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1. 发明授权

US06673857B1 Thermoplastic elastomer compositions 有权
标题翻译：热塑性弹性体组合物
公开(公告)号：US06673857B1
公开(公告)日：2004-01-06
申请号：US09959395
申请日：2001-10-24
申请人： Konrad Knoll , Richard Rebizak , Rainer Anderlik , Sabine Philipp , Josef Wünsch
发明人： Konrad Knoll , Richard Rebizak , Rainer Anderlik , Sabine Philipp , Josef Wünsch
IPC分类号： C08L510
CPC分类号： C08L53/02 , C08L23/04 , C08L23/10 , C08L23/22 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： A thermoplastic elastomer composition comprises a) from 5 to 99% by weight of a block copolymer which is composed of hard blocks S made from vinyl aromatic monomers and of one or more random soft blocks B/S made from dienes and from vinyl aromatic monomers, b) from 1 to 95% by weight of a plasticizer with a higher polarity than white oil and with a lower polarity than diisooctyl phthalate, c) from 0 to 50% by weight of a polyolefin, and d) from 0 to 60% by weight of additives, where the total of a) to d) is 100% by weight. The use of the molding compositions to produce flexible or elastic moldings is described, as are the resultant moldings.
摘要翻译：一种热塑性弹性体组合物包含：（a）5至99重量％的由乙烯基芳族单体制成的硬质块S和由二烯和乙烯基芳族单体制成的一种或多种无规软嵌段B / S组成的嵌段共聚物，b ）1至95重量％的具有比白油高的极性并且具有比二异辛基邻苯二甲酸酯低的极性的增塑剂，c）0至50重量％的聚烯烃，和d）0至60重量％的添加剂，其中a）至d）的总量为100重量％。描述了模制组合物用于生产柔性或弹性模制品的用途，以及所得模制品。

2. 发明授权

US06593430B1 Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis 有权
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物的透明耐冲击聚苯乙烯
公开(公告)号：US06593430B1
公开(公告)日：2003-07-15
申请号：US09936784
申请日：2001-09-18
申请人： Konrad Knoll , Wolfgang Fischer , Hermann Gausepohl , Jürgen Koch , Josef Wünsch , Paul Naegele
发明人： Konrad Knoll , Wolfgang Fischer , Hermann Gausepohl , Jürgen Koch , Josef Wünsch , Paul Naegele
IPC分类号： C08F29704
CPC分类号： C08F297/044 , C08F297/04 , C08L25/06 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinylaromatic monomers and, between these, at least one random soft block B/S made from vinylaromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer.
摘要翻译：嵌段共聚物包括由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在它们之间，由乙烯基芳族单体和二烯制成的至少一个无规软嵌段B / S，其中硬嵌段的比例高于40重量％，基于总嵌段共聚物。

3. 发明授权

US06521712B1 Glass-clear impact-modified polystyrene based on styrene-butadiene block copolymers 有权
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物的透明抗冲改性聚苯乙烯
公开(公告)号：US06521712B1
公开(公告)日：2003-02-18
申请号：US09471288
申请日：1999-12-23
申请人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F29300
CPC分类号： C08F293/00 , C08F293/005 , C08F297/04 , C08L25/06 , C08L51/003 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinyl aromatic monomers and, between these, at least ore random soft block B/S made from vinyl aromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer, wherein the 1,2-vinyl content in the soft block B/S is less than 20%.
摘要翻译：嵌段共聚物包含由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在这些之间，至少是由乙烯基芳族单体制成的矿石随机软嵌段B / S和二烯，其中硬嵌段的比例高于40％，基于总嵌段共聚物，其中软嵌段B / S中的1,2-乙烯基含量小于20％。

4. 发明授权

US06369160B1 Polymer mixtures comprised of styrene polymers 有权
标题翻译：由苯乙烯聚合物组成的聚合物混合物
公开(公告)号：US06369160B1
公开(公告)日：2002-04-09
申请号：US09623179
申请日：2000-08-29
申请人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
发明人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
IPC分类号： C08L5302
CPC分类号： C08J5/18 , C08J2325/06 , C08J2353/02 , C08L25/06 , C08L53/02 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2666/24 , C08L2666/04
摘要： Polymer mixtures comprise P1) from 1 to 85% by weight of an elastomeric block copolymer which has been built up from hard blocks S made from vinylaromatic monomers and from random soft blocks B/S made up from dienes and from vinylaromatic monomers, and which contains at least the block structure S-B/S-S, where the diene content is less than 50 percent by weight and the proportion of the soft phase formed from the blocks B/S is at least 60 percent by weight, based in each case on the entire block copolymer, P2) from 5 to 89% by weight of a block copolymer differing from P1) and made from vinylaromatic monomers and from dienes, P3) from 10 to 94% by weight of glass-clear or impact-modified polystyrene or mixtures thereof, and P4) from 0 to 84% by weight of other additives, where the total of components P1) to P4) is 100%.
摘要翻译：聚合物混合物包含1至85重量％的弹性体嵌段共聚物，其由由乙烯基芳族单体制成的硬块S和由二烯和乙烯基芳族单体组成的无规软嵌段B / S构成，并且其包含至少块结构SB / SS，其中二烯含量小于50重量％，并且由块B / S形成的软相的比例为至少60重量％，基于每种情况下在整个嵌段共聚物，P2）5至89重量％的不同于P1的嵌段共聚物，并由乙烯基芳族单体和二烯制成P3）10至94重量％的玻璃透明或冲击改性的聚苯乙烯或其混合物，和P 4 ）0〜84重量％的其他添加剂，其中组分P1）至P4的总量）为100％。

5. 发明授权

US06579937B1 Thermoplastic moulding materials 有权
标题翻译：热塑性成型材料
公开(公告)号：US06579937B1
公开(公告)日：2003-06-17
申请号：US09868516
申请日：2001-06-18
申请人： Norbert Güntherberg , Josef Wünsch , Peter Ittemann , Konrad Knoll , Norbert Niessner
发明人： Norbert Güntherberg , Josef Wünsch , Peter Ittemann , Konrad Knoll , Norbert Niessner
IPC分类号： C08L2508
CPC分类号： C08L51/04 , C08F265/04 , C08F265/06 , C08L53/02 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： Thermoplastic molding compositions comprising (A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer, (B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer, (C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed of at least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, and at least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene, (D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and (E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids, are useful for producing films, moldings or fibers.
摘要翻译：包含（A）基于组分（A）至（E）的至少一种弹性体接枝共聚物为5至98重量％的热塑性模制组合物，（B）基于组分（A）的1-90重量％）（E）中的另一种共聚物，（C）基于组分（A）至（D）的1-70重量％的由至少一个共聚的嵌段CA（硬相）组成的弹性体嵌段共聚物乙烯基芳族单体的单元和具有乙烯基芳族单体和二烯的共聚单元的至少一种弹性嵌段C（B / A）（软相），（D）基于组分（A）为0至300重量％）通过（C），聚碳酸酯，和（E）0〜30重量％，基于常规添加剂和加工助剂的组分（A）至（E），可用于制备膜，模制品或纤维。

6. 发明授权

US08536279B2 Phase-separating block or graft copolymers comprising incompatible hard blocks and moulding compositions having a high stiffness 有权
标题翻译：包含不相容的硬块和具有高刚度的模塑组合物的相分离嵌段或接枝共聚物
公开(公告)号：US08536279B2
公开(公告)日：2013-09-17
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

7. 发明授权

US08222307B2 Flameproof expandable styrene polymers, and method for the production thereof 有权
标题翻译：隔爆性可发性苯乙烯聚合物及其制造方法
公开(公告)号：US08222307B2
公开(公告)日：2012-07-17
申请号：US12743755
申请日：2008-11-20
申请人： Markus Allmendinger , Bernhard Schmied , Joachim Ruch , Konrad Knoll , Michael Riethues , Klaus Hahn , Carsten Schips , Jessica Rylander
发明人： Markus Allmendinger , Bernhard Schmied , Joachim Ruch , Konrad Knoll , Michael Riethues , Klaus Hahn , Carsten Schips , Jessica Rylander
IPC分类号： C08J9/16 , C08J9/14 , C08F290/06 , C08K5/02
CPC分类号： C08K5/0066 , C08J9/0019 , C08J9/0023 , C08J9/16 , C08J2201/03 , C08J2325/06 , C08K5/02 , C08K5/14 , C08L25/06
摘要： Expandable styrene polymers (EPS) comprising, in each case based on the styrene polymer, a) from 0.05 to 5% by weight of an organic bromine compound whose bromine content is at least 50% by weight, as flame retardant, b) from 0.05 to 2% by weight of a flame retardant synergist, c) from 0.1 to 5% by weight of a metal salt as acid scavenger, and process for their production.
摘要翻译：包括在每种情况下基于苯乙烯聚合物的可发射苯乙烯聚合物（a）a）0.05至5重量％的溴含量为至少50重量％的有机溴化合物作为阻燃剂，b）0.05 至2重量％的阻燃增效剂，c）0.1至5重量％的作为酸清除剂的金属盐及其制备方法。

8. 发明授权

US08217104B2 Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures 有权
标题翻译：高度透明和坚韧的苯乙烯 - 丁二烯嵌段共聚物混合物
公开(公告)号：US08217104B2
公开(公告)日：2012-07-10
申请号：US12306258
申请日：2007-06-13
申请人： Jennifer Stewart , Peter Merkel , Daniel Wagner , Konrad Knoll , Jürgen Koch
发明人： Jennifer Stewart , Peter Merkel , Daniel Wagner , Konrad Knoll , Jürgen Koch
IPC分类号： C08F293/00 , C08F295/00 , C08F297/04 , C08L53/00 , C08L53/02
CPC分类号： C08F297/044 , C08F297/04 , C08L53/02 , C08L2205/025 , C08L2205/03 , C08L2666/02 , C08L2666/24 , C08L25/06
摘要： A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
摘要翻译：一种混合物，其包含a）25至75重量％的嵌段共聚物A，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种软块BA，每种情况由0至5重量％的乙烯基芳族单体和95〜100重量％的二烯，其中嵌段共聚物A中的硬质块S的重量比为65〜90重量％ b）5至25重量％的嵌段共聚物B，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种共聚物嵌段（B / S）B，每种情况下由20至60％由乙烯基芳族单体的重量和80〜40重量％的二烯，其中嵌段共聚物B中的硬质块S的重量比为25〜70重量％ c）0至70重量％的聚苯乙烯或除A和B之外的嵌段共聚物C，以及d）0至6重量％的增塑剂D，其中组分A）至D）的总量为100 重量％，用于透明热成型箔或透明注塑件。

9. 发明授权

US08158722B2 Tough and rigid mixtures of alpha-methylstyrene-acrylnitrile copolymers and of block copolymers 失效
标题翻译： α-甲基苯乙烯 - 丙烯腈共聚物和嵌段共聚物的韧性和刚性混合物
公开(公告)号：US08158722B2
公开(公告)日：2012-04-17
申请号：US12921043
申请日：2009-03-04
申请人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
发明人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
IPC分类号： B32B1/08 , C08L53/02
CPC分类号： C08L25/16 , C08F297/02 , C08F297/04 , C08L25/06 , C08L53/00 , C08L53/02 , C08L2205/02 , Y10T428/139 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.
摘要翻译：组合物，其包含至少一种由至少一种烷基化苯乙烯，丙烯腈和（如果合适的话）至少一种另外的单体组成的共聚物A，至少一种嵌段共聚物B，其具有至少一个形成硬相的嵌段，至少一种乙烯基芳族单体，并且具有至少一个形成软相并由至少一种乙烯基芳族单体和至少一种二烯构成的嵌段和至少一种其它共聚物C，以及如果合适的话，一种聚合物D，其中共聚物C 是由至少一种乙烯基芳族单体组成的第一嵌段，至少由一种二烯构成的第二嵌段和由至少一种甲基丙烯酸甲酯单体组成的第三嵌段或至少包含至少50％的甲基丙烯酸甲酯，聚合物D是选自玻璃透明和耐冲击聚苯乙烯的至少一种苯乙烯聚合物。本发明还涉及制备本发明组合物的方法，本发明组合物用于生产模制品，箔，纤维或泡沫的用途，用于模制品，箔，纤维或泡沫，其包括本发明的组合物，以及本发明组合物用作电子部件的包装，例如集成电路（微芯片）（“电子包装”），用于化学工程，家用产品，浴室用品中的应用，例如牙刷滚筒，化妆品保持器等，作为外壳，作为管，用作医疗用品或医疗装置的型材，以及玩具。

10. 发明申请

US20120061287A1 PHASE-SEPARATING BLOCK OR GRAFT COPOLYMERS COMPRISING INCOMPATIBLE HARD BLOCKS AND MOULDING COMPOSITIONS HAVING A HIGH STIFFNESS 有权
标题翻译：包含不合适硬块的相分离块或共聚物和具有高刚度的成型组合物
公开(公告)号：US20120061287A1
公开(公告)日：2012-03-15
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： B65D85/86 , C08L53/02 , C08F12/08
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的组分的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

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