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1. 发明授权

US06727318B1 Method for producing aqueous polymer dispersions containing colorants 失效
标题翻译：含有着色剂的聚合物水分散体的制备方法
公开(公告)号：US06727318B1
公开(公告)日：2004-04-27
申请号：US09600868
申请日：2000-08-09
申请人： Klemens Mathauer , Arno Böhm , Walter Mächtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Müllen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlösser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rüdiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
发明人： Klemens Mathauer , Arno Böhm , Walter Mächtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Müllen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlösser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rüdiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
IPC分类号： C08K300
CPC分类号： C08F2/32 , C08F2/44 , C08K3/00 , C09B69/102
摘要： The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter
摘要翻译：本发明涉及一种在自由基引发剂存在下通过烯键式不饱和单体的自由基水乳液聚合制备含染料的聚合物水分散体的方法，其中至少一些单体以水包油乳液E1，其分散相包含至少一种油溶性染料，其中E1的分散相基本上由具有直径<500nm的含染料的单体液滴形成。本发明还涉及如权利要求35所述的式III的苝染料。本发明除了含有染料的制剂外，还包括本发明的含染料的聚合物和着色剂，其包含本发明包括荧光增白剂。

2. 发明授权

US06541032B1 Use of finely divided dye-containing polymers PD as color-imparting constituent in cosmetic compositions 失效
标题翻译：在化妆品组合物中使用细分散的含染料的聚合物PD作为赋色成分
公开(公告)号：US06541032B1
公开(公告)日：2003-04-01
申请号：US09677864
申请日：2000-10-03
申请人： Monika Medelnick , Ellen Pfrommer , Thorsten Clemens , Peter Erk , Arno Böhm , Sabine Kielhorn-Bayer , Helmut Witteler , Wilma M. Dausch , Horst Westenfelder , Thomas Wünsch , Klemens Mathauer , Thorsten Habeck , Takahiro Ikeda , Hideyuki Ichihara
发明人： Monika Medelnick , Ellen Pfrommer , Thorsten Clemens , Peter Erk , Arno Böhm , Sabine Kielhorn-Bayer , Helmut Witteler , Wilma M. Dausch , Horst Westenfelder , Thomas Wünsch , Klemens Mathauer , Thorsten Habeck , Takahiro Ikeda , Hideyuki Ichihara
IPC分类号： A61K914
CPC分类号： A61Q5/06 , A61K8/046 , A61K8/8152 , A61K8/8158 , A61Q1/02 , A61Q1/06 , A61Q1/08 , A61Q1/10 , A61Q3/02 , A61Q5/00 , A61Q17/04 , Y10S514/844 , Y10S514/937
摘要： The present invention describes the use of finely divided dye-containing polymers PD in the form of an aqueous polymer dispersion or a polymer powder obtainable therefrom, the polymer matrix of which comprises at least one organic dye D in homogeneously dispersed form, as color-imparting constituent in cosmetic compositions. The present invention also describes cosmetic compositions which comprise a color-containing polymer in an amount of from 0.1 to 50% by weight, based on the total weight of the cosmetic composition, and additives customary for cosmetic compositions.
摘要翻译：本发明描述了使用细分散的含染料的聚合物PD，其形式为聚合物水分散体或由其获得的聚合物粉末，其聚合物基质包含至少一种均匀分散形式的有机染料D，作为赋色剂化妆品组合物中的成分。本发明还描述了化妆品组合物，其包含基于化妆品组合物的总重量为0.1-50重量％的含颜色聚合物和用于化妆品组合物的添加剂。

3. 发明授权

US06890377B2 Thermochromic rylene dyes 失效
标题翻译：热变色二甲苯染料
公开(公告)号：US06890377B2
公开(公告)日：2005-05-10
申请号：US10468016
申请日：2002-02-14
申请人： Arno Böhm , Matthias Krieger , Stefan Becker , Klaus Müllen
发明人： Arno Böhm , Matthias Krieger , Stefan Becker , Klaus Müllen
IPC分类号： C07B61/00 , C07D221/18 , C09B5/62 , C09D5/26 , C09D7/12 , C09D11/02 , C09D201/00 , C09K9/02 , C09D11/00
CPC分类号： C09B5/62 , C07D221/18
摘要： Rylene dyes of the general formula I where R is hydrogen; unsubstituted or substituted C1-C30-alkyl, aryl or hetaryl; R′ is unsubstituted or substituted C2-C30-alkyl or C5-C8-cycloalkyl, or substituted methyl; n is 0 or 1, their preparation and use for coloring high-molecular-weight organic and inorganic materials, and aminorylene-3,4-dicarboximide of the formula IV as their intermediates.
摘要翻译：通式I的Rylene染料，其中R是氢; 未取代或取代的C 1 -C 30 - 烷基，芳基或杂芳基; R'是未取代的或取代的C 2 -C 30 - 烷基或C 5 -C 8 - 环烷基，或取代的甲基; n为0或1，它们用于着色高分子量有机和无机材料以及式Ⅳ的氨基亚砜-3,4-二甲酰亚胺作为其中间体。

4. 发明授权

US06878825B2 Rylene derivatives and their use as dyes 失效
标题翻译：二烯衍生物及其作为染料的用途
公开(公告)号：US06878825B2
公开(公告)日：2005-04-12
申请号：US10468601
申请日：2002-02-14
申请人： Matthias Krieger , Arno Böhm , Erik Reuther , Klaus Müllen
发明人： Matthias Krieger , Arno Böhm , Erik Reuther , Klaus Müllen
IPC分类号： A61K8/49 , C07D221/18 , C07D491/06 , C09B5/62 , C09B3/14
CPC分类号： C07D491/06 , C07D221/18 , C07D471/06 , C09B5/62
摘要： Rylene derivatives of the general formula I where the variables have the following meanings: R is hydrogen or substituted or unsubstituted C1-C30-alkyl, aryl or hetaryl; R1 is hydrogen or bromine; R2 is hydrogen or C1-C6-alkyl; R3 is hydrogen, C1-C18-alkyl or substituted or unsubstituted aryl or hetaryl; and n is 2 or 3.
摘要翻译： R 1为氢或取代或未取代的C 1 -C 30 - 烷基，芳基或杂芳基; R 1为氢或溴; R 2为氢或C 1 -C 6 - 烷基; R 3是氢，C 1 -C 18烷基或取代或未取代的芳基或杂芳基; andn是2或3。

5. 发明授权

US06486319B1 Thermochromic rylene dyes 失效
标题翻译：热变色二甲苯染料
公开(公告)号：US06486319B1
公开(公告)日：2002-11-26
申请号：US10069563
申请日：2002-02-27
申请人： Arno Böhm , Heinrich Schmeisser , Stefan Becker , Klaus Müllen
发明人： Arno Böhm , Heinrich Schmeisser , Stefan Becker , Klaus Müllen
IPC分类号： C09B562
CPC分类号： C09B5/62
摘要： The invention relates to rylene dyes of the general formula (I), wherein the variables have the following meanings: R represents hydrogen; optionally substituted C1-C30 alkyl-C5-C8-cycloalkyl, aryl or hetaryl; R′ represents optionally substituted C2-C30 alkyl or C5-C8 cycloalkyl, substituted methyl; and n is 0 or 1. The invention also relates to the preparation and use of said dyes for coloring highly molecular organic and inorganic materials and to 9-amino-perylene-3,4-dicarboxylic acid imides (Va) as their intermediate products.
摘要翻译：本发明涉及通式（I）的二烯染料，其中变量具有以下含义：R表示氢; 任选取代的C 1 -C 30烷基-C 5 -C 8 - 环烷基，芳基或杂芳基; R'表示任选取代的C 2 -C 30烷基或C 5 -C 8环烷基，取代的甲基; 本发明还涉及用于着色高分子有机和无机材料的所述染料的制备和用途以及作为其中间产物的9-氨基 - 苝-3,4-二羧酸酰亚胺（Va）的制备和用途。

6. 发明授权

US06533857B1 Gloss pigments comprising an absorbent low-refractive coating 失效
$Gloss pigments comprising an absorbent low-refractive coating$
标题翻译：包含吸收性低折射涂层的光泽颜料
公开(公告)号：US06533857B1
公开(公告)日：2003-03-18
申请号：US10069666
申请日：2002-02-28
申请人： Raimund Schmid , Arno Böhm , Oliver Seeger , Norbert Mronga , Thorsten Clemens
发明人： Raimund Schmid , Arno Böhm , Oliver Seeger , Norbert Mronga , Thorsten Clemens
IPC分类号： C09C162
CPC分类号： C09C1/003 , A61K8/0266 , A61K2800/412 , A61K2800/436 , A61K2800/63 , A61K2800/651 , A61Q1/02 , C01P2004/20 , C01P2004/84 , C03C1/04 , C08K9/02 , C09C1/0015 , C09C1/0036 , C09C2200/1054 , C09C2200/1058 , C09C2200/24 , C09C2200/303 , C09C2200/507 , C09C2220/106 , C09D5/36 , C09D11/037
摘要： Luster pigments based on multiply coated reflecting platelet-shaped substrates and comprising at least one layer packet comprising A) a low refractive coating which selectively absorbs visible light and B) a reflective coating which is at least partially transparent to visible light and also, if desired, C) an outer protective layer.
摘要翻译：基于多层涂覆的反射片状基底的光泽颜料并且包括至少一个层包，包括：A）选择性吸收可见光的低折射涂层和B）对可见光至少部分透明的反射涂层，以及如果需要，C ）外保护层。

7. 发明申请

US20120138125A1 FLUORESCENT SOLAR CONVERSION CELLS BASED ON FLUORESCENT TERYLENE DYES 审中-公开
标题翻译：基于荧光染料的荧光太阳能转换细胞
公开(公告)号：US20120138125A1
公开(公告)日：2012-06-07
申请号：US13187976
申请日：2011-07-21
申请人： Markus HAMMERMANN , Martin Könemann , Alfred Rennig , Axel Grimm , Arno Böhm , Peter Erk
发明人： Markus HAMMERMANN , Martin Könemann , Alfred Rennig , Axel Grimm , Arno Böhm , Peter Erk
IPC分类号： H01L31/055
CPC分类号： C09K11/06 , C09B5/62 , C09K2211/1011 , C09K2211/1029 , C09K2211/1044 , C09K2211/1088 , H01L31/055 , Y02E10/52
摘要： A fluorescence conversion solar cell based on one or more panels composed of polymer doped with at least one fluorescent dye and/or glass panels coated with the doped polymer and photovoltaic cells mounted on the edges of the panels, which comprise one or more fluorescent dyes based on terrylenecarboxylic acid derivatives or a combination of these fluorescent dyes with further fluorescent dyes.
摘要翻译：一种荧光转换太阳能电池，其基于由掺杂有至少一种荧光染料的聚合物组成的一个或多个面板，和/或涂覆有掺杂聚合物的玻璃面板和安装在面板边缘上的光伏电池，其包含一种或多种基于荧光染料的荧光染料对这些荧光染料与其他荧光染料的组合。

8. 发明授权

US06326494B1 1,7-Diaroxy- or 1,7-arylthio-substituted perylene-3,4,9,10-tetracarboxylic acids, their dianhydrides and diimides 有权
标题翻译： 1,7-二氧基 - 或1,7-芳硫基取代的二萘嵌苯-3,4,9,10-四羧酸，它们的二酐和二酰亚胺
公开(公告)号：US06326494B1
公开(公告)日：2001-12-04
申请号：US09631291
申请日：2000-08-02
申请人： Arno Böhm , Harald Arms , Georg Henning , Peter Blaschka
发明人： Arno Böhm , Harald Arms , Georg Henning , Peter Blaschka
IPC分类号： C07D31473
CPC分类号： C07D493/06 , C07C65/15 , C07C65/24 , C09B5/024 , C09B5/62 , C09K11/06
摘要： A 1,7-disubstituted perylene-3,4,9,10-tetracarboxylic diimide of the general formula VI: Compositions or products comprising the compound of formula VI. Compositions comprising 1,7-diaroxy- or 1,7-diarylthio-substituted perylene-3,4,9,10-tetracarboxylic dianhydrides (I) or 1,7-diaroxy- or 1,7-diarylthio-substituted perylene-3,4,9,10-tetracarboxylic acids (Ia).
摘要翻译：通式VI的1,7-二取代的二萘嵌苯-3,4,9,10-四羧酸二酰亚胺：包含式VI化合物的组合物或产物。包含1,7-二芳氧基或1,7-二芳基硫代取代的二萘嵌苯-3,4,9,10-四羧酸二酐（I）或1,7-二芳氧基或1,7-二芳硫基取代的二萘嵌苯-3的组合物， 4,9,10-四羧酸（Ia）。

9. 发明授权

US06184378B2 1,7-disubstituted perylene-3,4,9,10-tetracarboxylic acids, their dianhydrides and diimides 有权
标题翻译： 1,7-二取代的苝-3,4,9,10-四羧酸，它们的二酸酐和二酰亚胺
公开(公告)号：US06184378B2
公开(公告)日：2001-02-06
申请号：US09404534
申请日：1999-09-24
申请人： Arno Böhm , Harald Arms , Georg Henning , Peter Blaschka
发明人： Arno Böhm , Harald Arms , Georg Henning , Peter Blaschka
IPC分类号： C07D47106
CPC分类号： C07D493/06 , C07C65/15 , C07C65/19 , C09B5/024 , C09B5/62 , C09D7/41 , C09D11/037 , C09K11/06
摘要： A 1,7-disubstituted perylene-3,4,9,10-tetracarboxylic diimide of the general formula VI where X1 and X1 re independently bromine or —L—R, where L is 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene and R is hydrogen or C1-C30-alkyl whose carbon chain can be interrupted by one or more groups —O—, —S—, —NR3—, —CO— and/or —SO2— and/or which can be substituted one or more times by —COOR3, —SO3R3, hydroxyl, cyano, C1-C6-alkoxy, C5-C8-cycloalkyl or aryl or by a 5- to 7-membered heterocyclic radical which is attached via a nitrogen atom and can include further heteroatoms and/or can be aromatic, R3 being hydrogen or C1-C6-alkyl.
摘要翻译：通式VI的1,7-二取代的二萘嵌苯-3,4,9,10-四羧酸二酰亚胺X 1和X 1独立地为溴或-LR，其中L为1,2-亚乙基，1,2-亚乙烯基或1,2-亚乙基，亚乙炔基，R是氢或C 1 -C 30 - 烷基，其碳链可被一个或多个-O - ， - S - ， - NR 3 - ， - CO-和/或-SO 2 - 基团间隔，和/或可被一个或更多次通过-COOR 3，-SO 3 R 3，羟基，氰基，C 1 -C 6 - 烷氧基，C 5 -C 8 - 环烷基或芳基或通过氮原子连接的5-至7-元杂环基，并且可以包括另外的杂原子和/或可以是芳族的，R 3是氢或C 1 -C 6 - 烷基。

10. 发明申请

US20100218321A1 METHOD FOR CONVERTING PERYLEN-3,4:9,10-TETRACARBOXYLIC ACID DIIMIDES INTO A FORM SUITABLE FOR USE AS A FLUORESCENT DYE 审中-公开
标题翻译：将季戊四烯-3,4：9,10-四羧酸二异氰酸酯转化为适用于荧光染料的形式的方法
公开(公告)号：US20100218321A1
公开(公告)日：2010-09-02
申请号：US12718512
申请日：2010-03-05
申请人： Peter Erk , Simone Schäfer , Arno Böhm , Peter Blaschka , Harald Arms , Willi Helfer
发明人： Peter Erk , Simone Schäfer , Arno Böhm , Peter Blaschka , Harald Arms , Willi Helfer
IPC分类号： C09B5/00 , D06P5/00
CPC分类号： C09B67/0014 , C09B67/0025
摘要： Novel crystalline forms of and a process for converting perylene-3, 4:9, 10-tetracarboximide of the general formula I to a form used as a fluorescent dye. The process including: a) dissolving or suspending the perylene-3, 4:9, 10-tetracarboximide in a solvent to obtain a solution or suspension; and b1) cooling the solution obtained in step a) to a temperature at or below the crystallization temperature of the perylene-3, 4:9, 10-tetracarboximide and, if the solvent is organic, removing excess solvent until the first crystals form, otherwise, adding water or dilute aqueous solutions of the solvent until the first crystals form, and maintaining the solution at that temperature for further crystallization; or b2) cooling the suspension obtained in step a) to or below the crystallization temperature when the temperature in step a) was above the crystallization temperature, and maintaining the suspension at the temperature for further crystallization to form one or more solvate crystals.
摘要翻译：将通式I的苝-3,4：9,10-四甲酰亚胺转化成用作荧光染料的形式的新型结晶形式和方法。该方法包括：a）将苝-3,4：9,10-四甲酰亚胺溶解或悬浮在溶剂中以获得溶液或悬浮液; 和b1）将步骤a）中获得的溶液冷却至等于或低于苝-3,4:9,10-四甲酰亚胺的结晶温度的温度，如果溶剂是有机的，则除去多余的溶剂直到形成第一晶体，否则，加入水或稀释的溶剂水溶液直到形成第一晶体，并将溶液保持在该温度下进一步结晶; 或b2）当步骤a）中的温度高于结晶温度时，将步骤a）中获得的悬浮液冷却至或低于结晶温度，并将悬浮液保持在该温度下进一步结晶以形成一种或多种溶剂化物晶体。

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