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1. 发明授权

US5939595A Preparation of diarylethanes 失效
标题翻译：二月桂烷的制备
公开(公告)号：US5939595A
公开(公告)日：1999-08-17
申请号：US639833
申请日：1996-04-26
申请人： Eugen Gehrer , Klemens Massonne , Hermann Gausepohl , Martin Fischer , Christopher William Rieker , Lorenz Siggel
发明人： Eugen Gehrer , Klemens Massonne , Hermann Gausepohl , Martin Fischer , Christopher William Rieker , Lorenz Siggel
IPC分类号： B01J29/18 , B01J29/70 , C07B61/00 , C07C2/66 , C07C15/16 , C07C15/12 , C07C2/08 , C07C2/12
CPC分类号： C07C2/66 , C07C2529/18 , C07C2529/70
摘要： A process for preparing diarylethanes of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, by reacting aromatic compounds of the general formula II ##STR2## where R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the abovementioned meanings, with styrenes of the general formula III ##STR3## where R.sup.1 has the abovementioned meanings, at from -20 to 300.degree. C. under from 1 to 100 bar in the presence of heterogeneous catalysts, wherein beta-zeolites or mordenites are used as heterogeneous catalysts.
摘要翻译：制备通式Ⅰ的二芳基乙烷的方法，其中R 1，R 2，R 3，R 4，R 5和R 6各自是氢或C 1 -C 8烷基，通过使通式II的芳族化合物，其中R2，R3，R4，R5和 R6具有上述含义，具有通式III的苯乙烯，其中R 1具有上述含义，在-20至300℃下，在非均相催化剂存在下，在1-100巴下使用β-沸石或丝光沸石作为多相催化剂。

2. 发明授权

US06680416B1 Supported catalyst containing pseudo-boehmite and &ggr;-Al2O3, production of same and its use for producing 1,2-dichloroethane 失效
标题翻译：含有假勃姆石和γ-Al2O3的负载催化剂，生产方法及其用于生产1,2-二氯乙烷
公开(公告)号：US06680416B1
公开(公告)日：2004-01-20
申请号：US09646003
申请日：2000-09-11
申请人： Werner Hebgen , Christopher William Rieker , Ruprecht Meissner
发明人： Werner Hebgen , Christopher William Rieker , Ruprecht Meissner
IPC分类号： C07C1900
CPC分类号： B01J27/122 , C07C17/156 , C07C19/045
摘要： A process for preparing 1,2-dichloroethane by reacting about 2 mols of ethylene, about 4 mols of hydrogen chloride and about 1 mol of oxygen in the presence of a fixed bed of supported catalyst based on copper(II) chloride in only one reaction zone at a pressure of from 2 to 10 bar and at from 220 to 280° C., separating off 1,2-dichloroethane and water from the reaction mixture emerging from the reaction zone and passing most of the exhaust gas back into the reaction zone, where, prior to entry into the reaction zone, the exhaust gas is mixed with ethylene, hydrogen chloride and oxygen, and the oxygen content of the mixture does not exceed 7% by volume, and where the ethylene content of the gas mixture entering into the reaction zone is regulated so that the exhaust gas comprises less than 20% by volume of ethylene, where the supported catalyst used is obtained by tableting a mixture of pseudoboehmite and &ggr;-Al2O3 in a weight ratio from 4:1 to 1:4, if desired with addition of tableting auxiliaries, loading this support with the active components by saturating with a CuCl2/KCl solution so that the copper content is from 1 to 15% by weight and the potassium content is from 0.1 to 8% by weight, based in each case on the total weight of the catalyst, and then drying the catalyst at from 60 to 400° C.
摘要翻译：在仅一次反应的基于氯化铜（II）的固定床的负载型催化剂存在下，使约2摩尔乙烯，约4摩尔氯化氢和约1摩尔氧气反应制备1,2-二氯乙烷的方法在2至10巴的压力和220至280℃的压力范围内，从反应区中排出的反应混合物中分离出1,2-二氯乙烷和水，并将大部分废气送回反应区，其中在进入反应区之前，将废气与乙烯，氯化氢和氧气混合，并且混合物的氧含量不超过7体积％，并且其中气体混合物的乙烯含量进入对反应区进行调节，以使废气中的乙烯的含量少于20体积％，其中使用的负载催化剂是通过将重量比为4:1至1:4的假勃姆石和γ-Al2O3的混合物压片而得到的，如果需要添加表丁基辅助剂，用CuCl 2 / KCl溶液饱和将活性组分负载该载体，使铜含量为1〜15重量％，钾含量为0.1〜8重量％，基于催化剂的总重量，然后在60-400℃干燥催化剂。

3. 发明授权

US5689005A Reductive deoxygenation using a redox catalyst 失效
标题翻译：使用氧化还原催化剂还原脱氧
公开(公告)号：US5689005A
公开(公告)日：1997-11-18
申请号：US563627
申请日：1995-11-28
申请人： Alfred Hagemeyer , Christopher William Rieker , Thomas Lautensack , Dieter Hermeling
发明人： Alfred Hagemeyer , Christopher William Rieker , Thomas Lautensack , Dieter Hermeling
IPC分类号： B01J23/92 , B01J38/04 , B01J38/08 , B01J38/10 , C07B31/00 , C07B43/04 , C07B47/00 , C07B61/00 , C07C209/36 , C07F9/50
CPC分类号： C07C209/36 , C07B31/00 , C07F9/509 , Y02P20/584
摘要： A process for the deoxygenation of organic oxo compounds, in particular phosphine oxides to phosphines and nitrobenzene to aniline, with reduced redox catalysts in a non-steady-state reaction with decoupled reductive regeneration of the redox catalyst entails the redox catalyst being reduced to a lower oxidation state and being reused for the deoxygenation.
摘要翻译：有机氧化合物，特别是氧化膦，膦和硝基苯与苯胺脱氧的方法，在氧化还原催化剂的解耦还原再生的非稳态反应中还原的氧化还原催化剂需要将氧化还原催化剂还原为较低氧化态，并被再次用于脱氧。

4. 发明授权

US6028027A Method of producing selective-dehydrogenation catalysts, and catalysts produced in this way 失效
标题翻译：制备选择性脱氢催化剂的方法和以这种方式制备的催化剂
公开(公告)号：US6028027A
公开(公告)日：2000-02-22
申请号：US29643
申请日：1998-03-17
申请人： Michael Baier , Christopher William Rieker , Otto Hofstadt , Wolfgang Buchele , Wolfgang Jurgen Popel , Hermann Petersen , Norbert Neth
发明人： Michael Baier , Christopher William Rieker , Otto Hofstadt , Wolfgang Buchele , Wolfgang Jurgen Popel , Hermann Petersen , Norbert Neth
IPC分类号： B01J23/78 , B01J23/80 , B01J23/84 , B01J23/85 , B01J37/00 , C07C5/333 , C07C15/46 , B01J23/00 , B01J23/58 , C07C2/00 , C07C15/00
CPC分类号： B01J37/0009 , B01J23/78 , C07C5/3332
摘要： Catalysts comprising iron and potassium and, if desired, further elements, which catalysts are suitable for dehydrogenating hydrocarbons to give the corresponding olefinically unsaturated hydrocarbons, are prepared by calcining a finely divided dry or aqueous mixture of an iron compound with a potassium compound and, if desired, compounds of further elements in a first step that agglomerates having a diameter of from 5 to 50 .mu.m and formed from smaller individual particles are obtained and, in a second step, preferably after shaping, calcining it at from 300 to 1000.degree. C., with the maximum calcination temperature in the second step preferably being at least 30.degree. below the calcination temperature in the first step. The catalysts thus prepared are useful, in particular, for dehydrogenating ethylbenzene to give styrene.
摘要翻译： PCT No.PCT / EP96 / 04028 Sec。 371日期：1998年3月17日 102（e）1998年3月17日PCT PCT 1996年9月13日PCT公布。公开号WO97 / 10898 日期1997年3月27日包含铁和钾以及如果需要的其它元素的催化剂是通过将细碎的干燥或含水混合物与铁化合物的焙烧而制备的，该催化剂适用于使烃脱氢得到相应的烯属不饱和烃钾化合物，并且如果需要，获得在第一步骤中的另外的元素的化合物，其具有直径为5至50μm并且由较小的单个颗粒形成的附聚物，并且在第二步中，优选在成型之后，从其煅烧 300〜1000℃，第二步骤中的最高煅烧温度优选在第一步骤的煅烧温度以下至少30℃。因此制备的催化剂特别适用于使乙苯脱氢得到苯乙烯。

5. 发明授权

US07056356B2 Process for producing crystals 失效
标题翻译：晶体生产工艺
公开(公告)号：US07056356B2
公开(公告)日：2006-06-06
申请号：US10296442
申请日：2001-05-21
申请人： Peter Mark Allen , Christoph Gahn , Christopher William Rieker , Heinz-Walter Schneider , Robert Wagner
发明人： Peter Mark Allen , Christoph Gahn , Christopher William Rieker , Heinz-Walter Schneider , Robert Wagner
IPC分类号： B01D9/00
CPC分类号： B01D9/0022 , B01D9/0031 , B01D9/0036 , B01D9/0059
摘要： An apparatus and a process for crystallizing substances from solutions or dispersions containing these substances, in a crystallizer containing a classifying zone (3), comprise a) an inner and an outer circulation system (1; 2), the inner circulation system (1) being present in the crystallizer, the inlet of the outer circulation system (2) being connected to the inner circulation system (1) via the classifying zone (3), the outer circulation system, being present outside the crystallizer, the outlet of the outer circulation system (2) being connected to the inner circulation system (1) of the crystallizer, and a means for dissolving crystals being arranged in the outer circulation system (2), before its outlet, b) an inflow (4) for solution and/or dispersion, which inflow is present on the crystallizer or on the outer circulation system, and c) an outflow (5) for dispersions, which outflow is arranged on the crystallizer or on the outer circulation system. The novel apparatus has the special feature that a line (8) connecting the outer and inner circulation systems (1; 2) to one another and intended for transporting (recycling) dispersion and/or a line (8) for transporting (recycling) dispersion are additionally present, in which both its entrance and its exit are connected to the inner circulation system (1).
摘要翻译：一种用于在含有分级区（3）的结晶器中使含有这些物质的溶液或分散液中的物质结晶的装置和方法包括：a）内循环系统（1; 2），内循环系统（1）存在于结晶器中，外循环系统（2）的入口经由分级区（3）连接到内循环系统（1），外循环系统存在于结晶器外部，外部出口循环系统（2）连接到结晶器的内循环系统（1），以及用于溶解布置在外循环系统（2）中的晶体在其出口之前的装置，b）用于溶液的流入物（4） /或分散体，其流入存在于结晶器或外循环系统上，以及c）用于分散体的流出物（5），该流出物布置在结晶器或外循环系统上。该新型装置的特征在于，将外部和内部循环系统（1; 2）彼此连接并用于运输（再循环）分散体和/或用于运输（再循环）分散体的管线（8）的管线（8）另外存在，其入口和出口都连接到内循环系统（1）。

6. 发明授权

US06305833B1 Production of solids by precipitation 失效
标题翻译：通过沉淀生产固体
公开(公告)号：US06305833B1
公开(公告)日：2001-10-23
申请号：US09143405
申请日：1998-08-28
申请人： Hans Christoph Horn , Otto Kumberger , Marco Millies , Norbert Neth , Wolfgang Jürgen Pöpel , Christopher William Rieker , Michael Jolyon Sprague , Manfred Stroezel
发明人： Hans Christoph Horn , Otto Kumberger , Marco Millies , Norbert Neth , Wolfgang Jürgen Pöpel , Christopher William Rieker , Michael Jolyon Sprague , Manfred Stroezel
IPC分类号： B01F1502
CPC分类号： C01G1/00 , B01D9/005 , B01D9/0054 , B01F5/106
摘要： A process for producing solids by precipitation in a mixer to form a mixture of solid and liquid, where the starting materials are fed into a mixing apparatus which has essentially a rotationally symmetrical mixing chamber which has a rotor disposed therein and is formed by a peripheral wall and two end walls, and where a) the starting materials are each fed to at least one inlet opening in the peripheral wall of the mixing chamber, and b) the solid-containing mixture which is formed is removed from at least one outlet opening in the peripheral wall of the mixing chamber.
摘要翻译：一种通过在混合器中沉淀以形成固体和液体的混合物来生产固体的方法，其中将原料进料到基本上具有旋转对称的混合室的混合装置中，该混合室具有设置在其中的转子，并且由周壁和两个端壁，并且其中原料各自被供给到混合室的周壁中的至少一个入口开口，和b）形成的固体混合物从外围的至少一个出口开口去除混合室的墙壁。

7. 发明授权

US6087538A Addition reaction of hydroxyl-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6087538A
公开(公告)日：2000-07-11
申请号：US92059
申请日：1998-06-05
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
IPC分类号： B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C07C67/04 , C07C69/145 , C07C69/16 , C07C43/30 , B01J21/08 , C07C2/02
CPC分类号： B01J37/0203 , B01J23/06 , C07C41/06 , C07C41/08 , C07C41/54
摘要： Compounds of the formula I and II ##STR1## where R.sup.1 is hydrogen or an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical or an acyl radical, it being possible for these radicals to carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals which may be linked to one another with formation of a ring and m is 0 or 1, are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used contains, as an active component, an X-ray amorphous zinc silicate or cadmium silicate containing from 1 to 40% by weight, calculated as oxide, of zinc or cadmium and is obtainable by applying a zinc salt or cadmium salt of an organic acidic compound which is decomposable at below 400.degree. C., to an amorphous silica and forming the catalyst at from 50 to 500.degree. C., in the presence of a hydroxyl-containing compound selected from the group consisting of water, alkanols with up to 10 carbon atoms, diols and polyols having 2 to 6 carbon atoms and 2 or 3 OH groups and carboxylic acids of 1 to 6 carbon atoms.
摘要翻译：式I和II的化合物，其中R 1是氢或脂族，脂环族，芳脂族，芳族或杂环基或酰基，这些基团可能携带另外不与炔或炔反应的取代基和基团 R 2彼此独立地是氢或脂族，脂环族，芳脂族，芳族或杂环基团，其可以通过形成环而彼此连接并且m为0或1，其通过将化合物式IIIR1OHIII具有式IV或V的乙炔或二烯，其中R1和R具有上述含义，在气相中，在非均相含硅酸盐催化剂存在下，在升高的温度下，通过所用催化剂包含的方法，作为活性成分，含有以氧化物计为1〜40重量％的锌或镉的X射线无定形硅酸锌或铯硅酸盐，可通过应用在低于400℃下可分解的有机酸性化合物的锌锌盐或镉盐加入到无定形二氧化硅中，并在50-500℃下，在含羟基化合物存在下，在选自具有至多10个碳原子的链烷醇，具有2至6个碳原子的二醇和多元醇以及2或3个OH基团以及1至6个碳原子的羧酸组成的组。

8. 发明授权

US5698715A Preparation of unsaturated cyclic ethers 失效
标题翻译：不饱和环醚的制备
公开(公告)号：US5698715A
公开(公告)日：1997-12-16
申请号：US695630
申请日：1996-08-12
申请人： Jurgen Schroeder , Thomas Fetzer , Christopher William Rieker , Klaus Ebel
发明人： Jurgen Schroeder , Thomas Fetzer , Christopher William Rieker , Klaus Ebel
IPC分类号： C07D317/12 , B01J23/889 , B01J23/89 , C07B61/00 , C07D305/10 , C07D307/28 , C07D309/18 , C07D313/04 , C07D319/12 , C07D321/00 , C07D321/08 , C07D321/12
CPC分类号： C07D307/28 , B01J23/889 , B01J23/8913 , B01J23/8946 , C07D309/18 , C07D319/12
摘要： A process for the preparation of unsaturated cyclic ethers of the general formula I ##STR1## in which Z denotes --(CHR.sup.4).sub.q or --(CHR.sup.4).sub.q --O-- q is 0, 1, 2 or 3 and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 denote hydrogen or C.sub.1 -C.sub.4 alkyl from diols of the general formula II ##STR2## in which, R.sup.1, R.sup.2, and R.sup.3 have the aforementioned meanings, in the presence of a cobalt-containing supported catalyst, wherein the cobalt-containing supported catalyst used contains cobalt and a noble metal--selected from the group consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium, or mixtures thereof--in an atomic ratio of from 0.5:1 to 70000:1 on an inert support and optionally basic alkali metal and alkaline earth metal salts, scandium, vanadium, chromium, manganese, iron, nickel, copper, zinc, germanium, tin, lead, antimony, bismuth, or mixtures thereof and the reaction is carried out in the liquid phase at temperatures ranging from 150.degree. to 300.degree. C., and also novel cobalt-containing supported catalysts, prepared, in particular, by sol impregnation.
摘要翻译：其中Z表示 - （CHR4）q或 - （CHR4）qOq的通式I（I）的不饱和环醚的制备方法为0,1,2或3，R1，R2，R3，并且R 4表示在通式II（II）的二醇中的氢或C 1 -C 4烷基，其中R 1，R 2和R 3具有上述含义，在含钴担载催化剂存在下，其中钴的载体催化剂包含钴和选自铂，钯，铑，铱，钌，锇，铼或其混合物的贵金属 - 原子比为0.5:1至70000:1，对惰性载体和任选碱性碱金属和碱土金属盐，钪，钒，铬，锰，铁，镍，铜，锌，锗，锡，铅，锑，铋或其混合物，并且反应在在150℃至300℃的温度范围内的液相，以及新颖的含钴载体水晶，特别是通过溶胶浸渍制备。

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