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    • 6. 发明授权
    • Silver halide photographic light-sensitive materials
    • 卤化银照相感光材料
    • US5240826A
    • 1993-08-31
    • US788344
    • 1991-11-06
    • Nobuaki MiyasakaHideo IkedaShigeru Ohno
    • Nobuaki MiyasakaHideo IkedaShigeru Ohno
    • G03C1/09
    • G03C1/09
    • A novel silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer coated on at least one side of a support, wherein said photographic emulsion layer comprises a light-sensitive silver halide emulsion and said photographic emulsion or other layer(s) comprises a substantially light-insensitive, unfogged silver halide fine grain emulsion, with a heterocyclic mercapto compound represented by the following general formula (I) being adsorbed on the fine grains in said emulsion: general formula (I) ##STR1## wherein X represents --O--, --NH--, or --S--; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are a hydrogen atom or a substituent group; at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a substituted or unsubstituted alkyl or aryl group having up to 13 carbon atoms, such alkyl or aryl being bonded directly or through a divalent linkage group to the aromatic nucleus; X.sub.1 represents a hydrogen atom or a cation, such cation being required to neutralize the molecule.The silver halide photographic light-sensitive material is a high-speed material which exhibits improved granularity, gradation and rate of development.
    • 一种新型卤化银照相感光材料,其具有涂覆在载体的至少一侧上的至少一个卤化银照相乳剂层,其中所述照相乳剂层包含感光卤化银乳剂和所述照相乳剂或其它层 )包含基本上不光泽的未雾化的卤化银细粒乳液,其中由以下通式(I)表示的杂环巯基化合物被所述乳液中的细晶粒吸附:通式(I)其中X表示 -O - , - NH-或-S-; R1,R2,R3和R4是氢原子或取代基; R 1,R 2,R 3和R 4中的至少一个是具有至多13个碳原子的取代或未取代的烷基或芳基,所述烷基或芳基直接键合或通过二价连接基团键合至芳香核; X1表示氢原子或阳离子,这种阳离子是中和分子所必需的。 卤化银摄影感光材料是高速材料,其表现出改善的粒度,分级和发展速度。
    • 8. 发明授权
    • Direct positive photographic materials
    • 直接正面摄影材料
    • US4945033A
    • 1990-07-31
    • US291017
    • 1988-12-28
    • Naoyasu DeguchiShigeru Ohno
    • Naoyasu DeguchiShigeru Ohno
    • G03C1/485G03C1/825G03C1/83G03C7/00
    • G03C1/832G03C1/48538G03C1/48561
    • A direct positive photographic material which has at least one previously-not-fogged internal latent image-type silver halide emulsion layer on a support, wherein the photographic material contains at least one compound represented by the following formula (I): ##STR1## wherein each of R.sub.1 and R.sub.2 represents an alkyl group, an aryl group, a cyano group, --COOR.sub.5, --CONR.sub.5 R.sub.6, --OR.sub.5, --NR.sub.5 R.sub.6, --NR.sub.6 COR.sub.7, --NR.sub.5 CONR.sub.5 R.sub.6, --NR.sub.6 SO.sub.2 R.sub.7 (each of R.sub.5 and R.sub.6 represents a hydrogen atom, an alkyl group or an aryl group; R.sub.7 represents an alkyl or aryl group; R.sub.5 and R.sub.6, or R.sub.6 and R.sub.7 may link together to form a 5- or 6-membered ring); each of R.sub.3 and R.sub.4 represents a hydrogen atom or an alkyl group; each of Q.sub.1 and Q.sub.2 represents an aryl group; each of X.sub.1 and X.sub.2 represents a bond or a divalent linking group; each of Y.sub.1 and Y.sub.2 represents a sulfo group or a carboxyl group; each of L.sub.1, L.sub.2 and L.sub.3 represents a methine group; n represents 0, 1, or 2; each of m.sub.1 and m.sub.2 represents 1 or 2; each of p.sub.1 and p.sub.2 represents 0, 1, 2, 3 or 4; and each of q.sub.1 and q.sub.2 represents 1 or 2.The photographic materials show no change in photographic performance after preservation under high temperature and high humidity and give images of high sharpness.
    • 10. 发明授权
    • Near infrared absorbing composition
    • 近红外吸收组合物
    • US4923638A
    • 1990-05-08
    • US331075
    • 1989-03-28
    • Shigeru OhnoYuji MiharaKeiichi AdachiToshinao UkaiGouichi Hayashi
    • Shigeru OhnoYuji MiharaKeiichi AdachiToshinao UkaiGouichi Hayashi
    • B41M5/46
    • B41M5/465
    • A near infrared absorbing composition is disclosed, containing at least one compound represented by general formula (I), having its absorption maxima at wavelengths of 720 nm or more: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sup.2 and R.sup.5, which may be the same or different, each represents a hydrogen atom or a group capable of substituting a hydrogen atom; R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted alkyl group with the proviso that they do not simultaneously represent hydrogen atoms; and R.sup.6 and R.sup.7, which may be the same or different, each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an acyl group or a sulfonyl group, or R.sup.6 and R.sup.7 may be taken together to form a 5- or 6-membered ring.
    • 公开了一种近红外线吸收组合物,其含有至少一种通式(I)表示的化合物,其波长为720nm以上的吸收最大值:其中R 1表示取代或未取代的烷基, 取代或未取代的芳基或取代或未取代的杂环基; R 2和R 5可以相同或不同,各自表示氢原子或能够取代氢原子的基团; R 3和R 4可以相同或不同,各自表示氢原子,卤素原子,取代或未取代的烷氧基或取代或未取代的烷基,条件是它们不同时表示氢原子; 和可以相同或不同的R 6和R 7各自表示取代或未取代的烷基,取代或未取代的芳基,酰基或磺酰基,或者R 6和R 7可以一起形成5- 或6元环。