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    • 4. 发明授权
    • Photographic element having improved magenta dye light stability and
process for its use
    • 具有改善的品红染料光稳定性的照相元件及其使用方法
    • US5925503A
    • 1999-07-20
    • US784851
    • 1997-01-15
    • John W. HarderPaul A. BurnsPaul P. Spara
    • John W. HarderPaul A. BurnsPaul P. Spara
    • G03C7/38G03C7/46
    • G03C7/3835
    • The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: ##STR1## wherein X is hydrogen or a coupling-off group; andR' is a tertiary alkyl group and R" represents the group ##STR2## in which R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent; andW is a substituent selected from the group consisting of --C(O)R.sup.5, --SO.sub.2 R.sup.5, and --P(O)(OR.sup.6).sub.2 in which R.sup.5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R.sup.6 is selected from the group consisting of alkyl and aryl groups.The element exhibits improved magenta dye light stability.
    • 本发明提供了一种照相元件,其包含卤化银乳剂层,其具有与式I化合物形成的染料形成成色剂:其中X为氢或偶合离去基团; 并且R'是叔烷基,R“表示其中R 1,R 2和R 3是独立选择的烷基的基团,条件是R 1,R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基,条件是当R 4为取代基时,R 3和R 4可以连接形成环; 并且W是选自-C(O)R 5,-SO 2 R 5和-P(O)(OR 6)2的取代基,其中R 5选自烷基,芳基,烷氧基,芳氧基,烷基氨基 和芳基氨基,R 6选自烷基和芳基。 该元件表现出改善的品红染料光稳定性。
    • 9. 发明授权
    • Silver halide photographic element, imaging process, and compound
    • 卤化银照相元件,成像工艺和化合物
    • US06329130B1
    • 2001-12-11
    • US09747695
    • 2000-12-22
    • Barbara B. LussierMichael J. ProseusPaul A. BurnsBrian ThomasFrank D. Coms
    • Barbara B. LussierMichael J. ProseusPaul A. BurnsBrian ThomasFrank D. Coms
    • G03C108
    • G03C7/30535G03C7/36G03C7/362G03C7/367
    • Disclosed is a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith a yellow dye-forming coupler having formula I: wherein each A is independently a divalent group selected from the divalent groups consisting of aryl and —C(R1)(R2)—, in which each R1 and R2 is independently selected from the group consisting of hydrogen, alkyl, alkoxy, aryloxy, heterocyclic, and aryl groups, and one A can be joined to form a ring with another A or with R3, and m is from 2 to 6; R3 is selected from the group consisting of hydrogen, alkyl, heterocyclic, and aryl groups, provided that R3 may form a ring with A or is a group joined to R4 to form a heterocyclic five- or six-membered ring; R4 is selected from the group consisting of aryl, heterocyclic, and alkyl groups and may form a heterocyclic ring bonded to R3; Y is selected from the group consisting of —SO2—, —C(═O)—, —C(═O)NR9R10—, —C(═O)O—, and —P(═O)(OR9)(OR10—) where R9 and R10 are independently H or an alkyl or aryl group; and the remaining substituents are as described in the summary of the invention.
    • 公开了一种照相材料,其包含与其相关联的具有式I的黄色染料形成成色剂的感光卤化银乳剂层:其中A独立地为选自由芳基和-C(R 1)(R 2)组成的二价基团的二价基团, - ,其中每个R 1和R 2独立地选自氢,烷基,烷氧基,芳氧基,杂环和芳基,一个A可以与另一个A或与R3形成环,并且m是 2至6; R 3选自氢,烷基,杂环和芳基,条件是R 3可以与A形成环或是与R 4连接的基团以形成杂环五元或六元环 R 4选自芳基,杂环和烷基,并且可以形成与R 3键合的杂环; Y选自-SO 2 - , - C(= O) - , - C(= O)NR 9 R 10 - , - C(= O)O-和-P(= O)(OR 9)(OR 10 - )其中R 9和R 10独立地为H或 烷基或芳基; 而其余的取代基如本发明的概述所述。
    • 10. 发明授权
    • Tone control of photographic silver images
    • 照相银色图像的音调控制
    • US5314790A
    • 1994-05-24
    • US892846
    • 1992-06-03
    • Stephen A. HersheyJ. Ramon VargasPaul A. Burns
    • Stephen A. HersheyJ. Ramon VargasPaul A. Burns
    • G03C1/00G03C1/035G03C1/35G03C1/43G03C5/29G03C5/00
    • G03C1/35G03C1/035Y10S430/166
    • Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver chlorobromide emulsion layer in which the silver chlorobromide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 8 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.
    • 具有下式的单环和多环唑改性由氯化银氯化银颗粒的平均当量圆直径小于0.3μm的细晶粒辐射敏感性氯化银乳剂层形成的银图像的色调。 唑类具有下式:其中Z是-N =或-C(R5)=其中R5是氢,-NH2,1至8个碳原子的脂族或1至8个碳原子的芳族; R4是氢,1至8个碳原子的脂族或1至8个碳原子的芳族; R4和R5一起完成含有1至3个环氮原子的5或6元杂环核; L是含有1至8个碳原子的二价脂族连接基团; T是含有1至8个碳原子的脂肪族端基; m为0或1; n为1〜4的整数, p为2〜4的整数。