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1. 发明申请

US20080255394A1 High productivity process for alkylphenol ethoxylates 有权
标题翻译：烷基酚乙氧基化物的高生产率工艺
公开(公告)号：US20080255394A1
公开(公告)日：2008-10-16
申请号：US11787351
申请日：2007-04-16
申请人： Kenneth G. McDaniel , Jack R. Reese
发明人： Kenneth G. McDaniel , Jack R. Reese
IPC分类号： C07C41/01
CPC分类号： C08G65/2696 , C08G65/2612 , C08G65/2663
摘要： The present invention provides a process for the production of an alkylphenol ethoxylate involving charging a portion of product from a previous preparation (a “heel”) or an ethoxylate to a reactor, optionally, charging from about 0.2 wt. % to an amount equal to or greater than the weight of the heel of an alkylphenol starter to the reactor, charging ethylene oxide to activate a double metal cyanide (“DMC”) catalyst, adding the alkylphenol starter simultaneously with ethylene oxide for a portion of the process and continuing ethylene oxide addition following completion of the simultaneous alkylphenol starter and ethylene oxide addition. The process of the present invention provides significant improvements in cycle time and safety in producing ethoxylates which may find use in or as surfactants.
摘要翻译：本发明提供了一种制备烷基酚乙氧基化物的方法，其包括将来自先前制备物（“脚后跟”）或乙氧基化物的一部分产物装入反应器，任选地，将约0.2wt。％至等于或大于烷基酚起始物到反应器的后跟的重量的量，加入环氧乙烷以活化双金属氰化物（“DMC”）催化剂，将烷基酚起始物与环氧乙烷同时加入一部分完成同时烷基酚起始物和环氧乙烷添加后的方法和持续的环氧乙烷添加。本发明的方法提供循环时间和生产乙氧基化物的安全性方面的显着改进，其可用于或作为表面活性剂。

2. 发明申请

US20080132729A1 Continuous process for the production of ethoxylates 审中-公开
标题翻译：用于生产乙氧基化物的连续方法
公开(公告)号：US20080132729A1
公开(公告)日：2008-06-05
申请号：US11607349
申请日：2006-12-01
申请人： Kenneth G. McDaniel , Jack R. Reese
发明人： Kenneth G. McDaniel , Jack R. Reese
IPC分类号： C07C41/03
CPC分类号： C07C41/03 , C08G65/2609 , C08G65/2663 , C08G65/2696 , C07C43/11
摘要： The present invention provides continuous processes for the production of an ethoxylate from a C1-C26 non-phenolic alcohol in the presence of a double metal cyanide (“DMC”) catalyst. The inventive multi-stage continuous process produces an ethoxylate product with an essentially equivalent molecular weight distribution as compared to the same ethoxylate made by basic catalysis. The inventive single-stage continuous process produces ethoxylate products having only a slightly broader molecular weight distribution than the multi-stage process. The products made by the inventive multi-stage continuous process may offer advantages where the ethoxylate product is used in or as a surfactant.
摘要翻译：本发明提供了在双金属氰化物（“DMC”）存在下从C 1 -C 26非酚性醇生产乙氧基化物的连续方法，催化剂。与通过碱性催化制备的相同的乙氧基化物相比，本发明的多阶段连续方法产生具有基本上等同的分子量分布的乙氧基化产物。本发明的单级连续方法产生的乙氧基化产物仅具有比多级方法稍宽的分子量分布。通过本发明的多阶段连续方法制备的产品可以提供其中乙氧基化物产物在表面活性剂中或作为表面活性剂使用的优点。

3. 发明申请

US20080255378A1 High productivity process for non-phenolic ethoxylates 审中-公开
标题翻译：非酚类乙氧基化物的高生产率工艺
公开(公告)号：US20080255378A1
公开(公告)日：2008-10-16
申请号：US11787338
申请日：2007-04-16
申请人： Kenneth G. McDaniel , Jack R. Reese
发明人： Kenneth G. McDaniel , Jack R. Reese
IPC分类号： C07D301/03
CPC分类号： C08G65/2609 , C08G65/2663 , C08G65/2696
摘要： The present invention provides a process for the production of an ethoxylate involving charging a portion of product from a previous preparation (a “heel”) or an ethoxylate to a reactor, optionally, charging from about 0.2 wt. % to an amount equal or greater than the amount of heel of a C1-C56 non-phenolic alcohol to the reactor, charging ethylene oxide to activate a double metal cyanide (“DMC”) catalyst, adding C1-C56 non-phenolic alcohol simultaneously with ethylene oxide for a portion of the process and continuing addition of ethylene oxide following completion of the simultaneous C1-C56 non-phenolic alcohol and ethylene oxide addition. The process of the present invention provides significant improvements in cycle time and safety in producing ethoxylates which may find use in or as surfactants.
摘要翻译：本发明提供一种生产乙氧基化物的方法，其包括将来自先前制备物（“脚后跟”）或乙氧基化物的一部分产物装入反应器，任选地，将约0.2wt。％至等于或大于C 1 -C 15非酚性醇的量的量加入到反应器中，加入环氧乙烷以活化双金属氰化物（“DMC”）催化剂，与环氧乙烷同时加入C 1 -C 15 - 非酚性酚，用于该方法的一部分并在完成后继续加入环氧乙烷同时进行的C 1 -C 56非酚性醇和环氧乙烷的加成。本发明的方法提供循环时间和生产乙氧基化物的安全性方面的显着改进，其可用于或作为表面活性剂。

4. 发明申请

US20080132728A1 Continuous processes for the production of alkylphenol ethoxylates 审中-公开
标题翻译：生产烷基酚乙氧基化物的连续方法
公开(公告)号：US20080132728A1
公开(公告)日：2008-06-05
申请号：US11607537
申请日：2006-12-01
申请人： Kenneth G. McDaniel , Jack R. Reese
发明人： Kenneth G. McDaniel , Jack R. Reese
IPC分类号： C07C41/03
CPC分类号： C07C41/03 , C08G65/2612 , C08G65/2663 , C08G65/2696 , C07C43/23
摘要： The present invention provides continuous processes for the production of an alkylphenol ethoxylate from an alkylphenol in the presence of a double metal cyanide (“DMC”) catalyst. The products made by the inventive continuous processes may offer advantages where the alkylphenol ethoxylate is used in or as a surfactant.
摘要翻译：本发明提供了在双金属氰化物（“DMC”）催化剂存在下由烷基酚生产烷基酚乙氧基化物的连续方法。通过本发明的连续方法制备的产品可以提供其中烷基酚乙氧基化物在表面活性剂中或作为表面活性剂使用的优点。

5. 发明授权

US07473677B2 High productivity process for alkylphenol ethoxylates 有权
标题翻译：烷基酚乙氧基化物的高生产率工艺
公开(公告)号：US07473677B2
公开(公告)日：2009-01-06
申请号：US11787351
申请日：2007-04-16
申请人： Kenneth G. McDaniel , James R. Reese, II
发明人： Kenneth G. McDaniel , James R. Reese, II
IPC分类号： C11D1/72 , C11D13/00 , C07C41/01 , C07C43/164
CPC分类号： C08G65/2696 , C08G65/2612 , C08G65/2663
摘要： The present invention provides a process for the production of an alkylphenol ethoxylate involving charging a portion of product from a previous preparation (a “heel”) or an ethoxylate to a reactor, optionally, charging from about 0.2 wt. % to an amount equal to or greater than the weight of the heel of an alkylphenol starter to the reactor, charging ethylene oxide to activate a double metal cyanide (“DMC”) catalyst, adding the alkylphenol starter simultaneously with ethylene oxide for a portion of the process and continuing ethylene oxide addition following completion of the simultaneous alkylphenol starter and ethylene oxide addition. The process of the present invention provides significant improvements in cycle time and safety in producing ethoxylates which may find use in or as surfactants.
摘要翻译：本发明提供了一种制备烷基酚乙氧基化物的方法，其包括将来自先前制备物（“脚后跟”）或乙氧基化物的一部分产物装入反应器，任选地，将约0.2wt。％至等于或大于烷基酚起始物到反应器的后跟的重量的量，加入环氧乙烷以活化双金属氰化物（“DMC”）催化剂，将烷基酚起始物与环氧乙烷同时加入一部分完成同时烷基酚起始物和环氧乙烷添加后的方法和持续的环氧乙烷添加。本发明的方法提供循环时间和生产乙氧基化物的安全性方面的显着改进，其可用于或作为表面活性剂。

6. 发明申请

US20080167501A1 High productivity alkoxylation processes 审中-公开
标题翻译：高生产率烷氧基化方法
公开(公告)号：US20080167501A1
公开(公告)日：2008-07-10
申请号：US11893452
申请日：2007-08-16
申请人： Kenneth G. McDaniel
发明人： Kenneth G. McDaniel
IPC分类号： C07C41/01
CPC分类号： C08G65/2696 , C08G65/2606 , C08G65/2651 , C08G65/266 , C08G65/2663
摘要： The present invention provides a continuous process for the preparation of a polyoxyalkylene polyether product of number average molecular weight N employing continuous addition of starter, involving a) establishing in a continuous reactor a first portion of a catalyst/initial starter mixture effective initiate polyoxyalkylation of the initial starter after introduction of alkylene oxide into the continuous reactor, b) continuously introducing into the continuous reactor one or more alkylene oxides, c) continuously introducing into the continuous reactor one or more continuously added starters which may be the same or different than said initial starter, d) continuously introducing into the reactor fresh catalyst and/or further catalyst/further starter mixture such that the catalytic activity is maintained, wherein the catalyst is selected from the group consisting of modified oxides and hydroxides of calcium, strontium and barium, lanthanum phosphates or lanthanide series (rare earth) phosphates and hydrotalcites and synthetic hydrotalcites, e) polyoxyalkylating combined starters by continuously practicing at least steps b) through d) herein until a polyoxyalkylene polyether product of number average molecular weight N is obtained and f) continuously removing the polyoxyalkylene polyether product from the continuous reactor. Modified-calcium hydroxide or modified calcium oxide and lanthanum phosphate catalysts exhibit catch-up kinetics and are thus useful for the production of polyalkylene oxides using the continuous and CAOS processes.
摘要翻译：本发明提供了连续加入起始物制备数均分子量为N的聚氧化烯聚醚产物的连续方法，该方法包括：a）在连续反应器中建立第一部分催化剂/初始起动剂混合物，有效引发聚氧烷基化将烯化氧引入连续反应器中的初始起始物，b）连续地向连续反应器中引入一种或多种烯化氧，c）连续地向连续反应器中引入一个或多个连续添加的起始器，其可以与所述初始化合物相同或不同起始物，d）连续向反应器中引入新鲜催化剂和/或其它催化剂/进一步起动混合物以保持催化活性，其中催化剂选自钙，锶和钡的改性氧化物和氢氧化物，镧磷酸盐或镧系（稀土）磷酸盐和水滑石和合成水滑石，e）通过连续实施至少步骤b）至d）在本文中直到形成数均分子量为N的聚氧化亚烷基聚醚产物并且f）从连续反应器中连续除去聚氧化烯聚醚产物。改性氢氧化钙或改性氧化钙和磷酸镧催化剂表现出追赶动力学，因此可用于使用连续和CAOS方法生产聚环氧烷。

7. 发明授权

US6034208A Copolymers useful as cement additives and a process for their preparation 失效
标题翻译：可用作水泥添加剂的共聚物及其制备方法
公开(公告)号：US6034208A
公开(公告)日：2000-03-07
申请号：US74673
申请日：1998-05-08
申请人： Kenneth G. McDaniel , Edward T. Shawl , Xinhau Zhou
发明人： Kenneth G. McDaniel , Edward T. Shawl , Xinhau Zhou
IPC分类号： C08G65/10 , C08G65/26 , C08G59/00
CPC分类号： C08G18/635 , C08F2/40 , C08G18/636 , C08G65/10 , C08G65/2609 , C08G65/2615 , C08G65/2663 , C08G65/2696
摘要： Unique, well defined macromonomers containing hydroxyl-functionality, unsaturation-functionality, and polyoxyalkylene segments are prepared by oxyalkylating an unsaturated initiator molecule having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting unsaturated macromonomers are eminently suitable for such uses as copolymerization with ethylenically unsaturated monomers containing carboxylic acid-based groups such as acrylic acid to form effective superplasticizers and water reducers for cement and concrete applications.
摘要翻译：含有羟基官能团，不饱和官能度和聚氧化烯链段的独特的，明确定义的大单体通过在有效量的双金属氰化物配合物催化剂存在下，任选地，当需要时，使具有至少一个可氧化烷基化氢的不饱和引发剂分子在自由基聚合抑制剂存在下进行。所得的不饱和大单体非常适用于与含有羧酸基团的烯属不饱和单体如丙烯酸共聚形成用于水泥和混凝土应用的有效超增塑剂和减水剂的用途。

8. 发明授权

US4642319A Modified terephthalic ester polyols and rigid foams therefrom 失效
标题翻译：改性对苯二甲酸酯多元醇及其刚性泡沫
公开(公告)号：US4642319A
公开(公告)日：1987-02-10
申请号：US821319
申请日：1986-01-22
申请人： Kenneth G. McDaniel
发明人： Kenneth G. McDaniel
IPC分类号： C08G18/42 , C08G18/46 , C08G18/14 , C08G18/32 , C08G18/34
CPC分类号： C08G18/4219 , C08G18/4213 , C08G18/4615 , C08G2101/0025 , C08G2105/02 , Y10S521/902
摘要： The preparation of isocyanurate foams from a recycled polyethylene terephthalate polyol modified with aromatic amino polyols, sucrose polyols, ethoxylated alphamethyl glucosides, alkoxylated glycerine or alkoxylated sorbitol is disclosed. These modified foams exhibit improved fluorocarbon solubility. The foams may be used for building roofing and sheathing applications.
摘要翻译：公开了由芳族氨基多元醇，蔗糖多元醇，乙氧基化α-甲基葡糖苷，烷氧基化甘油或烷氧基化山梨醇改性的再循环聚对苯二甲酸乙二醇酯多元醇制备异氰脲酸酯泡沫。这些改性泡沫表现出改善的氟碳溶解度。泡沫可用于建筑屋顶和护套应用。

9. 发明授权

US5157057A Rim compositions using amino acid salt catalysts 失效
标题翻译：使用氨基酸盐催化剂的轮圈组合物
公开(公告)号：US5157057A
公开(公告)日：1992-10-20
申请号：US738081
申请日：1991-07-30
申请人： Maureen T. Pence , Kenneth G. McDaniel
发明人： Maureen T. Pence , Kenneth G. McDaniel
IPC分类号： C08G18/18
CPC分类号： C08G18/18 , C08G18/1875 , C08G2105/02 , C08G2120/00
摘要： Reaction injection molded (RIM) or structural RIM (SRIM) resins having improved (prolonged) set times, that is, reduced reactivity, may be produced by the addition of an acid blocked amino acid salt catalyst as co-catalyst, or even as a sole catalyst. This permits large molds to be filled completely before cure. However, cure rates are not affected permitting high production rates. The physical properties of RIM and SRIM compositions do not suffer from the addition of these co-catalysts. The amino acid salts may have the formula: ##STR1## where R and R' are independently selected from the group consisting of hydrogen and alkyl having 1 to 12 carbon atoms; where the R" groups are independently alkylene groups having from 1 to 4 carbon atoms; where M is an alkali metal; and where x ranges from 1 to 4.
摘要翻译：具有改善（延长）凝固时间，即反应性降低的反应注射成型（RIM）或结构RIM（SRIM）树脂可以通过加入酸封闭的氨基酸盐催化剂作为助催化剂，或者甚至作为唯一的催化剂。这样可以使固化前大量的模具完全充满。然而，治疗率不受影响，允许高生产率。 RIM和SRIM组合物的物理性质不会加入这些助催化剂。氨基酸盐可以具有下式：其中R和R'独立地选自氢和具有1至12个碳原子的烷基; 其中R“基团独立地为具有1至4个碳原子的亚烷基; 其中M是碱金属; 其中x的范围为1到4。

10. 发明授权

US4654376A Polyurethane foams based on amino polyols 失效
标题翻译：基于氨基多元醇的聚氨酯泡沫
公开(公告)号：US4654376A
公开(公告)日：1987-03-31
申请号：US791015
申请日：1985-10-24
申请人： Michael E. Brennan , Kenneth G. McDaniel , Howard P. Klein
发明人： Michael E. Brennan , Kenneth G. McDaniel , Howard P. Klein
IPC分类号： C08G18/50 , C08G18/54 , C08G18/14 , C08G18/32
CPC分类号： C08G18/5033 , C08G18/546 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , Y10S521/902
摘要： An improved method for preparing amino polyols is disclosed. The method is the Mannich condensation of phenol, formaldehyde and diethanolamine in a molar ratio of (1:1:1), and then alkoxylation with a mixture of ethylene oxide and propylene oxide in a weight ratio of about 5:95 to 20:80 to form an amino polyol of hydroxyl number 440 to 515.The method gives higher yields of aromatic amino polyols of lower viscosity than those of the comparative example.
摘要翻译：公开了改进的制备氨基多元醇的方法。该方法是苯酚，甲醛和二乙醇胺的摩尔比为（1:1:1）的曼尼希缩合，然后用环氧乙烷和环氧丙烷的混合物以约5:95至20:80的重量比进行烷氧基化以形成羟基数为440至515的氨基多元醇。该方法提供比比较例的更低的粘度的芳族氨基多元醇的较高产率。

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