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    • 2. 发明授权
    • Viscosity modifier for lubricating oil and lubricating oil composition
    • 润滑油和润滑油组成的粘度调节剂
    • US06589920B2
    • 2003-07-08
    • US09964485
    • 2001-09-28
    • Keiji OkadaRyousuke Kaneshige
    • Keiji OkadaRyousuke Kaneshige
    • C07C900
    • C10M143/02C08F210/16C10M143/00C10M2205/00C10M2205/02C10M2205/022C10M2205/04C10M2209/084C10M2209/086C10N2220/02C10N2230/02C08F2500/03C10M2205/024
    • The lubricating oil composition of the invention comprises a lubricating oil base (A) and a copolymer (B) of ethylene and an &agr;-olefin of 3 to 20 carbon atoms. The copolymer (B) of ethylene and an &agr;-olefin of 3 to 20 carbon atoms is contained in the composition in an amount of 1 to 20% by weight and has the following properties: (1) the ethylene content (E) is in the range of 40 to 77% by weight, (2) the weight-average molecular weight (Mw) in terms of polystyrene, as measured by GPC, is in the range of 80,000 to 400,000, (3) Mw/Mn is not more than 2.4, (4) the melting point (Tm), as measured by DSC, is not higher than 60° C., (5) the ethylene content (E, % by weight) and the melting point (Tm, ° C.), as measured by DSC, satisfy the following relation (I): 3.31×E−186≧Tm  (I), and (6) the intensity ratio, S&agr;&bgr;/S&agr;&agr;, measured by 13C-NMR spectrum is not more than 0.5.
    • 本发明的润滑油组合物包含乙烯和3-20个碳原子的α-烯烃的润滑油基料(A)和共聚物(B)。 乙烯和3〜20个碳原子的α-烯烃的共聚物(B)的含量为1〜20重量%,具有以下性质:(1)乙烯含量(E)为 40〜77重量%的范围,(2)通过GPC测定的聚苯乙烯换算重量平均分子量(Mw)在80,000〜400,000的范围内,(3)Mw / Mn不大 超过2.4,(4)通过DSC测量的熔点(Tm)不高于60℃,(5)乙烯含量(E,重量%)和熔点(Tm,℃) )通过DSC测量满足以下关系式(I):(6)通过13 C-NMR光谱测定的浓度比Salimuma / Salphaalpha不大于0.5。
    • 4. 发明授权
    • Viscosity modifier for lubricating oil and lubricating oil composition
    • 润滑油和润滑油组成的粘度调节剂
    • US06525007B2
    • 2003-02-25
    • US09876865
    • 2001-06-08
    • Keiji OkadaRyousuke Kaneshige
    • Keiji OkadaRyousuke Kaneshige
    • C07C900
    • C10M177/00C10M143/02C10M143/04C10M157/00C10M171/00C10M2205/00C10M2205/022C10M2205/024C10N2220/02
    • The present invention is intended to obtain a viscosity modifier for a lubricating oil, by the use of which a lubricating oil composition of excellent low-temperature properties can be obtained, and to obtain a lubricating oil composition of excellent low-temperature properties containing the viscosity modifier. The viscosity modifier for a lubricating oil comprises an ethylene/propylene copolymer (A) having the properties: the density is in the range of 857 to 882 kg/m3, Mw is in the range of 80,000 to 400,000, Mw/Mn is not more than 2.3, and the density (D (kg/m3)) and the melting point (Tm (° C.)) satisfy the relation Tm≦1.247×D−1037; or comprises an ethylene/propylene copolymer (B) having the properties: the ethylene content is in the range of 70 to 79 wt %, Mw is not less than 80,000 and less than 250,000, Mw/Mn is not more than 2.3, Tm is in the range of 15 to 60° C., and the ethylene content (E (wt %)) and the melting point (Tm (° C.)) satisfy the relation 3.44×E−206≧Tm; or comprises an ethylene/propylene copolymer (C) having the properties: the ethylene content is in the range of 70 to 79 wt %, Mw is in the range of 250,000 to 400,000, Mw/Mn is not more than 2.3, Tm is in the range of 15 to 60° C., and the ethylene content (E (wt %)) and the melting point (Tm (° C.)) satisfy the relation 3.44×E−204≧Tm. The lubricating oil composition comprises the ethylene/propylene copolymer (A) (B) or (C), a lubricating oil base (D), and if necessary, a pour point depressant.
    • 本发明旨在获得润滑油的粘度调节剂,通过使用可以获得具有优异的低温性能的润滑油组合物,并获得含有粘度的优异的低温性能的润滑油组合物 修饰语。 用于润滑油的粘度调节剂包括具有以下性质的乙烯/丙烯共聚物(A):密度在857-882kg / m 3的范围内,Mw在80,000至400,000范围内,Mw / Mn不大 (D(kg / m3))和熔点(Tm(℃))满足Tm <= 1.247×D-1037的关系; 或包含乙烯/丙烯共聚物(B),其乙烯含量在70至79重量%范围内,Mw不小于80,000且小于250,000,Mw / Mn不大于2.3,Tm为 在15〜60℃的范围内,乙烯含量(E(wt%))和熔点(Tm(℃))满足关系3.44×E-206> = Tm; 或包含具有以下性质的乙烯/丙烯共聚物(C):乙烯含量在70至79重量%的范围内,Mw在250,000至400,000的范围内,Mw / Mn不大于2.3,Tm在 15〜60℃的范围和乙烯含量(E(重量%))和熔点(Tm(℃))满足关系3.44×E-204> = Tm。 润滑油组合物包含乙烯/丙烯共聚物(A)(B)或(C),润滑油基料(D),如果需要,还含有倾点降低剂。
    • 10. 发明授权
    • Lubricating oil or lubricating oil composition and fuel oil composition
    • 润滑油或润滑油组成和燃油组成
    • US06214779B1
    • 2001-04-10
    • US09101335
    • 1998-07-07
    • Ryousuke KaneshigeHideki HiranoMasahide TanakaKenichi MorizonoKeiji Okada
    • Ryousuke KaneshigeHideki HiranoMasahide TanakaKenichi MorizonoKeiji Okada
    • C10M10102
    • C10L10/08C08L23/0815C08L91/00C10L1/165C10M107/02C10M107/12C10M143/00C10M143/10C10M2205/00C10M2205/02C10M2205/0206C10M2205/04C10M2205/043C08L2666/02
    • The present invention is directed towards a lubricating oil comprising a random copolymer of an &agr;-olefin/aromatic vinyl compound, wherein the copolymer has a viscosity falling within a specific range and comprises ethylene, an aromatic vinyl compound, and optionally an &agr;-olefin. The lubricating oil possesses excellent viscosity properties, thermal stability, oxidation stability, abrasion resistance, and compatibility with lubricating oil additives. The random copolymer having a different viscosity range is useful as a viscosity index improver and a compatibilizing agent for a lubricating oil. The invention also provides a lubricating oil composition comprising a base oil and the viscosity index improver or the compatibilizing agent. The invention further provides a fuel oil composition comprising a fuel oil fluidity improver based on the above random copolymer having a different viscosity range and a middle fraction fuel oil having a boiling point of 150 to 400° C. The fuel oil composition prevents an increase in viscosity of the middle fraction fuel oil, lowers the clogging point and the flow point in a low-temperature filter, and inhibits the abrasion of a fuel jet nozzle.
    • 本发明涉及包含α-烯烃/芳族乙烯基化合物的无规共聚物的润滑油,其中所述共聚物的粘度落在特定范围内并且包含乙烯,芳族乙烯基化合物和任选的α-烯烃。 润滑油具有优异的粘度性能,热稳定性,氧化稳定性,耐磨性和与润滑油添加剂的相容性。 具有不同粘度范围的无规共聚物可用作粘度指数改进剂和润滑油相容剂。 本发明还提供一种包含基础油和粘度指数改进剂或相容剂的润滑油组合物。 本发明还提供了一种燃料油组合物,其包含基于上述具有不同粘度范围的无规共聚物的燃料油流动性改进剂和沸点为150-400℃的中间馏分燃料油。燃料油组合物防止了 中间馏分燃料油的粘度降低低温过滤器中的堵塞点和流动点,并且抑制燃料喷嘴的磨损。