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    • 3. 发明申请
    • Method for Manufacturing Semiconductor Wafer
    • 半导体晶片制造方法
    • US20090047526A1
    • 2009-02-19
    • US11840615
    • 2007-08-17
    • Masaharu NinomiyaKoji MatsumotoMasahiko NakamaeMasanobu MiyaoTaizoh Sadoh
    • Masaharu NinomiyaKoji MatsumotoMasahiko NakamaeMasanobu MiyaoTaizoh Sadoh
    • H01L21/20B32B9/04
    • H01L21/76254
    • A method for manufacturing a semiconductor wafer with a strained Si layer having sufficient tensile strain and few crystal defects, while achieving a relatively simple layered structure, is provided. The method includes the steps of: (a) forming an SiGe mixed crystal layer 12 and a first Si layer 13 in this order on the surface of a silicon wafer 11; (b) forming an SiO2 layer 16 on top of the first Si layer and/or a support wafer 14; (c) forming a layered product 17 by stacking the silicon wafer and the support wafer with the SiO2 layer being placed therebetween; (d) forming a second Si layer 18 by thinning the silicon wafer of the layered product; (e) implanting hydrogen ion and/or rare gas ion, such that ionic concentration peaks in a predetermined area; (f) subjecting the layered product to a first heat treatment; and (g) carrying out a second heat treatment following the first heat treatment, thereby relaxing the SiGe mixed crystal layer and diffusing Ge through portions of the first Si layer and the second Si layer.
    • 本发明提供一种制造半导体晶片的方法,该半导体晶片具有具有足够的拉伸应变和很少的晶体缺陷的应变Si层,同时实现相对简单的分层结构。 该方法包括以下步骤:(a)在硅晶片11的表面上依次形成SiGe混晶层12和第一Si层13; (b)在第一Si层和/或支撑晶片14的顶部上形成SiO2层16; (c)通过将硅晶片和支撑晶片叠置在其间的SiO 2层来形成层叠体17; (d)通过使层叠体的硅晶片变薄来形成第二Si层18; (e)植入氢离子和/或稀有气体离子,使得离子浓度在预定区域中峰值; (f)对层叠体进行第一次热处理; 和(g)在第一热处理之后进行第二热处理,从而使SiGe混晶层松弛,并通过第一Si层和第二Si层的一部分扩散Ge。
    • 7. 发明授权
    • Method for manufacturing semiconductor wafer including a strained silicon layer
    • 包括应变硅层的半导体晶片的制造方法
    • US07767548B2
    • 2010-08-03
    • US11840615
    • 2007-08-17
    • Masaharu NinomiyaKoji MatsumotoMasahiko NakamaeMasanobu MiyaoTaizoh Sadoh
    • Masaharu NinomiyaKoji MatsumotoMasahiko NakamaeMasanobu MiyaoTaizoh Sadoh
    • H01L21/30
    • H01L21/76254
    • A method for manufacturing a semiconductor wafer with a strained Si layer having sufficient tensile strain and few crystal defects, while achieving a relatively simple layered structure, is provided. The method includes the steps of: (a) forming an SiGe mixed crystal layer 12 and a first Si layer 13 in this order on the surface of a silicon wafer 11; (b) forming an SiO2 layer 16 on top of the first Si layer and/or a support wafer 14; (c) forming a layered product 17 by stacking the silicon wafer and the support wafer with the SiO2 layer being placed therebetween; (d) forming a second Si layer 18 by thinning the silicon wafer of the layered product; (e) implanting hydrogen ion and/or rare gas ion, such that ionic concentration peaks in a predetermined area; (f) subjecting the layered product to a first heat treatment; and (g) carrying out a second heat treatment following the first heat treatment, thereby relaxing the SiGe mixed crystal layer and diffusing Ge through portions of the first Si layer and the second Si layer.
    • 本发明提供一种制造半导体晶片的方法,该半导体晶片具有具有足够的拉伸应变和很少的晶体缺陷的应变Si层,同时实现相对简单的分层结构。 该方法包括以下步骤:(a)在硅晶片11的表面上依次形成SiGe混晶层12和第一Si层13; (b)在第一Si层和/或支撑晶片14的顶部上形成SiO2层16; (c)通过将硅晶片和支撑晶片叠置在其间的SiO 2层来形成层叠体17; (d)通过使层叠体的硅晶片变薄来形成第二Si层18; (e)植入氢离子和/或稀有气体离子,使得离子浓度在预定区域中峰值; (f)对层叠体进行第一次热处理; 和(g)在第一热处理之后进行第二热处理,从而使SiGe混晶层松弛,并通过第一Si层和第二Si层的一部分扩散Ge。
    • 8. 发明授权
    • Silicon epitaxial wafer manufacturing method
    • 硅外延片制造方法
    • US06261362B1
    • 2001-07-17
    • US09395960
    • 1999-09-14
    • Takashi FujikawaMasaharu Ninomiya
    • Takashi FujikawaMasaharu Ninomiya
    • C30B1520
    • C30B29/06C30B15/00
    • The objective of this invention is to provide a manufacturing method wherewith optimally low-COP substrates can be efficiently manufactured for epitaxial wafers in order to obtain high epitaxial surface quality that will not have an adverse effect on device characteristics. A phenomenon was discovered whereby COPs are eliminated by solution annealing or flattening when epitaxial films are formed on wafers wherein the density of grown-in defects (COPs) with a size of 0.130 &mgr;m or larger is 0.03 defects/cm2 or lower, the use of which phenomenon is characteristic of the invention. For example, by pulling a monocrystal while deliberately controlling the carbon concentration therein to within a prescribed high range, and employing wafers cut from silicon monocrystal ingots grown with a pulling speed wherewith no OSF-ring outer region is present in the wafer surface, wafers having the low COP densities noted above are obtained, and the COPs are eliminated by solution-annealing or flattening when forming the epitaxial film, wherefore high-quality epitaxial wafers can be manufactured with good yield.
    • 本发明的目的是提供一种制造方法,其中为了获得不会对器件特性产生不利影响的高外延表面质量,可以有效地制造用于外延晶片的最佳低COP衬底。 发现一种现象,其中当在晶片上形成外延膜时,通过固溶退火或平坦化消除COP,其中尺寸为0.130μm或更大的生长缺陷(COP)的密度为0.03缺陷/ cm2或更低, 该现象是本发明的特征。 例如,通过在有意地将碳浓度控制在规定的高范围内的同时拉动单晶体,并且使用从在晶片表面没有OSF环外部区域的拉拔速度生长的硅单晶锭切割的晶片,具有 获得上述的低COP密度,并且在形成外延膜时通过固溶退火或平坦化来消除COP,因此可以以良好的成品率制造高品质的外延晶片。
    • 9. 发明授权
    • Semiconductor substrate and field-effect transistor, and manufacturing method for same
    • 半导体衬底和场效晶体管及其制造方法
    • US07405142B2
    • 2008-07-29
    • US10544310
    • 2003-02-06
    • Ichiro ShionoMasaharu NinomiyaHazumu Kougami
    • Ichiro ShionoMasaharu NinomiyaHazumu Kougami
    • H01L21/44
    • H01L29/165H01L21/02381H01L21/0245H01L21/02502H01L21/02505H01L21/0251H01L21/02532H01L21/0262H01L29/1054
    • A semiconductor substrate manufacturing method has a first layer formation process, a second layer formation process, a heat treatment process, and a polishing process; in the first layer formation process, the thickness of the first SiGe layer is set to less than twice the critical thickness, which is the film thickness at which dislocations appear and lattice relaxation occurs due to increasing film thickness; in the second layer formation process, the Ge composition ratio of the second SiGe layer is at least at the contact face with the first SiGe layer or with the Si layer, set lower than the maximum value of the Ge composition ratio in the first SiGe layer, and moreover, a gradient composition region in at least a portion of which the Ge composition ratio increases gradually toward the surface is formed. By this means, the penetrating dislocation density is kept low, surface roughness is low, and worsening of roughness at the surface and at interfaces due to heat treatment in device manufacturing processes or similar is prevented.
    • 半导体衬底制造方法具有第一层形成工艺,第二层形成工艺,热处理工艺和抛光工艺; 在第一层形成工艺中,第一SiGe层的厚度被设定为小于临界厚度的两倍,临界厚度是由于增加膜厚而发生位错的膜厚度和晶格弛豫; 在第二层形成工艺中,第二SiGe层的Ge组成比至少在与第一SiGe层或Si层的接触面处设定为低于第一SiGe层中的Ge组成比的最大值 ,并且形成至少部分Ge组成比逐渐朝向表面增加的梯度组成区域。 通过这种方式,穿透位错密度保持较低,表面粗糙度低,并且防止了器件制造过程中类似的热处理在表面和界面处的粗糙度恶化。