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1. 发明授权

US06657075B2 Continuous process for tertiary butyl esters 有权
公开(公告)号：US06657075B2
公开(公告)日：2003-12-02
申请号：US10108148
申请日：2002-03-27
申请人： Kevin Alan Williams , Steven Leroy Cook , Phillip Wayne Turner
发明人： Kevin Alan Williams , Steven Leroy Cook , Phillip Wayne Turner
IPC分类号： C07C6902
CPC分类号： C07C67/46 , C07C69/14
摘要： Disclosed is a continuous process for the production of tertiary butyl esters by the reaction of a ketene and tertiary butyl alcohol containing a finite concentration of water. The process may be carried out in an absorber reactor with continuous recovery and purification of products by distillation. This process provides high-purity tertiary butyl acetate without the production of unwanted by-products found in many strong acid catalyzed processes.

2. 发明授权

US06831115B2 UV-curable, non-chlorinated adhesion promoters 失效
公开(公告)号：US06831115B2
公开(公告)日：2004-12-14
申请号：US10068627
申请日：2002-02-06
申请人： Kevin Alan Williams , Michael Bellas , Charlie Carroll Freeman, Jr. , Lisa Kay Templeton
发明人： Kevin Alan Williams , Michael Bellas , Charlie Carroll Freeman, Jr. , Lisa Kay Templeton
IPC分类号： C08F246
CPC分类号： C08J7/04 , C08F8/14 , C08F290/042 , C08J2323/02 , C08L23/04 , C08L23/10 , C09D7/65 , Y10T428/31504 , Y10T428/31855 , C08F255/04
摘要： Modified polyolefins are produced by reacting a functionalized polyolefin with one or more ethylenically unsaturated compounds having a functional group reactive with the functional group on the polyolefin. These modified polyolefins may then polymerize in the presence of a photoinitiator upon exposure to ultraviolet radiation and also have the capability of copolymerizing in the presence of a photoinitiator with other ethylenically unsaturated crosslinking agents upon exposure to ultraviolet radiation. These modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines, and therefore may be rendered water-dispersible. The modified polyolefins of the present invention significantly improve the adhesion of paints, inks, and adhesives to various plastic and metal substrates.

3. 发明授权

US07388039B2 UV-curable, non-chlorinated adhesion promoters 失效
标题翻译：紫外光固化，非氯化粘合促进剂
公开(公告)号：US07388039B2
公开(公告)日：2008-06-17
申请号：US10890861
申请日：2004-07-14
申请人： Kevin Alan Williams , Michael Bellas , Charlie Carroll Freeman, Jr. , Lisa Kay Templeton
发明人： Kevin Alan Williams , Michael Bellas , Charlie Carroll Freeman, Jr. , Lisa Kay Templeton
IPC分类号： C08F2/50 , C08F255/04 , C08J3/24 , C08J3/03 , B32B27/32
CPC分类号： C08J7/04 , C08F8/14 , C08F290/042 , C08J2323/02 , C08L23/04 , C08L23/10 , C09D7/65 , Y10T428/31504 , Y10T428/31855 , C08F255/04
摘要： Modified polyolefins are produced by reacting a functionalized polyolefin with one or more ethylenically unsaturated compounds having a functional group reactive with the functional group on the polyolefin. These modified polyolefins may then polymerize in the presence of a photoinitiator upon exposure to ultraviolet radiation and also have the capability of copolymerizing in the presence of a photoinitiator with other ethylenically unsaturated crosslinking agents upon exposure to ultraviolet radiation. These modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines, and therefore may be rendered water-dispersible. The modified polyolefins of the present invention significantly improve the adhesion of paints, inks, and adhesives to various plastic and metal substrates.
摘要翻译：通过使官能化聚烯烃与具有与官能团反应的官能团的一种或多种烯键式不饱和化合物与聚烯烃反应来制备改性聚烯烃。然后这些改性的聚烯烃可以在光引发剂的存在下在暴露于紫外线辐射下聚合，并且还具有在光引发剂与其它烯属不饱和交联剂的存在下在暴露于紫外线辐射下进行共聚的能力。这些改性的聚烯烃也可以含有倾向于与胺形成亲水盐的倾向的羧基，因此可以使水分散。本发明的改性聚烯烃显着地改善了涂料，油墨和粘合剂对各种塑料和金属基材的粘合性。

4. 发明授权

US08058355B2 Modified chlorinated carboxylated polyolefins and their use as adhesion promoters 有权
标题翻译：改性氯化羧基聚烯烃及其用作粘合促进剂
公开(公告)号：US08058355B2
公开(公告)日：2011-11-15
申请号：US11218071
申请日：2005-08-31
申请人： Robert Lee Eagan , Kevin Alan Williams , Allen Morgan Cheek
发明人： Robert Lee Eagan , Kevin Alan Williams , Allen Morgan Cheek
IPC分类号： C08F8/20 , C08F8/14 , C09D151/06 , C09D123/28
CPC分类号： C09D175/04 , C08F8/44 , C08F2810/20 , C08K5/42 , C08L23/283 , C09D7/63 , C09D11/03 , C09D167/00 , C09D167/07 , C09D167/08 , Y10T428/31855 , C08L2666/06 , C08F8/22 , C08F285/00 , C08F8/14
摘要： The present invention provides solvent- and water-based primer compositions that include at least one chlorinated carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The chlorinated carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof then chlorinated. The chlorinated carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified chlorinated carboxylated polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified chlorinated carboxylated polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.
摘要翻译：本发明提供溶剂和水基底漆组合物，其包括至少一种已经用一种或多种多官能醇改性的氯化羧化聚烯烃。通过聚烯烃与不饱和羧酸酯，不饱和羧酸，不饱和羧酸酐，丙烯酸类单体及其混合物中的至少一种的反应得到氯化羧基化的聚烯烃，然后氯化。然后通过与一种或多种多官能醇反应来进一步修饰氯化羧化聚烯烃。这些多官能醇改性的氯化羧基化聚烯烃也可以含有侧链羧基，其倾向于与胺或无机碱形成亲水盐，从而使多官能醇改性的氯化羧化聚烯烃水分散。这些底漆组合物可用于显着改善涂料，粘合剂和油墨对各种塑料和金属基材的粘合性。

5. 发明授权

US08058354B2 Modified carboxylated polyolefins and their use as adhesion promoters 有权
标题翻译：改性羧化聚烯烃及其作为粘合促进剂的用途
公开(公告)号：US08058354B2
公开(公告)日：2011-11-15
申请号：US10610238
申请日：2003-06-30
申请人： Kevin Alan Williams , Robert Lee Eagan , Lisa Kay Templeton , Richard Leon McConnell
发明人： Kevin Alan Williams , Robert Lee Eagan , Lisa Kay Templeton , Richard Leon McConnell
IPC分类号： C08F8/14 , C08F8/32 , C08F8/46 , C08C19/22 , C08C19/28 , C08C19/36
CPC分类号： C08J7/047 , C08F8/14 , C08F255/00 , C08F255/02 , C08F290/042 , C08F2800/10 , C08F2810/20 , C08J2423/00 , C09D7/65 , C09D151/06 , C09J151/06 , Y10T428/31692 , Y10T428/31938 , C08F222/06 , C08F255/04
摘要： The present invention provides solvent- and water-based primer compositions that include at least one carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof. The carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.
摘要翻译：本发明提供了溶剂和水基底漆组合物，其包括至少一种已被一种或多种多官能醇改性的羧化聚烯烃。羧基化的聚烯烃是通过聚烯烃与不饱和羧酸酯，不饱和羧酸，不饱和羧酸酐，丙烯酸类单体及其混合物中的至少一种的反应得到的。然后通过与一种或多种多官能醇反应来进一步修饰羧化聚烯烃。这些多官能醇改性聚烯烃也可以含有侧链羧基，其倾向于与胺或无机碱形成亲水盐，从而使多官能醇改性的聚烯烃水分散。这些底漆组合物可用于显着改善涂料，粘合剂和油墨对各种塑料和金属基材的粘合性。

6. 发明申请

US20120040195A1 MODIFIED CARBOXYLATED POLYOLEFINS AND THEIR USE AS ADHESION PROMOTERS FOR POLYOLEFIN SURFACES 审中-公开
标题翻译：改性聚氧乙烯和它们作为粘合剂表面的粘合促进剂
公开(公告)号：US20120040195A1
公开(公告)日：2012-02-16
申请号：US13277504
申请日：2011-10-20
申请人： Kevin Alan Williams , Robert Lee Eagan , Lisa Kay Templeton , Richard Leon McConnell
发明人： Kevin Alan Williams , Robert Lee Eagan , Lisa Kay Templeton , Richard Leon McConnell
IPC分类号： B32B15/085 , C09D5/16 , B32B27/32 , C09D167/02
CPC分类号： C08J7/047 , C08F8/14 , C08F255/00 , C08F255/02 , C08F290/042 , C08F2800/10 , C08F2810/20 , C08J2423/00 , C09D7/65 , C09D151/06 , C09J151/06 , Y10T428/31692 , Y10T428/31938 , C08F222/06 , C08F255/04
摘要： The present invention provides solvent- and water-based primer compositions that include at least one carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof. The carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.
摘要翻译：本发明提供了溶剂和水基底漆组合物，其包括至少一种已被一种或多种多官能醇改性的羧化聚烯烃。羧基化的聚烯烃是通过聚烯烃与不饱和羧酸酯，不饱和羧酸，不饱和羧酸酐，丙烯酸类单体及其混合物中的至少一种的反应得到的。然后通过与一种或多种多官能醇反应来进一步修饰羧化聚烯烃。这些多官能醇改性聚烯烃也可以含有侧链羧基，其倾向于与胺或无机碱形成亲水盐，从而使多官能醇改性的聚烯烃水分散。这些底漆组合物可用于显着改善涂料，粘合剂和油墨对各种塑料和金属基材的粘合性。

7. 发明申请

US20110184321A1 HARD TO REACH FRACTURE APPLICATOR STRAP 审中-公开
标题翻译：很难达到断裂应用程序条
公开(公告)号：US20110184321A1
公开(公告)日：2011-07-28
申请号：US12918098
申请日：2009-02-27
申请人： Nicholas Scott Reback , Kevin Alan Williams , Craig Patrick Conner , Mark W. Cors , Jesse Charles Darley , Michael John Guse , Stephen Andrew Latham , Jason Splan
发明人： Nicholas Scott Reback , Kevin Alan Williams , Craig Patrick Conner , Mark W. Cors , Jesse Charles Darley , Michael John Guse , Stephen Andrew Latham , Jason Splan
IPC分类号： A61N7/00
CPC分类号： A61H23/0245 , A61F13/00025 , A61F13/00034 , A61F2013/00187 , A61F2013/00544 , A61F2013/00919 , A61H2201/165 , A61N7/00 , A61N2007/0013
摘要： There may be provided a hard-to-reach fracture applicator strap assembly (10). The assembly (10) includes a bottom portion (12); a stiffener (20) in contact with the bottom portion (12); a large pouch portion (16) in contact with the stiffener (20); a small pouch portion (18) in contact with the stiffener (20); and a top portion (14) in contact with at least one of the large pouch portion (16) and the small pouch portion (18).
摘要翻译：可以提供难以到达的骨折施放器带组件（10）。组件（10）包括底部（12）; 与底部部分（12）接触的加强件（20）; 与所述加强件（20）接触的大的袋部分（16）; 与所述加强件（20）接触的小袋部分（18）; 以及与大袋部分（16）和小袋部分（18）中的至少一个接触的顶部部分（14）。

8. 发明授权

US06310134B1 Adhesion-promoting primer compositions for polyolefin substrates 有权
标题翻译：用于聚烯烃基材的粘合促进底漆组合物
公开(公告)号：US06310134B1
公开(公告)日：2001-10-30
申请号：US09342181
申请日：1999-06-29
申请人： Lisa Kay Templeton , Kevin Alan Williams , Richard Leon McConnell , Michael Alan Callahan
发明人： Lisa Kay Templeton , Kevin Alan Williams , Richard Leon McConnell , Michael Alan Callahan
IPC分类号： C08F26704
CPC分类号： C09D151/06 , C08F8/00 , C08F10/00
摘要： The invention relates to solvent-based primer compositions containing 0.5 to 40 weight percent of a modified polyolefin and a solvent selected from the group consisting of ester solvents, ketone solvents, aliphatic solvents, aromatic solvents and mixtures thereof. The modified polyolefin is formed from an amorphous polyolefin selected from polypropylene and a propylene copolymer or a propylene terpolymer or an ethylene copolymer or terpolymer. Preferably the polyolefin is a polypropylene copolymer or terpolymer containing about 1 to about 99 mole percent ethylene, 1-butene, 1-pentene, and 1-hexene. The amorphous polyolefin has a number average molecular weight ranging from about 1,000 to 15,000 and is chemically modified with one or more unsaturated carboxylic acids selected from the group consisting of acids, esters and anhydrides. These primers are useful for significantly improving the adhesion of paints to polyolefin surfaces.
摘要翻译：本发明涉及含有0.5-40重量％改性聚烯烃和选自酯溶剂，酮溶剂，脂族溶剂，芳族溶剂及其混合物的溶剂的溶剂型底漆组合物。改性聚烯烃由选自聚丙烯和丙烯共聚物或丙烯三元共聚物或乙烯共聚物或三元共聚物的无定形聚烯烃形成。优选地，聚烯烃是含有约1至约99摩尔％乙烯，1-丁烯，1-戊烯和1-己烯的聚丙烯共聚物或三元共聚物。无定形聚烯烃的数均分子量为约1,000至15,000，并用一种或多种选自酸，酯和酸酐的不饱和羧酸进行化学改性。这些底漆可用于显着改善涂料对聚烯烃表面的粘合性。

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