing from 1 to 3 atoms of carbon, at least one of which is the methyl radical and p and q are integers between 0 and 10; from about 20% to about 40% of at least one surface-active fluorinated non-ionic compound of the formulaC.sub.n F.sub.2n.sub.+1 -- (CH.sub.2).sub.a -- CO--O--(CH.sub.2 --CH.sub.2 --O).sub.m R.sub.4wherein n and a have the same meaning as above, m is an integer between 1 and 20 and R.sub.4 is an alkyl radical containing from 1 to 6 atoms of carbon; and from about 8% to about 40% of at least one amine salt compound of the formula ##EQU2## wherein X is the group CO or SO.sub.2 R.sub.1, R.sub.5 and R.sub.6 may be hydrogen atoms, alkyl radicals containing from 1 to 6 atoms of carbon, or the group ##EQU3## in which R.sub.2, R.sub.3, p and q have the values given above.
摘要翻译：一种表面活性氟化组合物，其特征在于其中含有35％至约60％的至少一种式R 2 C n F 2n + 1（CH 2）a-CON-（CH 2）p N +的表面活性两性电解质化合物 ---（CH2）qCOO - | R1R3其中n为1至20之间的整数，a为2至10之间的数，R1为氢原子或含有1至6个碳原子的烷基， R2和R3是含有1至3个碳原子的烷基，其中至少一个是甲基，p和q是0和10之间的整数; 约20％至约40％的至少一种式CnF2n + 1-（CH2）a-CO-O-（CH2-CH2-O）mR4的表面活性氟化非离子化合物，其中n和a具有 m为1〜20的整数，R 4为含有1〜6个碳原子的烷基; 和约8％至约40％的至少一种式R 1 C n F 2n + 1 - （CH 2）a -XO - HN - R 6 R 6的胺盐化合物，其中X为基团CO或SO 2 + L，R 1，R 5和R 6可以是氢原子，含有1至6个碳原子的烷基或基团R 2 - （CH 2）p N + - （CH 2）q -COOH - ，其中 R2，R3，p和q具有上面给出的值。

7. 发明授权

US4613681A Process for the manufacture of fluorinated alkanols and esters thereof 失效
标题翻译：制备氟化链烷醇及其酯的方法
公开(公告)号：US4613681A
公开(公告)日：1986-09-23
申请号：US163978
申请日：1980-06-30
申请人： Louis Foulletier , Andre Lantz
发明人： Louis Foulletier , Andre Lantz
IPC分类号： C07C27/00 , C07C29/124 , C07C31/38 , C07C67/00 , C07C69/62 , C07C69/003 , C07C29/58
CPC分类号： C07C29/124 , C07C67/00
摘要： This invention relates to a process for the preparation of a fluorinated compound of the general formulaR.sub.F C.sub.2 H.sub.4 ORcomprising reacting an iodide of the general formula R.sub.F C.sub.2 H.sub.4 I with a percarboxylic acid of the general formula R.sup.1 CO.sub.3 H at a temperature and for a time sufficient to form said fluorinated compound; in said formulae R.sub.F is a straight or branched chain perfluorinated radical containing 1 to 20 C atoms, R is a hydrogen atom or --COR.sup.1, and R.sup.1 is a hydrogen atom or an aliphatic or aromatic hydrocarbon radical.
摘要翻译：本发明涉及制备通式为RFC2H4OR的含氟化合物的方法，包括使通式为RFC2H4I的碘化物与通式为R 1 CO 3 H的过羧酸在足以形成所述氟化化合物的温度和时间下反应; 在所述式中，RF是含有1至20个C原子的直链或支链全氟化基团，R是氢原子或-COR 1，R 1是氢原子或脂族或芳族烃基。

8. 发明授权

US4000175A Polyfluorinated quaternary ammonium salts 失效
标题翻译：多氟季铵盐
公开(公告)号：US4000175A
公开(公告)日：1976-12-28
申请号：US39147
申请日：1970-05-20
申请人： Louis Foulletier , Jean-Pierre Lalu
发明人： Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C09D7/00 , B01F17/00 , B03D1/001 , B03D1/01 , C07C67/00 , C07C213/00 , C07C213/02 , C07C215/40 , C08J7/06 , C09D7/12 , C09K3/00 , C09K3/18 , C07C141/04 , C07C87/30 , C07C91/26
CPC分类号： B03D1/01 , B01F17/0042 , B01F17/0057 , B03D1/012 , B03D2203/02
摘要： This invention relates to new products of the general formula: ##STR1## wherein C.sub.n F.sub.2n.sub.+1 represents a straight or branched perfluorinated hydrocarbon chain in which n is a number between 1 and 20; a is an even number having the value 2 or 4; R represents a hydrogen atom or the methyl radical; Z represents an alkyl hydrocarbon radical containing from 1 to 8 carbon atoms, or the radical -- CH.sub.2 -- CHOHR, or a cycloalkyl hydrocarbon radical containing from 5 to 9 carbon atoms or an aryl hydrocarbon radical containing from 6 to 10 carbon atoms; R' represents an alkyl hydrocarbon radical containing from 1 to 9 carbon atoms; and X is an anion which can be a halide, a sulphate, or an alkyl sulphate. These products are useful as surface active agents.

9. 发明授权

US4000168A Carboxylated polyfluoroamines 失效
标题翻译：羧氧基多氟胺
公开(公告)号：US4000168A
公开(公告)日：1976-12-28
申请号：US495220
申请日：1974-08-06
申请人： Rene Bertocchio , Louis Foulletier , Jean-Pierre Lalu
发明人： Rene Bertocchio , Louis Foulletier , Jean-Pierre Lalu
IPC分类号： C09D7/45 , C09D7/47 , C10M133/16
CPC分类号： C09D7/06 , C09D7/02 , C10M133/16 , C10M2211/00 , C10N2250/10
摘要： This invention relates to carboxylated polyfluoroamine compounds of the general formula ##STR1## wherein the radical C.sub.n F.sub.2n.sub.+1 -- is a straight or branched perfluorinated chain, n is an integer from 1 to 20, a is an integer from 2 to 10, p is an integer from 1 to 10, R.sup.2 and R.sup.3 each is an alkyl radical containing from 1 to 6 carbon atoms and R.sup.1 is a hydrogen atom or an alkyl radical containing from 1 to 6 carbon atoms and the process for their preparation.

10. 发明授权

US3989843A Emulsification of fluorocarbon compounds for biological application as oxygen transporters 失效
标题翻译：用于生物应用的氟碳化合物的乳化作为氧转运体
公开(公告)号：US3989843A
公开(公告)日：1976-11-02
申请号：US516899
申请日：1974-10-22
申请人： Pierre Chabert , Louis Foulletier , Andre Lantz
发明人： Pierre Chabert , Louis Foulletier , Andre Lantz
IPC分类号： A61K9/107 , A61K9/00 , A61K31/02 , B01F17/42 , A61K31/13
CPC分类号： A61K9/0026 , A61K31/02 , Y10S514/833
摘要： Aqueous emulsions of polyfluorinated organic compounds useful as physiological transporters of oxygen, particularly in saline solutions isotonic with blood, are prepared by a method which comprises mixing a polyfluorinated compound with water or aqueous saline solution in the presence of at least one predominantly lipophilic polyfluorinated emulsifier and also at least one predominantly hydrophilic polyfluorinated emulsifier.
摘要翻译：用作氧的生理转运蛋白的多氟化有机化合物的水乳液，特别是在与血液等渗的盐溶液中的多氟化有机化合物的制备方法包括在至少一种主要是亲脂性的多氟化乳化剂存在下，将多氟化合物与水或盐水溶液混合，还有至少一种主要是亲水的多氟化乳化剂。

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