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    • 2. 发明授权
    • In situ gasification process for producing product gas enriched in
carbon monoxide and hydrogen
    • 用于生产富含一氧化碳和氢气的产品气体的原位气化方法
    • US4122897A
    • 1978-10-31
    • US865156
    • 1977-12-28
    • John P. CappLarry A. Bissett
    • John P. CappLarry A. Bissett
    • E21B43/247E21B43/30E21B43/24
    • E21B43/305E21B43/247Y10S48/06
    • The present invention is directed to an in situ coal gasification process wherein the combustion zone within the underground coal bed is fed with air at increasing pressure to increase pressure and temperature in the combustion zone for forcing product gases and water naturally present in the coal bed into the coal bed surrounding the combustion zone. No outflow of combustion products occurs during the build-up of pressure and temperature in the combustion zone. After the coal bed reaches a temperature of about 2000.degree. F and a pressure in the range of about 100-200 psi above pore pressure the airflow is terminated and the outflow of the combustion products from the combustion zone is initiated. The CO.sub.2 containing gaseous products and the water bleed back into the combustion zone to react endothermically with the hot carbon of the combustion zone to produce a burnable gas with a relatively high hydrogen and carbon monoxide content. About 11 to 29 percent of the gas recovered from the combustion zone is carbon monoxide which is considerably better than the 4 to 10 percent carbon monoxide obtained by employing previously known coal gasification techniques.
    • 本发明涉及一种原位煤气化方法,其中地下煤层内的燃烧区以增加的压力供给空气以增加燃烧区中的压力和温度,以迫使煤层中天然存在的产物气体和水分进入 围绕燃烧区的煤层。 在燃烧区内压力和温度的积聚期间不会出现燃烧产物的流出。 在煤层达到约2000°F的温度和高于孔隙压力的约100-200 psi范围内的压力下,气流终止,并且燃烧产物从燃烧区域的流出开始。 含CO 2的气体产物和水回流到燃烧区中,与燃烧区的热碳吸热反应以产生具有相对高的氢和一氧化碳含量的可燃气体。 从燃烧区回收的气体中,约有11%〜29%是一氧化碳,比通过采用先前已知的煤气化技术获得的4%至10%的一氧化碳要好得多。
    • 4. 发明授权
    • Cyclic flow underground coal gasification process
    • 循环地下煤气化过程
    • US4069867A
    • 1978-01-24
    • US751624
    • 1976-12-17
    • Larry A. Bissett
    • Larry A. Bissett
    • E21B43/243E21B43/30E21C43/00
    • E21B43/243E21B43/305
    • The present invention is directed to a method of in situ coal gasification for providing the product gas with an enriched concentration of carbon monoxide. The method is practiced by establishing a pair of combustion zones in spaced-apart boreholes within a subterranean coal bed and then cyclically terminating the combustion in the first of the two zones to establish a forward burn in the coal bed so that while an exothermic reaction is occurring in the second combustion zone to provide CO.sub.2 -laden product gas, an endothermic CO-forming reaction is occurring in the first combustion zone between the CO.sub.2 -laden gas percolating thereinto and the hot carbon in the wall defining the first combustion zone to increase the concentration of CO in the product gas. When the endothermic reaction slows to a selected activity the roles of the combustion zones are reversed by re-establishing an exothermic combustion reaction in the first zone and terminating the combustion in the second zone.
    • 本发明涉及一种原位煤气化方法,用于为产物气体提供富集的一氧化碳浓度。 该方法通过在地下煤层内的间隔开的钻孔中建立一对燃烧区域,然后循环地终止在两个区域中的第一个区域中的燃烧,以在煤层中建立向前燃烧,使得在放热反应 发生在第二燃烧区域以提供含二氧化碳的产物气体,在其中渗入的载有二氧化碳的气体和限定第一燃烧区域的壁中的热碳之间的第一燃烧区域中发生吸热CO形成反应,以增加 产品气中的CO浓度。 当吸热反应减慢到所选择的活性时,通过在第一区域重新建立放热燃烧反应并终止第二区域中的燃烧来反转燃烧区域的作用。
    • 6. 发明授权
    • Apparatus for hot-gas desulfurization of fuel gases
    • 用于燃气气体脱硫的装置
    • US5130097A
    • 1992-07-14
    • US560666
    • 1990-07-31
    • Larry A. Bissett
    • Larry A. Bissett
    • B01D53/12B01J8/00B01J8/38B01J20/34
    • B01J8/0025B01D53/12B01J20/0229B01J20/0244B01J20/3433B01J20/3458B01J8/388B01J2220/56
    • An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.
    • 一种用于通过采用提升管再生装置在含有颗粒状吸附剂材料的流化床接触器中从热燃料气流中除去硫值的装置。 硫载体吸附剂通过立管连续地从流化床中移出到提升管,并且在通过使用含氧吸附剂再生气流输送吸附剂期间,在提升管中快速再生。 提升管从流化床下方的位置延伸到流化床上方的高度,其中气固分离机构用于将再生的颗粒吸附剂与再生气体和反应气体分离,使得再生的吸附剂可以返回到 流化床再利用。
    • 7. 发明授权
    • Two-stage coal gasification and desulfurization apparatus
    • 二期煤气化脱硫装置
    • US5069685A
    • 1991-12-03
    • US562298
    • 1990-08-03
    • Larry A. BissettLarry D. Strickland
    • Larry A. BissettLarry D. Strickland
    • C10J3/02F01K23/06
    • F01K23/067C10J3/02C10J3/20C10J2300/093C10J2300/1606C10J2300/1687Y02E20/18
    • The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.
    • 本发明涉及一种将两级固定床煤气化装置与来自两级气化炉的下级的第一燃料气流的热燃气脱硫和从 在燃料气体脱硫工艺中使用的硫吸附剂再生气体,其通过在含钙材料的存在下在燃烧装置中燃烧来自气化器的上段的第二气体燃料气体流。 第二气体燃料气体从煤气化炉的固定床上方取出,并含有氨,焦油和硫的含量。 该第二燃料气流在过量空气的存在下燃烧以提供足够的热能,以实现含钙材料与再生气体和第二燃料气体流携带的硫值之间的钙 - 硫化合物形成反应。 存在于燃料气体中的任何氨值在燃烧室内的燃料气体燃烧期间分解。 然后可将基本上无硫的燃烧产物与脱硫燃料气体组合,以提供用于驱动原动机的可燃流体。