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    • 3. 发明申请
    • Fluorinated photoresist materials with improved etch resistant properties
    • 具有改善耐蚀性能的氟化光致抗蚀剂材料
    • US20060105269A1
    • 2006-05-18
    • US10988137
    • 2004-11-12
    • Mahmoud KhojastehPushkara VaranasiWenjie LiKuang-Jung ChenKaushal Patel
    • Mahmoud KhojastehPushkara VaranasiWenjie LiKuang-Jung ChenKaushal Patel
    • G03C1/76
    • G03F7/0397C08F220/18C08F220/24C08F220/28G03F7/0046G03F7/0382Y10S430/108Y10S430/111Y10S430/122Y10S430/126
    • A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: where R1 represents hydrogen (H), a linear, branched or cyclo alkyl group of 1 to 20 carbons, a semi- or perfluorinated linear, branched or cyclo alkyl group of 1 to 20 carbons or CN; R2 represents an alicyclic group of 5 or more carbon atoms; X represents a methylene, ether, ester, amide or carbonate linkage; R3 represents a linear or branched alkylene group or semi- or perfluorinated linear or branched alkylene group with 1 or more carbon atoms; R4 represents hydrogen (H), methyl (CH3), trifluoromethyl (CF3), difluoromethyl (CHF2), fluoromethyl (CH2F), or a semi- or perflourinated aliphatic group; R5 represents trifluoromethyl (CF3), difluoromethyl (CHF2), fluoromethyl (CH2F), or a semi- or perfluorinated substituted or unsubstituted aliphatic group; n represents an integer of 1 or more; and OR12 represents OH or at least one acid labile group selected from a tertiary alkyl carbonate, a tertiary alkyl ester, a tertiary alkyl ether, an acetal and a ketal. A method of patterning a substrate is also disclosed, wherein the method includes: applying the photoresist composition mentioned above to the substrate to form a film; patternwise exposing the film to an imaging radiation source; and developing areas of the film to form a patterned substrate.
    • 公开了包含聚合物的光致抗蚀剂组合物,其中聚合物包括至少一种具有下式的单体:其中R 1表示氢(H),1至20个碳的直链,支链或环烷基 ,碳原子数为1〜20的半全氟化或全氟化的支链或环状烷基,CN; R 2表示5个以上碳原子的脂环基; X表示亚甲基,醚,酯,酰胺或碳酸酯键; R 3表示具有1个或更多个碳原子的直链或支链亚烷基或半或全氟化的直链或支链亚烷基; R 4表示氢(H),甲基(CH 3),三氟甲基(CF 3),二氟甲基(CHF 2) (CH 2 CH 2),或半或全氟化脂族基团; R 5表示三氟甲基(CF 3),二氟甲基(CH 2)2,氟甲基(CH 2 CH 2),氟甲基 或半或全氟取代或未取代的脂族基团; n表示1以上的整数, 和OR 12代表OH或选自叔碳酸烷基酯,叔烷基酯,叔烷基醚,缩醛和缩酮中的至少一种酸不稳定基团。 还公开了一种图案化衬底的方法,其中该方法包括:将上述光致抗蚀剂组合物施加到衬底上以形成膜; 将膜图案化地曝光到成像辐射源; 和显影区域以形成图案化衬底。