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1. 发明授权

US5424145A High capacity rechargeable cell having manganese dioxide electrode 失效
标题翻译：具有二氧化锰电极的大容量可再充电电池
公开(公告)号：US5424145A
公开(公告)日：1995-06-13
申请号：US207629
申请日：1994-03-09
申请人： Klaus Tomantschger , R. James Book , Josef Daniel-Ivad
发明人： Klaus Tomantschger , R. James Book , Josef Daniel-Ivad
IPC分类号： H01M2/16 , H01M4/42 , H01M4/50 , H01M4/62 , H01M10/05 , H01M10/24 , H01M10/26 , H01M10/36 , H01M10/52
CPC分类号： H01M2/1686 , H01M10/05 , H01M10/24 , H01M10/26 , H01M10/36 , H01M4/62 , H01M4/622 , H01M4/623 , H01M4/628 , H01M10/523 , H01M2/1653 , H01M4/42 , H01M4/50 , H01M4/621 , H01M4/625
摘要： A rechargeable manganese dioxide/zinc cell is provided, where the cell has high capacity, high volumetric and gravimetric energy densities, high cycle life, and is capable of continued charge-discharge cycles following an overdischarge. The cell has an aqueous electrolyte, with the usual solute of potassium hydroxide, but the solute may also be a mixture of zinc chloride and ammonium chloride. The electrode balance as determined by the ration of the theoretical discharge capacity of the zinc and the theoretical one electron discharge capacity of the manganese dioxide ranges from greater than 65% up to 110%. On the 15th discharge, a cell of the present invention will deliver a discharge capacity of at least 20% of the discharge capacity delivered on the first discharge. A cell according to the present invention is capable of continued charge-discharge cycles after overdischarge or voltage reversal.
摘要翻译：提供了可充电的二氧化锰/锌电池，其中电池具有高容量，高体积和重量能量密度，高循环寿命，并且能够在过放电之后继续充电 - 放电循环。电池具有通常的氢氧化钾溶质的电解质，但是溶质也可以是氯化锌和氯化铵的混合物。通过锌的理论放电容量和二氧化锰的理论电子放电容量的比例确定的电极平衡范围从大于65％到高达110％。在第15次放电时，本发明的电池将提供至少在第一次放电时输送的放电容量的20％的放电容量。根据本发明的电池能够在过放电或电压反转之后继续充电 - 放电循环。

2. 发明授权

US5626988A Sealed rechargeable cells containing mercury-free zinc anodes, and a method of manufacture 失效
标题翻译：含有无汞锌阳极的密封可充电电池及其制造方法
公开(公告)号：US5626988A
公开(公告)日：1997-05-06
申请号：US239059
申请日：1994-05-06
申请人： Josef Daniel-Ivad , R. James Book , Klaus Tomantschger
发明人： Josef Daniel-Ivad , R. James Book , Klaus Tomantschger
IPC分类号： H01M4/42 , H01M4/50 , H01M4/62 , H01M10/24 , H01M10/34 , H01M10/52
CPC分类号： H01M4/62 , H01M10/24 , H01M10/345 , H01M10/52 , H01M4/42 , H01M4/50
摘要： The zinc active powder for a mercury-free rechargeable electrochemical cell is coated with a surfactant, and separately with an aqueous solution of indium sulphate. Without any subsequent filtering, washing or drying, the powder is assembled into an electrochemical cell. The cell can include a hydrogen recombination catalyst in contact with the electrochemically active material of the cathode.
摘要翻译：用于无汞可充电电化学电池的锌活性粉末涂覆有表面活性剂，并分别与硫酸铟水溶液一起涂覆。没有任何后续的过滤，洗涤或干燥，将粉末组装成电化学电池。电池可以包括与阴极的电化学活性材料接触的氢复合催化剂。

3. 发明授权

US08906515B2 Metal-clad polymer article 有权
标题翻译：金属包覆聚合物制品
公开(公告)号：US08906515B2
公开(公告)日：2014-12-09
申请号：US12785524
申请日：2010-05-24
申请人： Klaus Tomantschger , Jonathan McCrea , Nandakumar Nagarajan , Francisco Gonzalez , Gino Palumbo , Konstantinos Panagiotopoulos , Herath Katugaha , Diana Facchini , Jared J. Victor , Uwe Erb
发明人： Klaus Tomantschger , Jonathan McCrea , Nandakumar Nagarajan , Francisco Gonzalez , Gino Palumbo , Konstantinos Panagiotopoulos , Herath Katugaha , Diana Facchini , Jared J. Victor , Uwe Erb
IPC分类号： B32B1/08 , B32B3/30 , B32B15/08 , C25D5/56 , B05D3/00 , C23C16/02 , C25D5/54 , C23C14/02 , C23C18/18
CPC分类号： C23C18/1641 , A63B59/70 , A63B2102/24 , B32B1/08 , B32B3/30 , B32B7/02 , B32B15/08 , B32B15/18 , B32B15/20 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/281 , B32B27/285 , B32B27/288 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/38 , B32B27/40 , B32B27/42 , B32B2255/06 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2262/101 , B32B2262/106 , B32B2264/02 , B32B2264/10 , B32B2264/12 , B32B2270/00 , B32B2307/202 , B32B2307/212 , B32B2307/30 , B32B2307/51 , B32B2307/538 , B32B2307/54 , B32B2307/718 , B32B2457/00 , B32B2509/00 , B32B2535/00 , B32B2597/00 , B32B2605/00 , C09J163/00 , C23C14/021 , C23C14/024 , C23C14/028 , C23C16/0227 , C23C16/0254 , C23C16/0272 , C23C18/1851 , C23C18/1855 , C23C18/1893 , C23C18/1896 , C25D5/54 , Y10T428/12111 , Y10T428/12389 , Y10T428/12451 , Y10T428/12472 , Y10T428/12569 , Y10T428/12944 , Y10T428/1355 , Y10T428/24355 , Y10T428/24545 , Y10T428/24612 , Y10T428/26 , Y10T428/269
摘要： Metal-clad polymer articles containing structural fine-grained and/or amorphous metallic coatings/layers optionally containing solid particulates dispersed therein, are disclosed. The fine-grained and/or amorphous metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, automotive parts and components exposed to thermal cycling although the coefficient of linear thermal expansion (CLTE) of the metallic layer and the substrate are mismatched. The interface between the metallic layer and the polymer is suitably pretreated to withstand thermal cycling without failure.
摘要翻译：公开了包含分散在其中的任选地含有固体颗粒的结构细晶粒和/或非晶金属涂层/层的金属包层聚合物制品。细晶粒和/或非晶金属涂层特别适用于强而轻的制品，精密模具，运动用品，暴露于热循环的汽车部件和部件，尽管金属层和基材的线性热膨胀系数（CLTE）不匹配。金属层和聚合物之间的界面适当地经过预处理以承受热循环而不失败。

4. 发明申请

US20130112563A1 FLOW-THROUGH CONSUMABLE ANODES 有权
标题翻译：流通消耗阳极
公开(公告)号：US20130112563A1
公开(公告)日：2013-05-09
申请号：US13289470
申请日：2011-11-04
申请人： Klaus Tomantschger , Diana Facchini , Francisco Gonzalez , Jonathan McCrea , John Kratochwil , Dan Woloshyn , Yusuf Bismilla , Nandakumar Nagarajan , Mioara Neacsu
发明人： Klaus Tomantschger , Diana Facchini , Francisco Gonzalez , Jonathan McCrea , John Kratochwil , Dan Woloshyn , Yusuf Bismilla , Nandakumar Nagarajan , Mioara Neacsu
IPC分类号： C25D17/10 , C25D21/18
CPC分类号： C25D5/06 , C25D1/00 , C25D5/08 , C25D5/18 , C25D17/14
摘要： Anode applicators include consumable anodes, that can be operated in a non-stationary mode and are insensitive to orientation, are used in selective plating/brush electrodeposition of coatings or free-standing components. The flow-through dimensionally-stable, consumable anodes employed are perforated/porous to provide relatively unimpeded electrolyte flow and operate at low enough electrochemical potentials to provide for anodic metal/alloy dissolution avoiding undesired anodic reactions. The consumable anodes include consumable anode material(s) in high surface area to reduce the local anodic current density. During electroplating, sufficient electrolyte is pumped through the consumable anodes at sufficient flow rates to minimize concentration gradient and/or avoid the generation of chlorine and/or oxygen gas and/or undesired reaction such as the anodic oxidation of P-bearing ions in the electrolyte. The active consumable anode material(s) can have a microstructure which is fine-grained and/or amorphous to ensure a uniform anodic dissolution.
摘要翻译：阳极施加器包括可以以非固定模式操作且对取向不敏感的消耗性阳极用于涂层或独立部件的选择性电镀/刷电沉积。使用的流通尺寸稳定的消耗性阳极是穿孔/多孔的，以提供相对无阻碍的电解质流动并且在足够低的电化学电势下操作以提供阳极金属/合金溶解以避免不期望的阳极反应。消耗性阳极包括高表面积的消耗性阳极材料，以减少局部阳极电流密度。在电镀过程中，足够的电解液以足够的流速被泵入消耗性阳极以最小化浓度梯度和/或避免产生氯和/或氧气和/或不期望的反应，例如电解质中含P离子的阳极氧化。活性消耗性阳极材料可以具有细晶粒和/或无定形的微结构，以确保均匀的阳极溶解。

5. 发明申请

US20120202116A1 Composite Current Collector for Aqueous Electrochemical Cell for aqueous electrochemical cell 有权
标题翻译：用于水电化学电池的水电化学电池的复合集电极
公开(公告)号：US20120202116A1
公开(公告)日：2012-08-09
申请号：US13451586
申请日：2012-04-20
申请人： Klaus Tomantschger
发明人： Klaus Tomantschger
IPC分类号： H01M4/64 , H01M4/66 , H01M4/70
CPC分类号： H01M4/667 , H01M4/14 , H01M4/244 , H01M4/661 , H01M4/662 , H01M4/72 , H01M4/74 , H01M4/742 , H01M4/765 , H01M4/78 , H01M4/808 , H01M6/06 , H01M10/06 , H01M10/24 , H01M2200/103
摘要： Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-fee and lead-free alkaline zinc electrodes.
摘要翻译：包含金属，合金或化合物的复合集流体，其选自Zn，Cd，Hg，Ga，In，Tl，Sn，Pb，As，Sb，Bi和Se，非金属，不导电或不良导电基底。复合集电器可用于电化学电池，特别是需要长存储寿命的密封电池。选择的金属，金属合金或金属化合物通过真空沉积技术，挤出，导电涂料（分散为合适涂料中的颗粒），无电沉积，胶结剂等应用于聚合物或陶瓷基材; 或通过电化学方法（电沉积或电泳）合适的金属化之后。金属化合物涂层通过化学或电流方法还原成各自的金属。所描述的集电器特别适用于含有汞和无铅碱性锌电极的密封初级或可充电电池。

6. 发明申请

US20110223470A1 Composite Current Collector for Electrochemical Cell 有权
标题翻译：电化学电池用复合集电极
公开(公告)号：US20110223470A1
公开(公告)日：2011-09-15
申请号：US13099390
申请日：2011-05-03
申请人： Klaus Tomantschger
发明人： Klaus Tomantschger
IPC分类号： H01M4/66 , H01M4/56 , H01M4/42 , H01M4/50 , H01M4/52 , H01M2/02 , H01M10/08
CPC分类号： H01M4/667 , H01M4/14 , H01M4/244 , H01M4/661 , H01M4/662 , H01M4/72 , H01M4/74 , H01M4/742 , H01M4/765 , H01M4/78 , H01M4/808 , H01M6/06 , H01M10/06 , H01M10/24 , H01M2200/103
摘要： Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-free and lead-free alkaline zinc electrodes.
摘要翻译：包含金属，合金或化合物的复合集流体，其选自Zn，Cd，Hg，Ga，In，Tl，Sn，Pb，As，Sb，Bi和Se，非金属，不导电或不良导电基底。复合集电器可用于电化学电池，特别是需要长存储寿命的密封电池。选择的金属，金属合金或金属化合物通过真空沉积技术，挤出，导电涂料（分散为合适涂料中的颗粒），无电沉积，胶结剂等应用于聚合物或陶瓷基材; 或通过电化学方法（电沉积或电泳）合适的金属化之后。金属化合物涂层通过化学或电流方法还原成各自的金属。所描述的集电器特别适用于含有无汞和无铅碱性锌电极的密封初级或可充电电池。

7. 发明申请

US20100304172A1 ELECTRODEPOSITED METALLIC-MATERIALS COMPRISING COBALT 失效
标题翻译：包含钴的电沉积金属材料
公开(公告)号：US20100304172A1
公开(公告)日：2010-12-02
申请号：US12476424
申请日：2009-06-02
申请人： Diana Facchini , Francisco Gonzalez , Jonathan McCrea , Mike Uetz , Gino Palumbo , Klaus Tomantschger
发明人： Diana Facchini , Francisco Gonzalez , Jonathan McCrea , Mike Uetz , Gino Palumbo , Klaus Tomantschger
IPC分类号： B32B15/02 , C25D5/02 , C25D5/00
CPC分类号： C25D3/562 , C25D3/12 , C25D3/26 , C25D5/18 , C25D5/50 , C25D15/00 , Y10T428/12049 , Y10T428/12493 , Y10T428/12861 , Y10T428/12937 , Y10T428/12993 , Y10T428/13 , Y10T428/24942 , Y10T428/24967 , Y10T428/26 , Y10T428/263 , Y10T428/264 , Y10T428/265
摘要： Free standing articles or articles at least partially coated with substantially porosity free, fine-grained and/or amorphous Co-bearing metallic materials optionally containing solid particulates dispersed therein, are disclosed. The electrodeposited metallic layers and/or patches comprising Co provide, enhance or restore strength, wear and/or lubricity of substrates without reducing the fatigue performance. The fine-grained and/or amorphous metallic coatings comprising Co are particularly suited for articles exposed to thermal cycling, fatigue and other stresses and/or in applications requiring anti-microbial properties.
摘要翻译：公开了至少部分地涂覆有基本上无孔隙的细颗粒和/或无定形的含Co金属材料的任选地含有分散在其中的固体颗粒的独立制品或制品。包含Co的电沉积金属层和/或贴剂提供，增强或恢复基底的强度，磨损和/或润滑性，而不降低疲劳性能。包含Co的细粒和/或无定形金属涂层特别适用于暴露于热循环，疲劳和其它应力和/或需要抗微生物性能的应用中的制品。

8. 发明授权

US07803072B2 Strong, lightweight article, containing a fine-grained metallic layer 有权
标题翻译：坚固，轻便的物品，含有细粒金属层
公开(公告)号：US07803072B2
公开(公告)日：2010-09-28
申请号：US12536821
申请日：2009-08-06
申请人： Gino Palumbo , Iain Brooks , Konstantinos Panagiotopoulos , Klaus Tomantschger , Jonathan McCrea , Dave Limoges , Uwe Erb
发明人： Gino Palumbo , Iain Brooks , Konstantinos Panagiotopoulos , Klaus Tomantschger , Jonathan McCrea , Dave Limoges , Uwe Erb
IPC分类号： A63B59/06
CPC分类号： C25D15/00 , A01K87/00 , A45B9/00 , A63B49/02 , A63B49/10 , A63B53/04 , A63B53/0466 , A63B53/10 , A63B53/12 , A63B59/00 , A63B59/50 , A63B59/70 , A63B60/54 , A63B2053/0416 , A63B2209/00 , A63B2209/023 , B82Y30/00 , C25D1/00 , C25D7/00 , Y02P20/582 , Y10T428/12028 , Y10T428/12493 , Y10T428/12708 , Y10T428/12778 , Y10T428/13 , Y10T428/24405 , Y10T428/24413 , Y10T428/26 , Y10T428/265 , Y10T428/31678
摘要： Articles for automotive, manufacturing and industrial applications including shafts or tubes used, for example, as golf club shafts, ski and hiking poles, fishing rods or bicycle frames, skate blades and snowboards are at least partially electroplated with fine-grained layers of selected metallic materials. Parts with complex geometry can be coated as well. Alternatively, articles such as conical or cylindrical golf club shafts, hiking pole shafts or fishing pole sections, plates or foils and the like can also be electroformed of fine-grained metallic materials on a suitable mandrel or temporary substrate to produce strong, ductile, lightweight components exhibiting a high coefficient of restitution and a high stiffness for use in numerous applications including sporting goods.
摘要翻译：用于汽车，制造和工业应用的制品，包括例如用作高尔夫球棒杆，滑雪和徒步杆，钓鱼竿或自行车车架，滑冰板和滑雪板的轴或管，至少部分地电镀有选定金属的细粒层材料具有复杂几何形状的部件也可以被涂覆。或者，诸如锥形或圆柱形高尔夫球杆杆，徒步杆杆或钓鱼杆部分，板或箔等的物品也可以在合适的心轴或临时基底上电铸成细粒度的金属材料，以产生强的，延性的，轻质的表现出高恢复系数和高刚度的组件用于包括运动用品在内的许多应用中。

9. 发明授权

US07771289B2 Sports articles formed using nanostructured materials 有权
标题翻译：使用纳米结构材料形成的运动用品
公开(公告)号：US07771289B2
公开(公告)日：2010-08-10
申请号：US11305842
申请日：2005-12-16
申请人： Gino Palumbo , William F. Davidson, III , Jonathan McCrea , Klaus Tomantschger , Iain Brooks , Dave Limoges , Konstantinos Panagiotopoulos , Uwe Erb
发明人： Gino Palumbo , William F. Davidson, III , Jonathan McCrea , Klaus Tomantschger , Iain Brooks , Dave Limoges , Konstantinos Panagiotopoulos , Uwe Erb
IPC分类号： A63B53/04
CPC分类号： C25D15/00 , A01K87/00 , A45B9/00 , A63B49/02 , A63B49/10 , A63B53/04 , A63B53/0466 , A63B53/10 , A63B53/12 , A63B59/00 , A63B59/50 , A63B59/70 , A63B60/54 , A63B2053/0416 , A63B2209/00 , A63B2209/023 , B82Y30/00 , C25D1/00 , C25D7/00 , Y02P20/582 , Y10T428/12028 , Y10T428/12493 , Y10T428/12708 , Y10T428/12778 , Y10T428/13 , Y10T428/24405 , Y10T428/24413 , Y10T428/26 , Y10T428/265 , Y10T428/31678
摘要： A sports article includes a portion that includes a nanostructured material. The nanostructured material includes a metal, and the nanostructured material has an average grain size that is in the range of 2 nm to 5,000 nm, a yield strength that is in the range of 200 MPa to 2,750 MPa, and a hardness that is in the range of 100 Vickers to 2,000 Vickers. The sports article can be any of a variety of sports equipment and associated components, such as a golf club, a baseball bat, a softball bat, a lacrosse stick, or a hockey stick.
摘要翻译：运动制品包括包括纳米结构材料的部分。纳米结构材料包括金属，纳米结构材料的平均粒径在2nm〜5000nm的范围内，屈服强度在200MPa〜2750MPa的范围内，硬度在范围为100维氏至2,000维氏。体育用品可以是各种运动器材和相关组件中的任何一种，例如高尔夫球杆，棒球棒，垒球棒，长曲棍棒棒棍或曲棍球棒。

10. 发明申请

US20080254310A1 Article comprising a fine-Grained metallic material and a polymeric material 审中-公开
标题翻译：包含细粒金属材料和聚合材料的制品
公开(公告)号：US20080254310A1
公开(公告)日：2008-10-16
申请号：US12155868
申请日：2008-06-11
申请人： Gino Palumbo , Jonathan McCrea , Klaus Tomantschger , Iain Brooks , Daehyun Jeong , Dave Limoges , Konstantinos Panagiotopoulos , Uwe Erb , Andrew Wang
发明人： Gino Palumbo , Jonathan McCrea , Klaus Tomantschger , Iain Brooks , Daehyun Jeong , Dave Limoges , Konstantinos Panagiotopoulos , Uwe Erb , Andrew Wang
IPC分类号： B32B15/04 , B22F7/02 , B32B1/08
CPC分类号： C25D7/00 , A01K87/00 , A45B9/00 , A63B49/02 , A63B49/10 , A63B49/12 , A63B53/04 , A63B53/0466 , A63B53/047 , A63B53/10 , A63B53/12 , A63B59/00 , A63B59/50 , A63B60/54 , A63B2053/0416 , A63B2209/00 , A63B2209/023 , B82Y30/00 , C23C26/00 , C25D5/00 , C25D15/02 , F42B5/30 , Y02T50/6765 , Y10T428/12049 , Y10T428/12201 , Y10T428/12569 , Y10T428/1321 , Y10T428/24612 , Y10T428/249941 , Y10T428/31507 , Y10T428/31511 , Y10T428/31681 , Y10T428/31685 , Y10T428/31692
摘要： Lightweight articles comprising a polymeric material at least partially coated with a fine-grained metallic material are disclosed. The fine-grained metallic material has an average grain size of 2 nm to 5,000 nm, a thickness between 25 micron and 5 cm, and a hardness between 200 VHN and 3,000 VHN. The lightweight articles are strong and ductile and exhibit high coefficients of restitution and a high stiffness and are particularly suitable for a variety of applications including aerospace and automotive parts, sporting goods, and the like.
摘要翻译：公开了包含至少部分涂覆有细粒金属材料的聚合材料的轻质制品。细晶金属材料的平均粒径为2nm〜5000nm，厚度为25μm〜5cm，硬度为200HHN〜3000HVN。轻型制品是坚固的和延展性的并且表现出高的恢复系数和高刚度，并且特别适用于各种应用，包括航空航天和汽车零件，运动用品等。

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