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1. 发明授权

US5917067A Process for producing an omega-functionalized aliphatic carboxylic acid and intermediate products of said process, including 2-oxepanone-7-substituted products 失效
标题翻译：制备ω官能化脂肪族羧酸的方法和所述方法的中间产物，包括2-氧杂环庚酮-7-取代的产物
公开(公告)号：US5917067A
公开(公告)日：1999-06-29
申请号：US556982
申请日：1996-04-18
申请人： Livius Cotarca , Paolo Maggioni , Alfonso Nardelli , Stefano Sguassero
发明人： Livius Cotarca , Paolo Maggioni , Alfonso Nardelli , Stefano Sguassero
IPC分类号： C07C51/08 , C07C51/347 , C07C69/34 , C07C69/593 , C07C69/675 , C07C229/08 , C07C253/30 , C07C255/19 , C07C255/23 , C07D313/04 , C07D315/00 , C07C51/16
CPC分类号： C07D315/00 , C07C229/08 , C07C253/30 , C07C255/19 , C07C255/23 , C07C51/08 , C07C51/347 , C07C69/34 , C07C69/593 , C07C69/675 , C07D313/04
摘要： A process for producing an omega-functionalized aliphatic carboxylic acid starting from cyclohexanone and omega-functionalized .alpha.-olefins or acrylic esters. The process comprises an addition step, an oxidation step, an isomerization step, and one or more hydrogenation steps. The process allows to use raw materials that are available at low cost and to achieve high selectivity and high yield with industrially simple steps. The process includes the production of new intermediate products, including 2-oxepanone-7-substituted products.
摘要翻译： PCT No.PCT / EP94 / 01864 Sec。 371日期：1996年4月18日 102（e）日期1996年4月18日PCT Filed 1994年6月8日PCT公布。公开号WO94 / 29258 日期1994年12月22日从环己酮和ω-官能化的α-烯烃或丙烯酸酯开始制备ω-官能化的脂族羧酸的方法。该方法包括加成步骤，氧化步骤，异构化步骤和一个或多个氢化步骤。该方法允许使用以低成本获得的原料，并且通过工业上简单的步骤实现高选择性和高产率。该方法包括生产新的中间产物，包括2-氧杂环庚酮-7-取代产物。

2. 发明授权

US5872267A Process for producing an omega-functionalized aliphatic carboxylic acid and intermediate products of said process 失效
标题翻译：制备ω官能化脂族羧酸的方法和所述方法的中间产物
公开(公告)号：US5872267A
公开(公告)日：1999-02-16
申请号：US556991
申请日：1996-04-16
申请人： Livius Cotarca , Paolo Maggioni , Alfonso Nardelli
发明人： Livius Cotarca , Paolo Maggioni , Alfonso Nardelli
IPC分类号： C07C51/08 , C07C51/347 , C07C69/593 , C07C69/675 , C07C253/30 , C07C255/19 , C07C255/23 , C07C51/16
CPC分类号： C07C255/23 , C07C253/30 , C07C255/19 , C07C51/08 , C07C51/347 , C07C69/593 , C07C69/675
摘要： A process for producing an omega-functionalized aliphatic carboxylic acid starting from cyclohexanone and omega-functionalized .alpha.-olefins. The process comprises an addition step, an oxidation step, an isomerization step, one or more hydrogenation steps and hydrolysis. The process allows to use raw materials that are available at low cost and to achieve high selectivity and high yield with industrially simple steps. The process includes the production of new intermediate products.
摘要翻译： PCT No.PCT / EP94 / 01865 Sec。 371日期1996年04月16日 102（e）日期1996年4月16日PCT Filed 1994年6月8日PCT公布。 WO94 / 29257 PCT出版物日期1994年12月22日从环己酮和ω-官能化的α-烯烃开始制备ω-官能化的脂族羧酸的方法。该方法包括加成步骤，氧化步骤，异构化步骤，一个或多个氢化步骤和水解。该方法允许使用以低成本获得的原料，并且通过工业上简单的步骤实现高选择性和高产率。该过程包括生产新的中间产品。

3. 发明授权

US4183861A Process for preparing aromatic methylene-dioxy compounds 失效
标题翻译：制备芳族亚甲基二氧化合物的方法
公开(公告)号：US4183861A
公开(公告)日：1980-01-15
申请号：US764424
申请日：1977-01-31
申请人： Paolo Maggioni
发明人： Paolo Maggioni
IPC分类号： B01J31/00 , C07B61/00 , C07D317/50 , C07D317/44
CPC分类号： C07D317/50
摘要： A method for preparing aromatic methylenedioxybenzene products which are optionally substituted in the aromatic ring by alkyl, aldehydo, carboxy, alkoxy, halo or nitro moieties; which comprises treating the corresponding dihydroxybenzene with methylene chloride in the presence of a catalyst selected from among ammonium, phosphonium or arsonium chlorides and bromides. The reaction is conducted in the aqueous phase in the presence of a suitable base, such as a sodium derivative to form a sodium salt of the dihydroxybenzene reactant.The aromatic methylenedioxy products of this invention are known compounds which are used in the chemical, pharmaceutical and cosmetic industries and they have utility as intermediates in the preparation of other known compounds.
摘要翻译：芳香族亚甲二氧基苯产物的制备方法，其任选在芳环中被烷基，醛，羧基，烷氧基，卤素或硝基部分取代; 其包括在选自铵，鏻或氯化钪和溴化物的催化剂存在下用二氯甲烷处理相应的二羟基苯。反应在水相中，在合适的碱如钠衍生物的存在下进行，形成二羟基苯反应物的钠盐。本发明的芳族亚甲二氧基产物是用于化学，制药和化妆品工业中的已知化合物，它们可用作制备其它已知化合物的中间体。

4. 发明授权

US4146582A Process for preparing aromatic aldehydes and ketones 失效
标题翻译：制备芳香醛和酮的方法
公开(公告)号：US4146582A
公开(公告)日：1979-03-27
申请号：US764422
申请日：1977-01-31
申请人： Paolo Maggioni
发明人： Paolo Maggioni
IPC分类号： C07C45/27 , B01J27/00 , C07B61/00 , C07C45/00 , C07C45/28 , C07C45/29 , C07C47/52 , C07C49/76 , C07C67/00 , C07C45/02 , C07C45/16
CPC分类号： C07C45/29 , C07C45/28
摘要： A method for preparing aromatic aldehydes and ketones in which the aldehydo or keto group is bonded directly to the aromatic ring; which comprises oxidizing an alkyl substituted aromatic compound or an aromatic compound which is substituted by an alpha-hydroxyalkyl moiety, via treatment with a persulfate and a metal catalyst. The metal catalysts include, for example, (1) iron salts and silver salts, or (2) a redox pair of salts such as an iron salt in combination with a copper salt or a silver salt in combination with a copper salt.

5. 发明授权

US4322547A Process for producing difunctional aliphatic organic compounds 失效
标题翻译：二官能脂肪族有机化合物的制备方法
公开(公告)号：US4322547A
公开(公告)日：1982-03-30
申请号：US170956
申请日：1980-07-21
申请人： Francesco Minisci , Paolo Maggioni , Attilio Citterio
发明人： Francesco Minisci , Paolo Maggioni , Attilio Citterio
IPC分类号： C07C51/36 , C07C409/20 , C07C409/22 , C07C409/40 , C07C67/10 , C07C67/22 , C07C99/00 , C07C120/00
CPC分类号： C07C255/00 , C07C407/00 , C07C51/36
摘要： Process industrially and economically useful for preparing difunctional aliphatic organic compounds of formulaX-(CH.sub.2).sub.n -Yin which n=6,7, X=--COOH, --COOR, Y=--CN, --COOH, --CONH.sub.2, --CH.sub.2 --NH.sub.2 --COOR wherein R is a linear or branched alkyl containing 1-6 carbon atoms.The process starts from a ketone of the formula ##STR1## in which n=2,3 and R.sub.1 =--CN, --COOH. The ketone (I) is changed to the corresponding hydroperoxide by means of H.sub.2 O.sub.2, the hydroperoxide is catalytically split by means of a catalyst Fe.sup.++ /Cu.sup.++ to give an unsaturated acid of the formulaHOOC--(CH.sub.2).sub.3 --CH.dbd.CH--(CH.sub.2).sub.2 -R.sub.1and this is catalytically hydrogenated to the compoundHOOC--(CH.sub.2).sub.n -R.sub.1When R.sub.1 is different from Y, R.sub.1 is changed to Y through known methods.
摘要翻译：工业上和经济上可用于制备其中n = 6,7，X = -COOH，-COOR，Y = -CN，-COOH，-CONH 2，-CH 2 -NH 2的式X-（CH 2）n Y的二官能脂族有机化合物 -COOR，其中R是含1-6个碳原子的直链或支链烷基。该方法从其中n = 2,3和R 1 = -CN，-COOH的式“I”酮的酮开始。通过H 2 O 2将酮（I）改变成相应的氢过氧化物，通过催化剂Fe ++ / Cu ++催化分解氢过氧化物，得到式HOOC-（CH 2）3 -CH = CH-（CH 2））2-R1，并且其被催化氢化成化合物HOOC-（CH 2）n -R 1当R 1不同于Y时，通过已知方法将R 1改变为Y。

6. 发明授权

US4542229A Process for preparing 2,3-dihydro-2,2-dimethylbenzofuran-7-ol 失效
标题翻译：制备2,3-二氢-2,2-二甲基苯并呋喃-7-醇的方法
公开(公告)号：US4542229A
公开(公告)日：1985-09-17
申请号：US483612
申请日：1983-04-11
申请人： Paolo Maggioni , Francesco Minisci , Mariano Correale
发明人： Paolo Maggioni , Francesco Minisci , Mariano Correale
IPC分类号： C07D307/79 , B01J27/00 , B01J31/00 , B01J31/02 , B01J31/18 , C07B61/00 , C07C41/16 , C07C43/23 , C07D307/86
CPC分类号： C07C41/16 , C07D307/86
摘要： A process is described for preparing 2,3-dihydro-2,2-dimethylbenzofuran-7-ol (I), which is a useful intermediary in the preparation of Carbofuran, a known multi-functional insecticide.The process consists essentially of reacting the pyrocatechol and a methallylhalide in an inert organic solvent in the presence of a solid inorganic base and a suitable catalyst, to obtain o.methallyloxyphenol with high conversion and high selectivity; this product is thermally transposed to o.methallylpyrocatechol, which is finally cyclized to the product (I) by heterogeneous catalysis in the presence of solid acid catalysts.All stages of the process can be carried out in a single reaction medium, without separating intermediate products.
摘要翻译：描述了制备2,3-二氢-2,2-二甲基苯并呋喃-7-醇（I）的方法，其是制备已知多功能杀虫剂的呋喃丹的有用中间体。该方法主要包括在固体无机碱和合适的催化剂存在下，使邻苯二酚与甲代烯丙基胺在惰性有机溶剂中反应，得到高转化率和高选择性的甲基丙烯酰氧基苯酚; 该产物热转移到甲基丙烯酰基邻苯二酚，其在固体酸催化剂存在下最终通过非均相催化环化成产物（I）。该方法的所有阶段都可以在单个反应介质中进行，而不分离中间产物。

7. 发明授权

US4370506A Terbutylating hydroxyaromatic compounds 失效
标题翻译：叔丁基化羟基芳族化合物
公开(公告)号：US4370506A
公开(公告)日：1983-01-25
申请号：US286612
申请日：1981-07-24
申请人： Francesco Ancillotti , Giuseppe Terzoni , Lidio Micucci , Paolo Maggioni , Pietro Panseri
发明人： Francesco Ancillotti , Giuseppe Terzoni , Lidio Micucci , Paolo Maggioni , Pietro Panseri
IPC分类号： B01J27/00 , B01J27/02 , B01J31/00 , B01J31/08 , C07B61/00 , C07C27/00 , C07C37/16 , C07C37/48 , C07C39/06 , C07C39/08 , C07C67/00 , C07C37/11
CPC分类号： C07C37/16
摘要： Hydroxyaromatic compounds, especially phenols, are reacted with an alkyl tert.butyl ether in the presence of an acidic catalyst and the as formed light alcoholic fractions are removed by flashing.
摘要翻译：在酸性催化剂存在下，使羟基芳族化合物，特别是酚与烷基叔丁基醚反应，通过闪蒸除去形成的轻质部分。

8. 发明授权

US4816592A Process for the production of certain 2,3-dihydro-benzofuran derivatives 失效
标题翻译：制备某些2,3-二氢 - 苯并呋喃衍生物的方法
公开(公告)号：US4816592A
公开(公告)日：1989-03-28
申请号：US575544
申请日：1984-01-31
申请人： Paolo Maggioni , Francesco Minisci , Mariano Correale
发明人： Paolo Maggioni , Francesco Minisci , Mariano Correale
IPC分类号： B01J29/06 , B01J31/00 , B01J31/04 , B01J31/38 , C07B61/00 , C07D307/86
CPC分类号： C07D307/86
摘要： A process for the production of benzofuran derivatives having the general formula, ##STR1## wherein R is alkyl, in particular of 2,3-dihydro-2,2-dimethyl benzofuran-7-ol, starting from pyrocatechol ethers in one step operation.The process essentially consists of heating a solution of pyrocatechol ether in an inert organic solvent in the presence of a catalyst comprising metals of 3.degree. and 4.degree. group of the Periodic System in form of carboxylates or of modified zeolites.The products are known intermediates for the production of insecticides.
摘要翻译：其中R为烷基，特别是2,3-二氢-2,2-二甲基苯并呋喃-7-醇的苯并呋喃衍生物的制备方法，其一步操作由邻苯二酚醚开始制备。该方法主要包括在含有羧酸盐或改性沸石形式的定期系统3和4的金属的催化剂存在下，将惰性有机溶剂中的邻苯二酚醚溶液加热。该产品是用于生产杀虫剂的已知中间体。

9. 发明授权

US4599461A Process for the synthesis of o-isopropoxyphenol 失效
标题翻译：合成邻异丙氧基苯酚的方法
公开(公告)号：US4599461A
公开(公告)日：1986-07-08
申请号：US690120
申请日：1985-01-10
申请人： Paolo Maggioni , Francesco Minisci , Mariano Correale
发明人： Paolo Maggioni , Francesco Minisci , Mariano Correale
IPC分类号： C07C41/01 , B01J31/00 , C07B61/00 , C07C41/00 , C07C41/16 , C07C43/23 , C07C67/00
CPC分类号： C07C41/16
摘要： A process for preparing o-isopropoxyphenol (I) by means of the reaction: ##STR1## in which X is a halogen atom and in which the pyrocatechol (II) is reacted with the isopropyl halide (III) in the presence of an alkaline base in the solid state and of a solid-liquid phase transfer catalyst, in a reaction medium constituted by one or more organic solvents.The catalyst is constituted by a quaternary ammonium or phosphonium salt.The reaction is conducted in a nitrogen atmosphere, at atmospheric pressure, under agitation, at a temperature of preferably between 50.degree. C. and 130.degree. C.
摘要翻译：通过以下反应制备邻异丙氧基苯酚（I）的方法：其中X是卤素原子，其中邻苯二酚（II）与异丙基卤化物（III）在碱性碱存在下反应在固体状态和固相 - 液相转移催化剂的反应介质中，由一种或多种有机溶剂构成。催化剂由季铵盐或鏻盐构成。反应在氮气气氛中，在大气压下，在搅拌下，优选在50℃至130℃的温度下进行。

10. 发明授权

US4217290A Process for preparing bifunctional aliphatic organic compounds 失效
标题翻译：双功能脂肪族有机化合物的制备方法
公开(公告)号：US4217290A
公开(公告)日：1980-08-12
申请号：US50331
申请日：1979-06-20
申请人： Paolo Maggioni , Francesco Mauri , Attilio Citterio
发明人： Paolo Maggioni , Francesco Mauri , Attilio Citterio
IPC分类号： C07C45/00 , C07C49/12 , C07C51/00 , C07C51/373 , C07C67/39 , C08K5/3475 , C09F5/00 , C07C87/28 , C07C121/00 , C11C3/00 , C11C3/02
CPC分类号： C07C51/373 , C07C45/00 , C07C49/12 , C07C51/00 , C07C67/39 , C08K5/3475 , C07C2101/14
摘要： This invention consists of a process for preparing bifunctional aliphatic organic compounds of at least 6 carbon atoms, wherein a cycloaliphatic oxyhydroperoxide is reacted with an alpha-olefine having its double bond activated by a conjugate electron-attracting group, in the presence of a bivalent Cr salt, a bivalent V salt or a trivalent Ti salt.
摘要翻译：本发明包括一种制备至少6个碳原子的双官能脂族有机化合物的方法，其中脂环氧基过氧化氢与其双键激活的α-烯烃与共轭电子吸引基团反应，在二价Cr 盐，二价V盐或三价Ti盐。

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