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1. 发明授权

US06541423B1 4-(3′,4′-heterocyclyl benzoyl) pyrazoles as herbicidal agents 失效
标题翻译： 4-（3'，4'-杂环基苯甲酰基）吡唑作为除草剂
公开(公告)号：US06541423B1
公开(公告)日：2003-04-01
申请号：US09959636
申请日：2001-11-01
申请人： Guido Mayer , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Michael Rack , Thorsten Volk , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Guido Mayer , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Michael Rack , Thorsten Volk , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： C07D41706
CPC分类号： C07D403/06 , A01N43/74 , C07D413/06 , C07D417/06
摘要： The invention relates to pyrazolyl derivatives of benzo-condensated, unsaturated 5-membered nitrogen heterocycles of the general formula (I), wherein X represents N or a group C—R3; Y is O, S, SO, SO2 or NR4 or X—Y is S═N, and wherein X means sulfur, and the variables R1, R2 and Pz have the meanings indicated in claim 1. The invention, further relates to a method of producing said compounds, to agents that contain them and to their use as herbicidal agents.
摘要翻译：本发明涉及通式（I）的苯并缩合的不饱和5元氮杂环的吡唑基衍生物，其中X代表N或C-R3基团; Y是O，S，SO，SO 2或NR 4或XY是S = N，并且其中X表示硫，并且变量R1，R2和Pz具有权利要求1中所示的含义。本发明还涉及一种生产所述化合物，含有它们的试剂并用作除草剂。

2. 发明授权

US06908884B2 Benzazolonylcarbonylcyclohexenones and their use as herbicides 失效
标题翻译：苯并唑烷基羰基环己烯酮及其作为除草剂的用途
公开(公告)号：US06908884B2
公开(公告)日：2005-06-21
申请号：US10433013
申请日：2001-12-10
申请人： Guido Mayer , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Michael Hofmann , Thorsten Volk , Matthias Witschel , Cyrill Zagar , Andreas Landes , Klaus Langemann
发明人： Guido Mayer , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Michael Hofmann , Thorsten Volk , Matthias Witschel , Cyrill Zagar , Andreas Landes , Klaus Langemann
IPC分类号： A01N43/74 , A01N43/76 , A01N43/78 , C07D263/58 , C07D277/68 , C07D417/06 , C07D521/00 , C07D261/18 , C07D271/00
CPC分类号： C07D263/58 , A01N43/74 , C07D231/12 , C07D233/56 , C07D249/08 , C07D277/68 , C07D417/06
摘要： Cyclohexenone derivatives of benzazolones of the formula I where the variables R1, R2, R3, A and Hex are as defined in claim 1, and their salts, and their use for controlling harmful plants, are described.
摘要翻译：其中变量R 1，R 2，R 3，A和Hex的式I的苯并唑酮的环己烯酮衍生物如权利要求1中所定义，及其盐，及其用于控制有害植物的用途。

3. 发明授权

US06613717B1 Phosphoric benzoyl derivatives and their use as herbicides 失效
标题翻译：磷酰苯甲酰衍生物及其作为除草剂的用途
公开(公告)号：US06613717B1
公开(公告)日：2003-09-02
申请号：US09959510
申请日：2001-10-29
申请人： Klaus Langemann , Thorsten Volk , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Klaus Langemann , Thorsten Volk , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N5726
CPC分类号： C07F9/65685 , A01N57/22 , A01N57/24 , C07F9/4021 , C07F9/4025 , C07F9/4419 , C07F9/5325 , C07F9/5329 , C07F9/572 , C07F9/65031 , C07F9/653 , C07F9/657181 , C07F9/65785
摘要： Phosphorus-containing benzoyl derivatives of the formula I where: P(═X)R1R2X is an organic phosphorus radical; R3 is hydrogen, nitro, cyano, halogen, unsub. or sub. alkyl, alkylcarbonyl, alkoxycarbonyl, unsub. or sub. alkoxy, unsub. or sub. alkylthio, unsub. or sub. alkylsulfinyl, unsub. or sub. alkylsulfonyl, unsub. or sub. aminosulfonyl, unsub. or sub. amino, P(═X)R1R2, unsub. or sub. phenyl or unsub. or sub. heterocyclyl; R4 is nitro, cyano, halogen, alkyl, alkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; l is 0, 1 or 2; Q is unsub. or sub. 1-hydroxy-3-oxocyclohex-1-en-2-yl, unsub. or sub. 5-hydroxypyrazol-4-yl, unsub. or sub. isoxazol-4-yl or unsub. or sub. 2-cyano-1-oxoeth-2-yl; and their agriculturally useful salts; processes and intermediates for preparing the phosphorus-containing benzoyl derivatives; compositions comprising them and the use of these derivatives or the compositions comprising them for controlling undesirable plants are described.
摘要翻译：含有式I的苯甲酰基衍生物其中：P（= X）R 1 R 2 X是有机磷基; R 3是氢，硝基，氰基，卤素，未取代的。或子。烷基，烷基羰基，烷氧基羰基，未取代的。或子。烷氧基或子。烷硫基或子。烷基亚磺酰基或子。烷基磺酰基或子氨基磺酰基或子。氨基，P（= X）R 1 R 2，未取代。或子。苯基或未取代的。或子。杂环基; R 4是硝基，氰基，卤素，烷基，烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; l是0,1或2; Q是未取代的。或子。 1-羟基-3-氧代环己-1-烯-2-基，或子。 5-羟基吡唑-4-基，或子。异恶唑-4-基或未取代的。或子。 2-氰基-1-氧代乙基-2-基;及其农业上可用的盐;制备含磷苯甲酰基衍生物的方法和中间体; 描述了包含它们的组合物以及这些衍生物或包含它们的组合物用于防治不期望的植物的用途。

4. 发明授权

US06589915B1 Benzohetero cyclylcyclo hexenones and their use as herbicides 失效
标题翻译：苯并环基环己烯酮及其作为除草剂的用途
公开(公告)号：US06589915B1
公开(公告)日：2003-07-08
申请号：US09959801
申请日：2001-11-07
申请人： Guido Mayer , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Michael Rack , Thorsten Volk , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Guido Mayer , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Michael Rack , Thorsten Volk , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4378
CPC分类号： C07D263/56 , A01N43/74 , C07D249/18 , C07D263/58 , C07D277/62 , C07D277/64 , C07D277/66 , C07D277/68 , C07D277/74 , C07D285/14
摘要： The invention relates to cyclohexenone derivatives of benzo-condensed, unsaturated 5-ring nitrogen heterocycles of general formula (I) wherein X represents N or a group C—R3, Y represents O, S, SO, SO2 or NR4 or X—Y represent S═N and X represents sulfur, and the variables R1, R2 and Hex have the meanings given in claim 1. The invention also relates to a method for producing these compounds, to agents containing these compounds, and to their use as herbicides.
摘要翻译：本发明涉及通式（I）的苯并稠合的不饱和5-环氮杂环的环己烯酮衍生物，其中X表示N或C-R 3，Y表示O，S，SO，SO 2或NR 4或XY表示S = N和X表示硫，并且变量R1，R2和Hex具有权利要求1中给出的含义。本发明还涉及制备这些化合物的方法，含有这些化合物的试剂及其作为除草剂的用途。

5. 发明授权

US06815563B2 Method for producing bicyclic 1,3-diketones 失效
标题翻译：双环1,3-二酮的制备方法
公开(公告)号：US06815563B2
公开(公告)日：2004-11-09
申请号：US10332034
申请日：2003-01-06
申请人： Klaus Langemann , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Thorsten Volk , Guido Mayer
发明人： Klaus Langemann , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Thorsten Volk , Guido Mayer
IPC分类号： A01N4358
CPC分类号： C07C255/47 , C07C17/00 , C07C45/27 , C07C45/29 , C07C45/298 , C07C45/673 , C07C49/433 , C07C2602/44 , C07C23/30 , C07C49/693
摘要： A process for preparing bicyclic 1,3-diketones of the formula I where R1, R2, R3 and R4 are hydrogen, C1-C4-alkyl, C1-C4-alkoxy-carbonyl, halogen, cyano, nitro, C1-C4-alkylthio, C1-C4-alkylsulfenyl or C1-C4-alkylsulfonyl and Z is C1-C4-alkylene, O, S, N—R5 where R5 is C1-C4-alkyl or C1-C4-alkylcarbonyl, which comprises a) reacting a bicyclic olefin of the formula II with haloform in the presence of a base to give the ring-expanded product of the formula III where R1-R4 and Z are as defined above and X is halogen; b) hydrolyzing the allylic halogen of the compound of the formula III to the allyl alcohol of the formula IV c) oxidizing the allyl alcohol of the formula IV to the unsaturated ketone of the formula V d) reacting the ketone of the formula V with a nucleophilic ion Y− which stabilizes a negative charge to give the ketone of the formula VI e) hydrolyzing the ketone of the formula VI to the bicyclic 1,3-diketone of the formula I, novel intermediates and novel processes for preparing these intermediates are described.
摘要翻译：制备式I其中R 1，R 2，R 3和R 4的双环1,3-二酮的方法是氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基 - 羰基，卤素氰基，硝基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基硫基或C 1 -C 4 - 烷基磺酰基，Z是C 1 -C 4 - 亚烷基，O，S，NR 5，其中R 5是C 1 -C 4烷基或C 1 -C4 - 烷基羰基，其包括a）在碱存在下使式II的双环烯烃与卤代甲基反应，得到式III的环扩展产物，其中R 1 -R 4和Z如上所定义，X和X 将式III的化合物的烯丙基卤水解成式IVc的烯丙醇，将式Ⅳ的烯丙醇氧化为式ⅤⅤ的不饱和酮）使式Ⅴ的酮与使负电荷稳定以得到式VIe的酮）将式VI的酮水解成式I的双环1,3-二酮的新型中间体和新方法描述这些中间体。

6. 发明授权

US06599860B1 Herbicidal halogenalkyl-substituted 3-(4,5-dihydroisoxazol-3-yl)-benzoyl-cyclohexenones 失效
标题翻译：除草卤代烷基取代的3-（4,5-二氢异恶唑-3-基） - 苯甲酰基 - 环己烯酮
公开(公告)号：US06599860B1
公开(公告)日：2003-07-29
申请号：US10130308
申请日：2002-05-16
申请人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
发明人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4380
CPC分类号： C07D261/04 , A01N43/80
摘要： Herbicidally active haloalkyl-substituted 3-(4,5-dihydroisoxazol-3-yl)benzoylcyclohexenones of the formula I in which R1 to R3 and R5 to R14 are as defined in the description and R4 is C1-C4-haloalkyl are described.
摘要翻译：描述了R1至R3和R5至R14定义的式Iin的除草活性卤代烷基取代的3-（4,5-二氢异恶唑-3-基）苯甲酰基环己烯酮，其中R 4为C 1 -C 4 - 卤代烷基。

7. 发明授权

US06583089B1 Tricyclic benzoylcyclohexanedione derivatives 失效
标题翻译：三环苯甲酰基环己二酮衍生物
公开(公告)号：US06583089B1
公开(公告)日：2003-06-24
申请号：US09979991
申请日：2001-11-29
申请人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4390
CPC分类号： C07D495/04
摘要： Tricyclic benzoylcyclohexanedione derivatives of the formula I where X, Y, R1, R2, R3, R4, R5, R9, and m are defined herein, and their agriculturally useful salts. Process for preparing the tricyclic benzoylcyclohexanedione derivatives; compositions comprising them and the use of these derivatives or of the compositions comprising them for controlling undesirable plants are described.
摘要翻译：其中X，Y，R 1，R 2，R 3，R 4，R 5，R 9和m的式I的三环苯甲酰基环己二酮衍生物在本文中定义，以及它们的农业上有用的盐。三环苯甲酰环己二酮衍生物的制备方法; 描述了包含它们的组合物以及这些衍生物或包含它们的组合物用于防治不期望的植物的用途。

8. 发明授权

US06475957B1 N-cycloalkyl-3-alkenybenzoyl-pyrazole derivatives 失效
标题翻译： N-环烷基-3-烯基苯甲酰基 - 吡唑衍生物
公开(公告)号：US06475957B1
公开(公告)日：2002-11-05
申请号：US10019047
申请日：2001-12-27
申请人： Ulf Neidlein , Norbert Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Roland Götz , Klaus Langemann , Guido Mayer , Ulf Misslitz , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Ulf Neidlein , Norbert Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Roland Götz , Klaus Langemann , Guido Mayer , Ulf Misslitz , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4356
CPC分类号： A01N43/56 , C07D231/20
摘要： Cycloalkyl-substituted benzoylpyrazoles of the formula I where the variables have, for example, the following meanings: R1 is hydrogen, nitro, halogen, cyano, thiocyanato, or an unsubstituted or substituted aliphatic radical; R2 is an unsubstituted or substituted aliphatic radical, halogen, nitro, or substituted sulfonyl or amino groups, R3 is hydrogen, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkynyl; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, an unsubstituted or substituted aliphatic radical or substituted sulfonyl or amino groups; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7 is a cyclic ring system having 3-14 ring atoms; R16 is hydroxyl or a substituted hydroxyl group; and their tautomers or agriculturally useful salts are described. Moreover, the invention describes processes for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and of the compositions comprising them for controlling harmful plants.
摘要翻译：式I的环烷基取代的苯甲酰基吡唑，其中变量具有例如以下含义：R 1是氢，硝基，卤素，氰基，氰硫基或未取代或取代的脂族基; R 2是未取代或取代的脂族基，卤素，硝基或取代的磺酰基或氨基，R 3是氢，卤素，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; R 4，R 5是氢硝基，卤素，氰基，氰硫基，未取代或取代的脂族基团或取代的磺酰基或氨基; R 6是氢，卤素，C 1 -C 6烷基，C 1 -C 6 - 烷氧基，C 3 -C 8环烷基; 具有3-14个环原子的环系; R 16是羟基或取代的羟基;并且描述了它们的互变异构体或农业上有用的盐。此外，本发明描述了制备式I化合物的方法，包含它们的组合物，以及使用式I化合物和组合物的化合物包括它们用于控制有害植物。

9. 发明申请

US20070197393A1 TRICYCLIC BENZOYLPYRAZOLE DERIVATIVES 审中-公开
标题翻译：三苯甲酰基吡唑衍生物
公开(公告)号：US20070197393A1
公开(公告)日：2007-08-23
申请号：US11461491
申请日：2006-08-01
申请人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N43/02 , A01N43/08 , A01N43/16 , A01N43/18 , A01N43/58
CPC分类号： C07D413/06 , A01N43/80 , A01N43/90 , C07D491/04 , C07D495/04
摘要： Tricyclic benzoylpyrazole derivatives of the formula I where: X is oxygen, sulfur, S═O, S(═O)2, CR6R7, NR8 or a bond; Y together with the two carbons to which it is attached forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle; R1, R2, R6, R7 are hydrogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R3 is halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R4 is hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, unsubstituted or substituted aminosulfonyl or unsubstituted or substituted sulfonylamino; R5 is hydrogen, alkyl or halogen; l is 0, 1 or 2; R8 is hydrogen, alkyl, haloalkyl, alkylcarbonyl, formyl, alkoxycarbonyl, haloalkoxycarbonyl, alkylsulfonyl or haloalkylsulfonyl; R9 is substituted pyrazol-4-ylcarbonyl or substituted 5-oxopyrazolin-4-ylmethylidene; and their agriculturally useful salts; processes and intermediates for preparing the tricyclic benzoylpyrazole derivatives; compositions comprising them and the use of these derivatives or of the compositions comprising them for controlling undesirable plants are described.
摘要翻译：式I的三环苯甲酰基吡唑衍生物其中：X是氧，硫，SO，S（-O）2，CR 6，R 7， NR 8或键; Y与连接的两个碳一起形成饱和的，部分饱和的或不饱和的5-或6-元杂环; R 1，R 2，R 6，R 7是氢，烷基，卤代烷基，烷氧基或卤代烷氧基; R 3是卤素，烷基，卤代烷基，烷氧基或卤代烷氧基; R 4是氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基，卤代烷基磺酰基，未取代或取代的氨基磺酰基或未取代或取代的磺酰基氨基; R 5是氢，烷基或卤素; l为0,1或2; R 8是氢，烷基，卤代烷基，烷基羰基，甲酰基，烷氧基羰基，卤代烷氧基羰基，烷基磺酰基或卤代烷基磺酰基; R 9是取代的吡唑-4-基羰基或取代的5-氧代吡唑啉-4-基亚甲基; 及其农业用盐; 制备三环苯甲酰基吡唑衍生物的方法和中间体; 描述了包含它们的组合物以及这些衍生物或包含它们的组合物用于防治不期望的植物的用途。

10. 发明授权

US07115545B1 Tricyclic benzoylpyrazole derivatives used as a herbicide 失效
标题翻译：用作除草剂的三环苯甲酰基吡唑衍生物
公开(公告)号：US07115545B1
公开(公告)日：2006-10-03
申请号：US09936356
申请日：2000-03-08
申请人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Matthias Witschel , Steffen Kudis , Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N43/80 , A61K31/423 , C07D261/20
CPC分类号： C07D413/06 , A01N43/80 , A01N43/90 , C07D491/04 , C07D495/04
摘要： Tricyclic benzoylpyrazole derivatives of the formula I wherein X, Y, R1, R2, R6, R7, R3, R4, R5, l, R8 and R9 are as defined in the disclosure and their agriculturally useful salts; processes and intermediates for preparing the tricyclic benzoylpyrazole derivatives; compositions comprising them and the use of these derivatives or of the compositions comprising them for controlling undesirable plants are described.
摘要翻译：其中X，Y，R 1，R 2，R 6，R 7，O， R 3，R 4，R 5，R 8，R 9和R 9， / SUP>如本公开中所定义的及其农业上有用的盐; 制备三环苯甲酰基吡唑衍生物的方法和中间体; 描述了包含它们的组合物以及这些衍生物或包含它们的组合物用于防治不期望的植物的用途。

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