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    • 2. 发明授权
    • Process for producing meta-type wholly aromatic polyamide filaments
    • 制备间位型全芳族聚酰胺长丝的方法
    • US06569366B1
    • 2003-05-27
    • US09958900
    • 2001-10-15
    • Kiyotsuna ToyoharaJiro SadanobuTsutomu Nakamura
    • Kiyotsuna ToyoharaJiro SadanobuTsutomu Nakamura
    • D01D506
    • D01F6/605
    • A meta-type wholly aromatic polyamide containing, as principal repeating units, meta-phenylenediamineisophthalamide units is dissolved in an amide compound solvent; the resultant polymer solution is subjected to a wet-spinning procedure wherein the polymer solution is extruded in the form of filamentary streams into a coagulation bath containing an amide compound-containing solvent and water but substantially not containing salts, through spinning orifices of a spinneret, to coagulate the extruded filamentary polymer solution streams in the coagulation bath; the coagulated porous undrawn filaments are subjected to a drawing procedure wherein the porous undrawn filaments are drawn in a plasticizing drawing bath containing an aqueous solution of an amide compound solvent; the resultant drawn filaments are washed with water, and then heat-treated (for example, further drawn at a draw ratio of 0.7 to 4.0 while being heated at a temperature of 250 to 400° C.), to provide uniform and dense meta-type wholly aromatic polyamide fibers.
    • 将作为主要重复单元的间苯二甲酰胺间苯二酰胺单元的间位型全芳香族聚酰胺溶解在酰胺化合物溶剂中; 所得聚合物溶液经受湿纺丝程序,其中聚合物溶液以丝状流的形式挤出到含有含酰胺化合物的溶剂和水但基本上不含盐的凝固浴中,通过喷丝头的纺丝孔, 使凝固浴中挤出的丝状聚合物溶液流凝结; 对凝固的多孔未拉伸丝进行拉伸处理,其中将多孔未拉伸丝在含有酰胺化合物溶剂的水溶液的增塑拉伸浴中拉伸; 将得到的拉伸长丝用水洗涤,然后进行热处理(例如,在250〜400℃的温度下加热的同时以拉伸比为0.7〜4.0进一步拉伸),得到均匀且致密的间 - 型全芳族聚酰胺纤维。
    • 4. 发明授权
    • Elastic fiber, process for the same and polyester elastomer used thereof
    • 弹性纤维,与其相同的方法和使用的聚酯弹性体
    • US5853878A
    • 1998-12-29
    • US704539
    • 1996-09-12
    • Toyoaki IshiwataJiro Sadanobu
    • Toyoaki IshiwataJiro Sadanobu
    • C08G63/672D01F6/86C08G63/66C08F20/00C08G63/00C08G63/02
    • D01F6/86C08G63/672Y10T428/2913Y10T428/2969
    • The present invention relates to an elastic fiber of polyester elastomer mainly comprising the polyester elastomer further comprising aromatic polyester component as a hard segment and poly(alkyleneoxide)glycol having a number-average molecular weight of 500 to 5000 as a soft segment, wherein a residual elongation after 400 percent stretching does not exceed 100 percent. Made of the polyester elastomer comprising 1,2-bis�4-(2-hydroxyethyl)phenoxy!ethane as the diol component constituting said aromatic polyester component, or 1,4-benzenediethanol and ethyleneglycol as the diol component constituting said aromatic polyester component, the elastic fiber features excellent elastic properties in the event of great deformation and provides suitable material for clothing.
    • PCT No.PCT / JP96 / 00729 Sec。 371日期:1996年9月12日 102(e)1996年9月12日PCT PCT 1996年3月21日PCT公布。 WO96 / 30427PC PCT出版物 日期:1996年10月3日本发明涉及一种聚酯弹性体弹性纤维,主要由聚酯弹性体构成,该聚酯弹性体还包含作为硬链段的芳族聚酯组分和数均分子量为500〜5000的聚(环氧烷)二醇作为软质 其中400%拉伸后的残余伸长率不超过100%。 由构成所述芳香族聚酯成分的二醇成分的1,2-双[4-(2-羟乙基)苯氧基]乙烷或作为构成所述芳香族聚酯成分的二醇成分的1,4-苯二乙醇和乙二醇的聚酯弹性体构成, 弹性纤维在大变形的情况下具有优异的弹性,并为衣服提供合适的材料。