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    • 2. 发明授权
    • Apparatus for control of gas flow into a mass spectrometer using a series of small orifices
    • 用于使用一系列小孔控制气体流入质谱仪的装置
    • US06518581B1
    • 2003-02-11
    • US09539605
    • 2000-03-31
    • Seksan DheandhanooRalph J. CiottiSuhas Narayan KetkarRichard Vincent Pearce
    • Seksan DheandhanooRalph J. CiottiSuhas Narayan KetkarRichard Vincent Pearce
    • H01J3934
    • H01J49/0422
    • A gas sampling and inlet device for a mass spectrometer has a hollow housing sleeve with an open inside region and a hollow inner sleeve with an open inside region, with the inner sleeve coaxial to the housing sleeve. One end of the housing sleeve and one end of the inner sleeve are connected with a single first end cap. The second end of the housing sleeve has a second end cap, but the second end of the inner sleeve is open such that the inside of the inner sleeve is open to the inside of the housing sleeve. The first end cap has a small diameter orifice adapted to receive a gaseous fluid. The second end cap is connected to a mass spectrometer. The second end cap has an orifice adapted to receive a gaseous fluid into the mass spectrometer that is substantially smaller in diameter than the orifice in the first end cap. The housing sleeve has a vacuum pump port to allow a vacuum to be created in the interior of the inlet device.
    • 用于质谱仪的气体取样和入口装置具有中空的壳体套筒,其具有敞开的内部区域和具有敞开的内部区域的中空的内部套筒,内部套筒与壳体套筒同轴。 壳体套筒的一端和内套筒的一端与单个第一端盖连接。 壳体套筒的第二端具有第二端盖,但是内套筒的第二端是敞开的,使得内套筒的内部对壳体套筒的内部敞开。 第一端盖具有适于容纳气态流体的小直径孔口。 第二端帽连接到质谱仪。 第二端盖具有适于将气态流体接收到质谱仪中的孔口,其直径比第一端盖中的孔口小得多。 壳体套筒具有真空泵端口,以允许在入口装置的内部产生真空。
    • 8. 发明授权
    • Method of using an aerosol to calibrate spectrometers
    • 使用气溶胶校准光谱仪的方法
    • US06686999B2
    • 2004-02-03
    • US10020559
    • 2001-12-14
    • Suhas Narayan Ketkar
    • Suhas Narayan Ketkar
    • G01J330
    • G01N21/278G01N21/73
    • Using a nebulizer gas, sub micron and micron size particulates can be generated from a solution containing salts covering a broad range of elements. The fractional concentration of elements can be determined by bubbling the aerosol through aqueous acid and analyzing the aqueous acid for metals. The nebulizer can be coupled to an ICP (Inductively Coupled Plasma) torch and the ICPMS (Inductively Coupled Plasma Mass Spectrometer) or ICPOES (Inductively Coupled Plasma Optical Emission Spectrometer) response to different elements can be determined. This provides the response factor of the ICPMS or ICPOES for different elements.
    • 使用雾化器气体,亚微米和微米尺寸的颗粒可以由含有宽范围元素的盐的溶液产生。 元素的分数浓度可以通过使气溶胶鼓泡通过含水酸并分析含水酸的金属来确定。 喷雾器可以耦合到ICP(电感耦合等离子体)手电筒,并且可以确定对不同元件的ICPMS(电感耦合等离子体质谱仪)或ICPOES(电感耦合等离子体发射光谱仪)响应。 这为不同元素提供了ICPMS或ICPOES的响应因子。
    • 9. 发明授权
    • Method of improving the performance of an ion mobility spectrometer used to detect trace atmospheric impurities in gases
    • 用于检测气体中痕量大气杂质的离子迁移谱仪的性能的方法
    • US06639214B1
    • 2003-10-28
    • US09567387
    • 2000-05-09
    • Suhas Narayan KetkarSeksan Dheandhanoo
    • Suhas Narayan KetkarSeksan Dheandhanoo
    • B01D5944
    • G01N27/622
    • A method for eliminating interference when analyzing a test sample of a bulk inert gas in an ion mobility spectrometer is disclosed which includes the steps of providing an ionization source for the spectrometer to form ions of the bulk inert gas, mixing a reagent gas with the test sample prior to entry into the spectrometer to alter the nature of the ions formed by the bulk inert gas to shift the location of a bulk inert gas mobility peak such that a bulk inert gas mobility peak does not overlap with an impurity mobility peak of the ions of a trace impurity of interest, whereby bulk inert gas ions are quenched and a clusters of the reagent gas and the bulk gas are formed. Alternatively, the reagent gas may be mixed with the drift gas in the ion mobility spectrometer, rather than with the test sample.
    • 公开了一种在分析离子迁移谱仪中的大量惰性气体的测试样品时消除干扰的方法,其包括以下步骤:为光谱仪提供离子源以形成大量惰性气体的离子,将试剂气体与测试 在进入光谱仪之前的样品以改变由大量惰性气体形成的离子的性质,以移动体惰性气体迁移率峰的位置,使得体惰性气体迁移率峰不与离子的杂质迁移率峰重叠 的痕量杂质,由此大量惰性气体离子被淬灭并形成了一组反应气体和本体气体。 或者,反应气体可以与离子迁移谱仪中的漂移气体而不是与测试样品混合。