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    • 1. 发明授权
    • Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures
    • 高度透明和坚韧的苯乙烯 - 丁二烯嵌段共聚物混合物
    • US08217104B2
    • 2012-07-10
    • US12306258
    • 2007-06-13
    • Jennifer StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • Jennifer StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • C08F293/00C08F295/00C08F297/04C08L53/00C08L53/02
    • C08F297/044C08F297/04C08L53/02C08L2205/025C08L2205/03C08L2666/02C08L2666/24C08L25/06
    • A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
    • 一种混合物,其包含a)25至75重量%的嵌段共聚物A,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种软块BA,每种情况由0至5重量% 的乙烯基芳族单体和95〜100重量%的二烯,其中嵌段共聚物A中的硬质块S的重量比为65〜90重量% b)5至25重量%的嵌段共聚物B,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种共聚物嵌段(B / S)B,每种情况下由20至60%由 乙烯基芳族单体的重量和80〜40重量%的二烯,其中嵌段共聚物B中的硬质块S的重量比为25〜70重量% c)0至70重量%的聚苯乙烯或除A和B之外的嵌段共聚物C,以及d)0至6重量%的增塑剂D,其中组分A)至D)的总量为100 重量%,用于透明热成型箔或透明注塑件。