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    • 7. 发明授权
    • Distillation of ionic liquids
    • 蒸馏离子液体
    • US08382962B2
    • 2013-02-26
    • US12675445
    • 2008-08-15
    • Klemens MassonneMichael SiemerWerner MormannWei Leng
    • Klemens MassonneMichael SiemerWerner MormannWei Leng
    • B01D3/00
    • C07C51/44C07B63/00C07D233/54C07C53/122C07C53/10
    • A method of distilling mixtures of salts having a melting point of less than 200° C. at 1 bar (ionic liquids). The cation of the ionic liquid has a heterocyclic ring system having at least one nitrogen atom, and all nitrogen atoms of the heterocyclic ring system have an organic group as substituent. The anion of the ionic liquid is a compound having at least one carboxylate group or at least one phosphate group. The distance from the surface via which the heat of distillation is introduced in the distillation (vaporizer surface) to the surface at which condensation takes place (condenser surface) is less than 50 cm at at least one point, with the vaporizer surface and condenser surface themselves having at least one length dimension of greater than 50 cm.
    • 在1巴(离子液体)下蒸馏出熔点小于200℃的盐的混合物的方法。 离子液体的阳离子具有至少具有一个氮原子的杂环系统,并且杂环系统的所有氮原子都具有有机基团作为取代基。 离子液体的阴离子是具有至少一个羧酸酯基团或至少一个磷酸酯基团的化合物。 在蒸馏(蒸发器表面)中引入蒸馏热的表面到发生冷凝的表面(冷凝器表面)的表面的距离在至少一点处小于50cm,蒸发器表面和冷凝器表面 它们具有至少一个长度尺寸大于50cm的自身。
    • 10. 发明申请
    • FLAME RETARDANTS
    • 阻燃剂
    • US20110196052A1
    • 2011-08-11
    • US13022045
    • 2011-02-07
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • C08K5/5398C08L25/06C08J9/18C08J9/12
    • C08J9/0038C08J9/16C08J2325/04C08K5/5398C08L25/06
    • Phosphine sulfide derivatives of the formula (I), S═PR1R2R3  (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.
    • 式(I)的硫化膦衍生物,S = PR1R2R3(I)适用作阻燃剂,特别是用于聚合物的阻燃剂,其中式(I)中符号的定义如下:R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基,C 2 -C 12 - 烯基,C 2 -C 12炔基,C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H,SH,SR4,OH,OR5或 - (Y1)n- [P(= X1)R6-(Y2)n] m-P(= X2)R7R8组; 或两个基团R 1,R 2,R 3与键合的磷原子一起形成环系; X1和X2相同或不同,为O或S; Y1和Y2相同或不同,为O或S; R 4,R 5,R 6,R 7和R 8相同或不同,彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基 ,C 2 -C 12 - 烯基,C 2 -C 12 - 炔基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0,则n为1,如果Y1分别为Y2,并且分别为1,2,3,4,5,6,7或8,并且m分别为0至100的整数。 。