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1. 发明申请

US20140312273A1 SUPERABSORBING POLYMERS WITH RAPID ABSORPTION PROPERTIES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：具有快速吸收性能的超吸收聚合物及其制造方法
公开(公告)号：US20140312273A1
公开(公告)日：2014-10-23
申请号：US14352091
申请日：2012-11-12
申请人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
发明人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
IPC分类号： A61L15/22 , B01J20/30 , B01J20/26
CPC分类号： A61L15/225 , A61L15/24 , A61L15/60 , B01J20/267 , B01J20/3064 , C08F216/1416 , C08F220/06 , C08F222/1006 , C08J3/245 , C08J2333/02 , C08L33/02
摘要： This invention relates to a method for producing a water-absorbing polymer, including the following steps: (i) mixing (α1) 0.1 to 99.999 wt % polymerizable, ethylenically unsaturated, acid-group-containing monomers; (α2) 0 to 70 wt % polymerized ethylenically unsaturated, monomers copolymerizable with (α1); (α3) 0.00 1 to 10 wt %, cross-linking agent(s); (α4) 0 to 30 wt % water-soluble polymers; and (α5) 0 to 20 wt % additive(s), wherein the total quantity by weight of (α1) to (α5) amounts to 100 wt %, (ii) radical polymerization while cross-linking, in order to form a hydrogel polymer, (iii) drying the hydrogel polymer, (iv) grinding and sifting the water-absorbing polymer, (v) surface post-cross-linking the hydrogel polymer, and (vi) drying and processing the polymer, wherein, before the admixture of the initiator and the start of radical polymerization, 0.01 to 5 wt % of a surfactant, relative to acrylic acid, 0.01 to 5 wt % foaming agent, are added.
摘要翻译：本发明涉及一种吸水性聚合物的制造方法，包括以下步骤：（i）将（α1）0.1〜99.999重量％的可聚合的烯属不饱和的含酸基单体混合; （α2）0-70重量％聚合的烯属不饱和单体，可与（α1）共聚的单体; （α3）0.001-10重量％，交联剂; （α4）0〜30重量％水溶性聚合物; 和（α5）0〜20重量％的添加剂，其中（α1）〜（α5）的总量为100重量％，（ii）交联时的自由基聚合，以形成水凝胶聚合物，（iii）干燥水凝胶聚合物，（iv）研磨和筛选吸水聚合物，（v）表面后交联水凝胶聚合物，和（vi）干燥和加工聚合物，其中在混合物的引发剂和自由基聚合的开始，添加相对于丙烯酸的0.01〜5重量％的表面活性剂，0.01〜5重量％的发泡剂。

2. 发明授权

US08686216B2 Superabsorbent composition with metal salicylate for odor control 失效
标题翻译：超吸收组合物与金属水杨酸盐进行气味控制
公开(公告)号：US08686216B2
公开(公告)日：2014-04-01
申请号：US12867943
申请日：2009-02-27
申请人： Laurent Wattebled , Franck Furno
发明人： Laurent Wattebled , Franck Furno
IPC分类号： A61F13/15 , A61K31/60 , A61K47/30 , A61K33/32
CPC分类号： A61K31/60 , A61L15/18 , A61L15/46 , A61L15/60 , A61L2300/102 , A61L2300/21 , A61L2300/404 , C08K5/098 , C08L33/02
摘要： The present invention relates to a water-absorbing particulate composition comprising water-absorbing polymer particulate structure comprising partly neutralized, crosslinked polyacrylate, a surface crosslinking agent and a compound of the structure I in which R1, R2, R3 and R4 can be identical or different and in each case represent a hydrogen atom, a halogen atom, a C1- to C4-hydrocarbon group or a hydroxyl group, R5 represents a hydrogen atom, a C1- to C4-hydrocarbon group or an acetyl group, n represents an integer chosen from the group consisting of 1, 2 or 3 and Mn+ represents an n-valent metal cation or an H+ cation. In addition, the present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, and products, such as hygiene articles.
摘要翻译：本发明涉及一种吸水性颗粒组合物，其包含吸水聚合物颗粒结构，其包含部分中和的交联聚丙烯酸酯，表面交联剂和结构I的化合物，其中R 1，R 2，R 3和R 4可以相同或不同并且在每种情况下都表示氢原子，卤素原子，C 1〜C 4烃基或羟基，R 5表示氢原子，C 1〜C 4烃基或乙酰基，n表示选择的整数由1,2或3组成的组，Mn +表示n价金属阳离子或H +阳离子。此外，本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，可通过该方法获得的复合材料，和卫生用品等产品。

3. 发明申请

US20100209379A1 SUPERABSORBENT COMPOSITION WITH TANNINS FOR ODOR CONTROL 有权
标题翻译：用于气味控制的鞣剂的超吸收组合物
公开(公告)号：US20100209379A1
公开(公告)日：2010-08-19
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L9/01 , C09K3/00
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

4. 发明授权

US08658146B2 Superabsorbent composition with tannins for odor control 有权
标题翻译：超吸收剂组合物，含有单宁，用于气味控制
公开(公告)号：US08658146B2
公开(公告)日：2014-02-25
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L101/34 , A61K31/78
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

5. 发明申请

US20110009272A1 SUPERABSORBENT COMPOSITION WITH METAL SALICYLATE FOR ODOR CONTROL 失效
标题翻译：具有金属盐酸盐的超吸收组合物用于气味控制
公开(公告)号：US20110009272A1
公开(公告)日：2011-01-13
申请号：US12867943
申请日：2009-02-27
申请人： Laurent Wattebled , Franck Furno
发明人： Laurent Wattebled , Franck Furno
IPC分类号： A01N25/10 , A01P21/00 , C09K3/00 , C07F3/06
CPC分类号： A61K31/60 , A61L15/18 , A61L15/46 , A61L15/60 , A61L2300/102 , A61L2300/21 , A61L2300/404 , C08K5/098 , C08L33/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures and a compound of the structure I in which R1, R2, R3 and R4 can be identical or different and in each case represent a hydrogen atom, a halogen atom, a C1- to C4-hydrocarbon group or a hydroxyl group, R5 represents a hydrogen atom, a C1- to C4-hydrocarbon group or an acetyl group, n represents an integer chosen from the group consisting of 1, 2 or 3 and Mn+ represents an n-valent metal cation or an H+ cation. The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, and products, such as hygiene articles.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构和结构I的化合物，其中R 1，R 2，R 3和R 4可以相同或不同，并且在每种情况下都表示氢原子，卤素原子， C 1 -C 4烃基或羟基，R 5表示氢原子，C 1〜C 4烃基或乙酰基，n表示选自1,2或3的整数，Mn +表示 n价金属阳离子或H +阳离子。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料和产品，如卫生用品。

6. 发明申请

US20120302445A1 PROCESS FOR RECYCLING POLYMER FINES 审中-公开
标题翻译：回收聚合物精华的方法
公开(公告)号：US20120302445A1
公开(公告)日：2012-11-29
申请号：US13574945
申请日：2011-01-18
申请人： Henry Rudolph , Thomas Hoefges , Manfred Van Stiphoudt , Jörg Harren , Laurent Wattebled , Franck Furno , Frank Soppe
发明人： Henry Rudolph , Thomas Hoefges , Manfred Van Stiphoudt , Jörg Harren , Laurent Wattebled , Franck Furno , Frank Soppe
IPC分类号： B01J20/26 , A61K47/00 , A01N25/00 , B01J19/00 , B01J20/30
CPC分类号： C08F220/06 , C08F2/22 , C08F2/44 , C08J3/245 , C08J2300/14
摘要： The present invention relates to a process for producing a water-absorbing polymer structure based on acid group-containing monomers, comprising the process steps of: i) providing a monomer solution comprising the optionally partly neutralized, acid group-containing monomer; ii) mixing the monomer solution with fines which consist at least to an extent of 90% by weight, based on the total weight of the fines, of particles having a particle size of less than 850 μm, to obtain a monomer solution mixed with fines; wherein the mixing in process step ii) is effected in a mixer in which a first stream of the fines and at least one further stream of the monomer solution are passed from different directions simultaneously to a rotating mixing tool.
摘要翻译：本发明涉及一种基于含有酸基团的单体制备吸水聚合物结构的方法，包括以下工艺步骤：i）提供包含任选部分中和的含酸基单体的单体溶液; ii）将单体溶液与细粒混合，细粉至少达到基于细粉总重量的90重量％，粒径小于850μm的颗粒，以获得与细粒混合的单体溶液 ; 其中工艺步骤ii）中的混合在混合器中进行，其中细粉的第一流和单体溶液的至少一个另外的流同时从不同的方向通过到旋转的混合工具。

7. 发明申请

US20110144294A1 WATER-ABSORBING POLYMER STRUCTURES BASED ON RENEWABLE RAW MATERIALS AND PROCESS FOR THEIR PRODUCTION BY DEHYDRATION 有权
标题翻译：基于可再生原料的吸水聚合物结构及其脱水生产工艺
公开(公告)号：US20110144294A1
公开(公告)日：2011-06-16
申请号：US13029208
申请日：2011-02-17
申请人： Günther Bub , Jürgen Mosler , Franz-Felix Kuppinger , Andreas Sabbagh , Guido Stochniol , Jörg Sauer , Markus Winterberg , Udo Knippenberg , Günter Latoschinski , Franck Furno , Thorsten Schwärtzke , Jörg Leistner
发明人： Günther Bub , Jürgen Mosler , Franz-Felix Kuppinger , Andreas Sabbagh , Guido Stochniol , Jörg Sauer , Markus Winterberg , Udo Knippenberg , Günter Latoschinski , Franck Furno , Thorsten Schwärtzke , Jörg Leistner
IPC分类号： C08F120/06
CPC分类号： B01J19/2415 , B01J8/025 , B01J8/22 , B01J10/002 , B01J19/006 , B01J19/32 , B01J2208/00176 , B01J2208/0053 , B01J2219/0004 , B01J2219/00081 , B01J2219/00094 , B01J2219/00159 , B01J2219/00768 , B01J2219/185 , B01J2219/1943 , B01J2219/32279 , B01J2219/32286 , C07C45/52 , C07C51/252 , C08F2/00 , C08F2/20 , C08F220/06 , C07C47/22 , C07C57/04
摘要： The present invention relates to a process for production of acrylic acid, comprising at least the following steps: a. dehydration of glycerine to an acrolein-comprising dehydration product; b. gas phase oxidation of the dehydration product to obtain an acrylic acid-comprising monomer gas; c. bringing into contact of the monomer gas with a quench agent to obtain an acrylic acid-comprising quench phase; d. work-up of the quench phase to obtain an acrylic acid-comprising monomer phase; whereby, during the dehydration a liquid phase a1 and a gas phase a2 is present, whereby in the liquid phase a1 a plurality of gas bubbles is generated, as well as a process for production of polymers by polymerization of acrylic acid, preferably for production of water-absorbing polymers, the water-absorbing polymers obtainable by this process, a composite, a process for production of a composite, the composite obtainable by this process, and further chemical products.
摘要翻译：本发明涉及丙烯酸的制备方法，其至少包括以下步骤：a。将甘油脱水至含丙烯醛的脱水产物; b。脱水产物的气相氧化，得到含丙烯酸的单体气体; C。使单体气体与骤冷剂接触以获得含丙烯酸的淬火相; d。淬火阶段的后处理以获得含丙烯酸的单体相; 由此，在脱水时，存在液相a1和气相a2，由此在液相a1中产生多个气泡，以及通过丙烯酸的聚合制备聚合物的方法，优选用于生产吸水聚合物，通过该方法获得的吸水聚合物，复合材料，复合材料的制造方法，可通过该方法获得的复合材料，以及其他化学产品。

8. 发明申请

US20090202805A1 WATER-ABSORBING POLYMER STRUCTURES WITH IMPROVED ABSORPTION PROPERTIES 有权
标题翻译：具有改进的吸收性能的吸水聚合物结构
公开(公告)号：US20090202805A1
公开(公告)日：2009-08-13
申请号：US11912011
申请日：2006-04-21
申请人： Franck Furno , Harald Schmidt , Peter Herbe , Ursula Nielinger , Michael Keup
发明人： Franck Furno , Harald Schmidt , Peter Herbe , Ursula Nielinger , Michael Keup
IPC分类号： B32B27/00 , C08G77/00 , C08G85/00
CPC分类号： B01J20/26 , A61L15/18 , A61L15/60 , B01J2220/68 , C08F222/1006 , C08J7/12 , Y10T428/24942
摘要： The present invention relates to a process for production of water-absorbing polymer structures comprising the process steps: I. providing an untreated, water-absorbing polymer structure (Pu) with a retention determined according to the test method described herein of at least about 35 g/g; and II. bringing into contact of this water-absorbing untreated polymer structure (Pu) with a permeability-increasing agent. The invention further relates to the water-absorbing polymer structures obtainable by this process, water-absorbing polymer structures, a composite, a process for production of a composite, a composite obtainable by this process, chemical products comprising water-absorbing polymer structures or a composite as well as the use of water-absorbing polymer structures or of the composite in chemical products.
摘要翻译：本发明涉及一种生产吸水聚合物结构的方法，包括以下工艺步骤：I.提供未经处理的吸水聚合物结构（Pu），其保留根据本文所述的测试方法确定为至少约35 g / g; 和II。使该吸水性未处理聚合物结构（Pu）与渗透性增加剂接触。本发明还涉及通过该方法获得的吸水聚合物结构，吸水聚合物结构，复合材料，复合材料的制备方法，可通过该方法获得的复合材料，包含吸水聚合物结构的化学产品或复合材料以及吸水聚合物结构或复合材料在化学产品中的应用。

9. 发明申请

US20080214740A1 Hydrolytically Stable Postcrosslinked Superabsorbents 失效
标题翻译：水解稳定的后交联超吸收剂
公开(公告)号：US20080214740A1
公开(公告)日：2008-09-04
申请号：US11885250
申请日：2006-02-24
申请人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
发明人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
IPC分类号： C08F8/30
CPC分类号： C08J3/24 , C08F220/06 , C08J2333/02
摘要： The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
摘要翻译：本发明涉及一种生产后交联的吸水聚合物地层的方法，包括以下步骤：通过烯键式不饱和酸官能单体或其盐的聚合获得的吸水聚合物地层P 1 存在具有包含后交联剂的流体F 1 N的交联剂，将与流体F 1 1接触的吸水聚合物层加热到40〜 300℃以获得后交联的吸水聚合物组合物P 2，根据测试方法测定的具有热稳定性的吸水性聚合物组合物P 1 <1> 如本文所述，小于3.0％。本发明还涉及吸水聚合物地层，可通过该方法获得的吸水聚合物地层，基于交联的含羧基单体的吸水聚合物地层，包括吸水聚合物地层和基底的复合材料，涉及通过该方法可获得的复合材料的方法，涉及包含吸水聚合物结构或复合材料的化学产品，使用吸水聚合物结构或化学产品中的复合材料，以及使用的三烯丙基异氰脲酸酯作为内部交联剂在基于交联的含羧基单体的吸水性聚合物地层的生产中。

10. 发明申请

US20140339469A1 BIODEGRADABLE SUPERABSORBENT POLYMER COMPOSITION WITH GOOD ABSORPTION AND RETENTION PROPERTIES 审中-公开
标题翻译：具有良好吸收和保持性能的可生物降解的超吸收聚合物组合物
公开(公告)号：US20140339469A1
公开(公告)日：2014-11-20
申请号：US14448188
申请日：2014-07-31
申请人： Franck Furno , Harald Schmidt , Nicolaas De Bruin
发明人： Franck Furno , Harald Schmidt , Nicolaas De Bruin
IPC分类号： A01N25/04 , B01J20/30 , B01J20/26 , A61L15/60 , B01J20/28
CPC分类号： A01N25/04 , A61L15/60 , A61L15/62 , B01J20/267 , B01J20/28026 , B01J20/3085 , C08F2/44
摘要： The present invention generally relates to a method for the production of a superabsorbent composition comprising the process steps: i. production of a hydrogel by radical polymerization of an aqueous monomer solution containing at least one monomer ii. drying the hydrogel to obtain a water-absorbing polymer structure iii. surface crosslinking of the water-absorbing polymer structure to obtain a surface-crosslinked water-absorbing polymer structure, iv. incorporation of a starch compound in one or at least two of the variants V1 to V6, V1. in process step i. into the monomer solution V2. after process step i. and prior to process step ii. into the hydrogel V3. in process step ii. V4. after process step ii. and prior to process step iii. into the water-absorbing polymer structure V5. in process step iii V6. after process step iii onto the surface-crosslinked water-absorbing polymer structure. The present invention also related to a superabsorbent composition obtainable according to this method, a particulate superabsorbent composition and a composite, a sanitary article core and a sanitary item, furthermore chemical products and also the use of this superabsorbent composition in chemical products.
摘要翻译：本发明一般涉及一种生产超吸收剂组合物的方法，包括以下工艺步骤：i。通过含有至少一种单体的单体水溶液的自由基聚合制备水凝胶。干燥水凝胶以获得吸水聚合物结构iii。吸水聚合物结构的表面交联以获得表面交联的吸水聚合物结构，iv。在一个或至少两个变体V1至V6，V1中掺入淀粉化合物。在处理步骤i。进入单体溶液V2。后加工步骤i。并在加工步骤ii之前。进入水凝胶V3。在工艺步骤ii中。 V4。后加工步骤ii。并且在处理步骤iii之前。进入吸水聚合物结构V5。在处理步骤iii V6中。后处理步骤iii加到表面交联的吸水聚合物结构上。本发明还涉及根据该方法获得的超吸收剂组合物，颗粒超吸收组合物和复合材料，卫生用品芯和卫生用品，以及化学产品以及该超吸收组合物在化学产品中的用途。

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