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1. 发明申请

US20050009990A1 Transparent styrol-butadiene block copolymer mixtures 失效
标题翻译：透明苯乙烯 - 丁二烯嵌段共聚物混合物
公开(公告)号：US20050009990A1
公开(公告)日：2005-01-13
申请号：US10496080
申请日：2002-11-19
申请人： Konrad Knoll , Philippe Desbois , Hans-Michael Walter , Michael Ishaque , Till Gerlach , Friederike Osswald
发明人： Konrad Knoll , Philippe Desbois , Hans-Michael Walter , Michael Ishaque , Till Gerlach , Friederike Osswald
IPC分类号： C08F279/02 , C08F297/04 , C08L25/04 , C08L53/02 , C08L53/00
CPC分类号： C08L53/02 , C08F297/04 , C08L53/025 , C08L2666/24
摘要： Mixtures comprising linear block copolymers made from vinylaromatic monomers and from dienes of the structure (I) S1—B1—S2 and (II) S3—B2—S4, where S1 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 40,000 to 100,000 g/mol, each of S2, S3 and S4 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 5,000 to 20,000 g/mol, each of B1 and B2 is a block made from dienes or a copolymer block made from dienes and from vinylaromatic monomers with number-average molar mass Mn in the range from 15,000 to 40,000 g/mol, and the ratio of the block copolymers (I)/(II) is in the range from 0.6 to 2.
摘要翻译：包括由乙烯基芳族单体和结构（I）S1-B1-S2和（II）S3-B2-S4的二烯制备的线性嵌段共聚物的混合物，其中S1是由具有数均摩尔质量Mn的乙烯基芳族单体制成的嵌段 40,000至100,000g / mol的范围，S2，S3和S4中的每一个是由数均摩尔质量Mn在5,000至20,000g / mol范围内的乙烯基芳族单体制成的嵌段，B1和B2各自为嵌段由二烯制得的共聚物嵌段和数均摩尔质量Mn为15,000至40,000g / mol的乙烯基芳族单体，并且嵌段共聚物（I）/（II）的比例在从0.6到2。

2. 发明授权

US07064164B2 Transparent styrol-butadiene block copolymer mixtures 失效
标题翻译：透明苯乙烯 - 丁二烯嵌段共聚物混合物
公开(公告)号：US07064164B2
公开(公告)日：2006-06-20
申请号：US10496080
申请日：2002-11-19
申请人： Konrad Knoll , Philippe Desbois , Hans-Michael Walter , Michael Ishaque , Till Gerlach , Friederike Osswald
发明人： Konrad Knoll , Philippe Desbois , Hans-Michael Walter , Michael Ishaque , Till Gerlach , Friederike Osswald
IPC分类号： C08F297/04
CPC分类号： C08L53/02 , C08F297/04 , C08L53/025 , C08L2666/24
摘要： The present invention relates to mixtures comprising linear block copolymers made from vinylaromatic monomers and from dienes of the structure (I) S1-B1-S2 and (II) S3-B2-S4, where S1 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 40,000 to 100,000 g/mol, each of S2, S3 and S4 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 5,000 to 20,000 g/mol, each of B1 and B2 is a block made from dienes or a copolymer block made from dienes and from vinylaromatic monomers with numberaverage molar mass Mn in the range from 15,000 to 40,000 g/mol, and the ratio of the block copolymers (I)/(II) is in the range from 0.6 to 2.
摘要翻译：本发明涉及包含由乙烯基芳族单体和结构式（I）的二烯制备的线性嵌段共聚物的混合物，其中R 1，R 2，R 2，和（II）S 3 -S 2 -S S 4，其中S 1是一个制成的块来自具有40,000至100,000g / mol的数均分子量M N n N的乙烯基芳族单体，S 2，S 3，和S 4是由数均分子量M 2 N 2以上的乙烯基芳族单体制成的嵌段，其数量为5,000〜20,000g / mol，B 1 和B 2是由二烯制成的嵌段或由二烯制成的共聚物嵌段和数均分子量M N n N的乙烯基芳族单体在15,000至 40,000g / mol，嵌段共聚物（I）/（II）的比例在0.6〜2的范围内。

3. 发明申请

US20080125549A1 COUPLING OF LIVING CARBOCATIONIC POLYMERS 审中-公开
标题翻译：生活CARCOCICIC聚合物的联合
公开(公告)号：US20080125549A1
公开(公告)日：2008-05-29
申请号：US11564650
申请日：2006-11-29
申请人： Judit E. PUSKAS , Szilard Csihony , Konrad Knoll , Heike Pfistner , Hans-Michael Walter
发明人： Judit E. PUSKAS , Szilard Csihony , Konrad Knoll , Heike Pfistner , Hans-Michael Walter
IPC分类号： C08F297/00
CPC分类号： C08F299/00
摘要： A process for coupling a living carbocationic polymer by reacting two molecules of a living carbocationic polymer with a coupling agent, the coupling agent having the formula I: CR1R2═CR3-Zn—CR4═CR5R6 (I) wherein R1, R2, R3, R4, R5 and R6 are, independently from one another, hydrogen, alkyl, or alkenyl, or two of R1, R2, R3, R4, R5 and R6, together are alkylene or alkenylene, Z is CR7R8, R7 and R8 are, independently from one another, hydrogen or alkyl, and n is 0 or an integer from 1 to 5, with the proviso that, when R3 is hydrogen, both R1 and R2 are different from hydrogen, and, when R4 is hydrogen, both R5 and R6 are different from hydrogen. The process allows for the convenient preparation of ABA-type block copolymers and of telechelic polymers.
摘要翻译：通过使活性碳阳离子聚合物的两分子与偶联剂反应来偶联活性碳阳离子聚合物的方法，具有式I的偶联剂：<？in-line-formula description =“In-line Formulas”end =“lead” ？>>>>> 2 2>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>> 其中R 1是一个或多个，其中R 1，R 2，R 3，R 6， R 2，R 3，R 4，R 5，R 5和R 6，氢，烷基或链烯基，或R 1，R 2，R 3，R 3，R 3， R 4，R 5和R 6一起是亚烷基或亚烯基，Z是CR 7 R 7， R 8，R 7和R 8彼此独立地为氢或烷基，n为0或1至5的整数，条件是当R 3是氢时，R 1和R 2都不同于氢，并且wh R 4是氢，R 5和R 6都不同于氢。该方法可以方便地制备ABA型嵌段共聚物和遥爪聚合物。

4. 发明申请

US20050272875A1 Anionically polymerized impact polystyrene having good flowability 审中-公开
标题翻译：具有良好流动性的阴离子聚合抗冲聚苯乙烯
公开(公告)号：US20050272875A1
公开(公告)日：2005-12-08
申请号：US10527039
申请日：2003-09-04
申请人： Philippe Desbois , Hans-Dieter Schwaben , Ulrike Dardin , Hans-Michael Walter
发明人： Philippe Desbois , Hans-Dieter Schwaben , Ulrike Dardin , Hans-Michael Walter
IPC分类号： C08L25/04 , C08F2/38 , C08F2/44 , C08F4/46 , C08F279/00 , C08F287/00 , C08F297/04 , C08L51/00 , C08L53/02 , D01F6/30 , C08L25/02
CPC分类号： C08L51/006 , C08F287/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L2666/04
摘要： The invention relates to anionically polymerized impact polystyrene which is characterized in that it has a melt volume flow rate MVR of at least 8 cm3/10 min which is measured in accordance with EN ISO 1133 at a test temperature of 200°C. and with a nominal load of 5 kg.
摘要翻译：本发明涉及阴离子聚合的抗冲聚苯乙烯，其特征在于其具有至少8cm 3 / 10min的熔体体积流量MVR，其在试验温度下根据EN ISO 1133测量为200°C。标称负荷为5公斤。

5. 发明授权

US4822945A Preparation of decene oligomers and use thereof as lubricating oils 失效
标题翻译：癸烯低聚物的制备及其作为润滑油的用途
公开(公告)号：US4822945A
公开(公告)日：1989-04-18
申请号：US128342
申请日：1987-12-03
申请人： Klaus Bronstert , Helmut Mach , Hans P. Rath , Hans-Michael Walter
发明人： Klaus Bronstert , Helmut Mach , Hans P. Rath , Hans-Michael Walter
IPC分类号： C07C2/30 , C08F110/14 , C10M107/10 , C07C2/02
CPC分类号： C10M107/10 , C07C2/30 , C08F110/14 , C07C2531/02 , C07C2531/14 , C10M2205/028 , C10N2220/02
摘要： Decene oligomers useful with or without hydrogenation as basis for synthetic lubricating oils are prepared by oligomerizing decene-1 in the presence of an alkylaluminum chloride catalyst and an alkyl halide cocatalyst, in a first reaction stage the decene-1 being mixed with the catalyst at from 0 to +25.degree. C. and being kept in contact therewith within the same temperature range for not less than 15 minutes and in a second reaction stage the cocatalyst being added at from 0 to +35.degree. C. in the course of a period of from 15 to 180 minutes.
摘要翻译：通过在烷基氯化铝催化剂和烷基卤助催化剂存在下使癸烯-1低聚而制备用于合成润滑油或不加氢的癸烯低聚物，在第一反应阶段中，癸烯-1与催化剂在 0至+25℃，并在相同温度范围内保持接触不少于15分钟，而在第二反应阶段，助催化剂在0至+35℃的加入过程中从15到180分钟。

6. 发明申请

US20090023882A1 PROCESS FOR PREPARATION OF POLYISOBUTYLENE WHOSE CONTENT OF TERMINAL DOUBLE BONDS IS MORE THAN 50% FROM AN INDUSTRIAL C4 HYDROCARBON STREAM COMPRISING 1-BUTENE, 2-BUTENE AND ISOBUTENE 审中-公开
标题翻译：用于制备聚异丁烯的方法包含1-BOTENE，2-BOTENE和ISOBUTENE的端子双重含量的含量超过了工业C4烃类流体的50％以上
公开(公告)号：US20090023882A1
公开(公告)日：2009-01-22
申请号：US12278590
申请日：2007-02-15
申请人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
发明人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C08F110/10
CPC分类号： C10G57/02 , C08F110/10 , C10G25/00 , C10G2300/1044 , C10G2300/1092 , C08F2/00
摘要： Preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene using a polymerization catalyst customary therefor from a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream which may comprise up to 3000 ppm by weight, of 1,3-butadiene, by reducing the content of oxygenates in the C4 hydrocarbon stream before the polymerization of the isobutene by contacting it with an inorganic adsorbent at a pressure of from 1 to 20 bar and a temperature of from 20 to 220° C.
摘要翻译：通过聚合催化剂制备具有大于50％的末端双键的聚异丁烯，所用的聚合催化剂通常来自可以包含高达3000ppm的1-丁烯，2-丁烯和异丁烷的C4烃流通过在异丁烯聚合之前通过将其与无机吸附剂在1至20巴的压力和20至20℃的温度下接触来降低C4烃流中的含氧化合物的含量，从而降低1,3-丁二烯的含量 220°C

7. 发明申请

US20100292422A1 METHOD FOR PRODUCING COPOLYMERS MADE FROM ISOBUTENE AND AT LEAST ONE VINYLAROMATIC COMPONENT 审中-公开
标题翻译：从ISOBUTENE和至少一种乙烯基成分制备共聚物的方法
公开(公告)号：US20100292422A1
公开(公告)日：2010-11-18
申请号：US12063034
申请日：2006-08-11
申请人： Hans Peter Rath , Hans-Michael Walter , Oskar Nuyken , Fritz Elmar Kuehn , Yanmei Zhang , Hui Yee Yeong , Brigitte Voit , Radha Krishnan Narayanan
发明人： Hans Peter Rath , Hans-Michael Walter , Oskar Nuyken , Fritz Elmar Kuehn , Yanmei Zhang , Hui Yee Yeong , Brigitte Voit , Radha Krishnan Narayanan
IPC分类号： C08F4/44
CPC分类号： C08F8/00 , C08F210/10 , C08K3/00 , C08L23/22 , C08F10/00 , C08F4/695 , C08F212/08
摘要： The invention relates to a method for producing copolymers made from isobutene and at least one vinylaromatic component. Said method consists of polymerising isobutene or a hydrocarbon mixture containing isobutene with at least one vinylaromatic compound in the presence of a solvent-stable transistion metal complex comprising slightly co-ordinating anions as a polymerisation catalyst. The invention also relates to copolymers made of isobutene and at least one vinylaromatic compound, which can be obtained by means of said inventive method, in addition to specific functionalisation products therefrom.
摘要翻译：本发明涉及一种由异丁烯和至少一种乙烯基芳族成分制备共聚物的方法。所述方法包括将异丁烯或含有异丁烯的烃混合物与至少一种乙烯基芳族化合物在溶剂稳定的转移金属络合物存在下聚合，所述络合物包含稍微配位的阴离子作为聚合催化剂。本发明还涉及由异丁烯和至少一种乙烯基芳族化合物制成的共聚物，其可以通过所述本发明方法获得，除了其中的特定的官能化产物。

8. 发明申请

US20090018298A1 COPOLYMERS FORMED BY RADICAL POLYMERIZATION 审中-公开
标题翻译：由辐射聚合形成的共聚物
公开(公告)号：US20090018298A1
公开(公告)日：2009-01-15
申请号：US12025675
申请日：2008-02-04
申请人： Josef Michl , Kamesh Vyakaranam , Stefanie Koerbe , Phillip Hanefeld , Hans-Michael Walter , Arno G. Lange
发明人： Josef Michl , Kamesh Vyakaranam , Stefanie Koerbe , Phillip Hanefeld , Hans-Michael Walter , Arno G. Lange
IPC分类号： C08F220/18
CPC分类号： C08F4/484 , C08F4/00 , C08F110/10 , C08F110/14 , C08F210/00
摘要： Certain copolymers formed from alkenes and one or more activated alkenes. In particular copolymers of isobutylene and one or more activated alkenes. Activated alkenes are, for example, selected from alkyl acrylates, alkyl methacrylates, maleic anhydride, or isobutenyl succinic anhydride.
摘要翻译：由烯烃和一种或多种活化烯烃形成的某些共聚物。特别是异丁烯和一种或多种活化烯烃的共聚物。活性烯烃例如选自丙烯酸烷基酯，甲基丙烯酸烷基酯，马来酸酐或异丁烯基琥珀酸酐。

9. 发明授权

US5266647A Branched copolymers 失效
标题翻译：支链共聚物
公开(公告)号：US5266647A
公开(公告)日：1993-11-30
申请号：US596384
申请日：1990-10-12
申请人： Dietmar Bender , Klaus Bronstert , Hans-Michael Walter , Daniel Wagner , Helmut Mach
发明人： Dietmar Bender , Klaus Bronstert , Hans-Michael Walter , Daniel Wagner , Helmut Mach
IPC分类号： C08F297/04 , C08C19/44 , C08F8/04 , C08F297/02 , C08F297/00 , C08F293/00
CPC分类号： C08F8/04 , C08C19/44
摘要： A copolymer with stellate branching, of the general formula [A-].sub.k X, where A is the monovalent radical of a homopolymer, block copolymer or random copolymer of a conjugated diene and/or vinyl-aromatic hydrocarbon, k is a number from 1 to 10, and X is the k-valent radical of a coupling center produced by coupling with hexatriene, and the product of the hydrogenation thereof are described.
摘要翻译：具有通式[A-] kX的星状支化的共聚物，其中A是共轭二烯和/或乙烯基芳族烃的均聚物，嵌段共聚物或无规共聚物的一价基团，k为1至 10，X是通过与己烯偶联产生的偶联中心的k价基团，并描述其氢化产物。

10. 发明申请

US20100170636A1 SEMI-INTERPENETRATING NETWORK HAVING A PHASE OF A LINEAR NONCROSSLINKED ISOBUTENE POLYMER 审中-公开
标题翻译：具有线性非交联ISOBUTENE聚合物相的半互连网络
公开(公告)号：US20100170636A1
公开(公告)日：2010-07-08
申请号：US12664527
申请日：2008-06-19
申请人： Phillip Hanefeld , Nicole Hildebrandt , Klaus Muehlbach , Helmut Mach , Hans-Michael Walter , Dominique Teyssie , Odile Fichet , Cedric Vancaeyzeele , Benjamin Davion
发明人： Phillip Hanefeld , Nicole Hildebrandt , Klaus Muehlbach , Helmut Mach , Hans-Michael Walter , Dominique Teyssie , Odile Fichet , Cedric Vancaeyzeele , Benjamin Davion
IPC分类号： C08L23/00 , C08L25/02 , C08L83/04 , C08L75/04 , C08L75/02 , B32B37/12 , B05D3/02 , B05D3/06
CPC分类号： C08J3/246 , C08F255/08 , C08J2323/22 , C08L23/22 , C08L33/08 , C08L2205/04 , C08L2205/22 , C08L2666/06
摘要： A description is given of a semi-interpenetrating network having a first phase of a linear noncrosslinked isobutene polymer and a second phase of a crosslinked polymer, wherein the crosslinked polymer is obtained by crosslinking molecular enlargement reaction in the presence of the isobutene polymer. The crosslinked polymer is preferably obtained by free-radical polymerization of ethylenically unsaturated monomers comprising at least one polyethylenically unsaturated monomer. The networks are suitable as molding compounds having gas and moisture barrier effect or as adhesives.
摘要翻译：给出了具有线性非交联异丁烯聚合物的第一相和交联聚合物的第二相的半互穿网络的描述，其中交联聚合物通过在异丁烯聚合物存在下进行分子扩增反应而获得。交联聚合物优选通过包含至少一种多烯属不饱和单体的烯属不饱和单体的自由基聚合而获得。网络适合作为具有气体和水分阻隔作用的模制化合物或作为粘合剂。

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