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1. 发明授权

US5035985A Silver halide photographic development and washing process of the containing element 失效
标题翻译：卤化银照相显影和洗涤过程的含有元素
公开(公告)号：US5035985A
公开(公告)日：1991-07-30
申请号：US534299
申请日：1990-06-07
申请人： Keiichi Adachi , Shigeru Ohno , Kokichi Waki
发明人： Keiichi Adachi , Shigeru Ohno , Kokichi Waki
IPC分类号： G03C1/825 , G03C1/83
CPC分类号： G03C1/832
摘要： A method for processing a silver halide photographic element comprising carrying out developement processing, including a washing step, of an imagewise exposed silver halide photographic element, wherein the washing step is carried out at 45.degree. C. or less for 90 sec. or less, and wherein the silver halide color photographic element comprises a support having provided thereon at least one silver halide emulsion layer, wherein the silver halide photographic element contains in a hydrophilic colloid layer, from 2 mg/m.sup.2 to 40 mg/n.sup.2 of at least one dye represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which can be the same or different, can each represents --COOR.sub.5, or ##STR2## R.sub.3 and R.sub.4, which can be the same or different, each represents a hydrogen atom or an alkyl group, R.sub.5 and R.sub.6, which can be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, and R.sub.1 and R.sub.2 represent --COOR.sub.5 and R.sub.5 represents a hydrogen atom, R.sub.1 and R.sub.2 represent a carboxyl group which can form a salt, R.sub.5 and R.sub.6 can combine together to form a 5- or 6-membered ring, Q.sub.1 and Q.sub.2, which can be the same or different, each represents a substituted or unsubstituted aryl group, X.sub.1 and X.sub.2, which can be the same or different, each represents a divalent linking group or a bond, Y.sub.1 and Y.sub.2, which can be the same or different, each represents a sulfo group or a carboxyl group which can form a salt, L.sub.1, L.sub.2 and L.sub.3, which can be the same or different, each represents a substituted or unsubstituted methine group, m.sub.1 and m.sub.2 each is 1 or 2, n is 0, 1 or 2, p.sub.1 and p.sub.2 each is 0, 1, 2, 3, or 4, and s.sub.1 and s.sub.2 each is 1 or 2.
摘要翻译：一种用于处理卤化银照相元件的方法，包括进行成像曝光的卤化银照相元件的洗涤步骤的洗涤步骤，其中洗涤步骤在45℃或更低温度下进行90秒。并且其中所述卤化银彩色照相元件包括其上提供有至少一个卤化银乳剂层的载体，其中所述卤化银照相元件在亲水胶体层中含有2mg / m 2至40mg / n 2的由下列通式（I）表示的至少一种染料：其中R 1和R 2可相同或不同，各自表示-COOR 5或R 3和R 4，其可以是相同或不同，各自表示氢原子或烷基，可以相同或不同的R5和R6各自表示氢原子，取代或未取代的烷基，取代或未取代的芳基，R1和R2 表示-COOR 5，R 5表示氢原子，R 1和R 2表示可以形成盐的羧基，R 5和R 6可以结合在一起形成可以相同或不相同的5-或6-元环的Q 1和Q 2，各自表示取代或未取代的芳基 p，X1和X2可以相同或不同，表示二价连接基团或键，Y1和Y2可以相同或不同，表示可以形成盐的磺基或羧基，L1，L2和L3可相同或不同，分别表示取代或未取代的次甲基，m1和m2各自为1或2，n为0,1或2，p1和p2各自为0,1或2， 2,3或4，s1和s2分别为1或2。

2. 发明授权

US5147770A Entitled silver halide photographic materials 失效
标题翻译：卤化银照相材料
公开(公告)号：US5147770A
公开(公告)日：1992-09-15
申请号：US814858
申请日：1991-12-30
申请人： Kokichi Waki , Shigeru Ohno
发明人： Kokichi Waki , Shigeru Ohno
IPC分类号： G03C1/12 , G03C1/035 , G03C1/14 , G03C7/392
CPC分类号： G03C1/14 , G03C1/035 , G03C7/39292
摘要： A silver halide color photographic material is disclosed. The photographic material comprises a support having provided thereon at least one silver halide emulsion layer wherein silver halide grains comprise monodisperse silver chlorobromide containing at least 2 mol % of silver chloride and having an area ratio of crystal face of Mirror indeces (100) satisfying the relationship:5.0.ltoreq.K.ltoreq..infin.wherein K represents the ratio of the intensity of diffracted rays attributable to (200) face to that of diffracted rays attributable to (222) face determined by X-ray diffraction analytical method, represented by: ##EQU1## and wherein said silver halide color photographic material contains at least one dye represented by the formula (II): ##STR1## wherein n, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and L are as defined above.
摘要翻译：公开了一种卤化银彩色照相材料。照相材料包括其上设置有至少一个卤化银乳剂层的载体，其中卤化银颗粒包含含有至少2mol％氯化银的单分散氯化银，并且具有满足关系的镜面凹痕（100）的晶面面积比：5.0

3. 发明授权

US4923638A Near infrared absorbing composition 失效
标题翻译：近红外吸收组合物
公开(公告)号：US4923638A
公开(公告)日：1990-05-08
申请号：US331075
申请日：1989-03-28
申请人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi , Toshinao Ukai , Gouichi Hayashi
发明人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi , Toshinao Ukai , Gouichi Hayashi
IPC分类号： B41M5/46
CPC分类号： B41M5/465
摘要： A near infrared absorbing composition is disclosed, containing at least one compound represented by general formula (I), having its absorption maxima at wavelengths of 720 nm or more: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sup.2 and R.sup.5, which may be the same or different, each represents a hydrogen atom or a group capable of substituting a hydrogen atom; R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted alkyl group with the proviso that they do not simultaneously represent hydrogen atoms; and R.sup.6 and R.sup.7, which may be the same or different, each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an acyl group or a sulfonyl group, or R.sup.6 and R.sup.7 may be taken together to form a 5- or 6-membered ring.
摘要翻译：公开了一种近红外线吸收组合物，其含有至少一种通式（I）表示的化合物，其波长为720nm以上的吸收最大值：其中R 1表示取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂环基; R 2和R 5可以相同或不同，各自表示氢原子或能够取代氢原子的基团; R 3和R 4可以相同或不同，各自表示氢原子，卤素原子，取代或未取代的烷氧基或取代或未取代的烷基，条件是它们不同时表示氢原子; 和可以相同或不同的R 6和R 7各自表示取代或未取代的烷基，取代或未取代的芳基，酰基或磺酰基，或者R 6和R 7可以一起形成5- 或6元环。

4. 发明授权

US4920031A Silver halide photographic light-sensitive elements containing water soluble dyestuffs 失效
标题翻译：含有水溶性染料的卤化银照相感光元件
公开(公告)号：US4920031A
公开(公告)日：1990-04-24
申请号：US208608
申请日：1988-06-20
申请人： Shigeru Ohno , Yoshio Inagaki , Keiichi Adachi , Yasuhito Momoki
发明人： Shigeru Ohno , Yoshio Inagaki , Keiichi Adachi , Yasuhito Momoki
IPC分类号： G03C1/825 , C09B23/04 , C09B23/06 , C09B23/08 , G03C1/83
CPC分类号： C09B23/06 , C09B23/04 , C09B23/083 , G03C1/832
摘要： There are provided by the invention silver halide photographic light-sensitive materials containing dyestuff(s) represented by the general formula (I): ##STR1## wherein R.sup.1, R.sup.3, R.sup.4, R.sup.6, L.sub.1, L.sub.2, L.sub.3, Z.sup.1 and Z.sup.2 are groups conventional in this technical field, and R.sup.2 and R.sup.5 each represent an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, COR.sup.7 and SO.sub.2 R.sup.7 (wherein R.sup.7 represents an optionally substituted alkyl group or an optionally substituted aryl group) (including the case where the dyestuff(s) is(are) in the form of salt(s)).The dyestuff(s) act(s) as a coloring agent for colored layer(s) for color filtering, antihalation, antiiradiation, etc.Silver halide photographic light-sensitive materials containing dyestuffs represented by the general formula (I) of the invention have remarkable effects, for example, that stability of dyestuffs in the membrane with time lapse is high, relative sensitivity is high, lowering of sensitivity in exposure to light under high humidity is small, image quality is excellent, there is only a little remaining color, and/or there is only a little fog, as compared with silver halide photographic light-sensitive materials containing conventional dyestuffs for the aforementioned purposes.

5. 发明授权

US4833246A Novel pyrazolone dye 失效
标题翻译：新型吡唑啉酮染料
公开(公告)号：US4833246A
公开(公告)日：1989-05-23
申请号：US127309
申请日：1987-12-02
申请人： Keiichi Adachi , Shigeru Ohno , Yoshio Inagaki , Nobuo Seto , Yoshihiro Jinbo
发明人： Keiichi Adachi , Shigeru Ohno , Yoshio Inagaki , Nobuo Seto , Yoshihiro Jinbo
IPC分类号： C09B23/00 , C07D231/24 , C09B23/01 , C09B23/04 , C09B23/06 , C09B23/08 , G03C1/83
CPC分类号： C07D231/24 , C09B23/04 , C09B23/06 , C09B23/083 , G03C1/832
摘要： A novel pyrazolone dye represented by the following formula (I), which can be effectively used as a filter dye, an irradiation inhibiting dye, an antihalation dye or the like in a photographic light-sensitive material: ##STR1## wherein R.sub.1 and R.sub.2 each represents --COOR or ##STR2## R and R' each represents a hydrogen atom, an alkyl group, or an aryl group or may combine with each other to form a 5- or 6-membered ring; Q.sub.1 and Q.sub.2 each represents an aryl group; X.sub.1 and X.sub.2 each represents a linkage group; Y.sub.1 and Y.sub.2 each represents a sulfo group or a carboxyl group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; L.sub.4 and L.sub.5 each represents an alkylene group; m.sub.1 and m.sub.2 each represents 1 or 2; n represents 0, 1 or 2; p.sub.1 and p.sub.2 each represents 0 or 1; q.sub.1 and q.sub.2 each represent 0, 1, 2, 3 or 4; and s.sub.1 and s.sub.2 each represents 1 or 2.
摘要翻译：由下式（I）表示的新颖的吡唑啉酮染料，其可以有效地用作照相感光材料中的滤光染料，照射抑制染料，防光晕染料等：其中R1 并且R 2各自表示-COOR或R 3，R'各自表示氢原子，烷基或芳基，或者可以彼此结合形成5-或6-元环; Q1和Q2各自表示芳基; X1和X2各自表示连接基团; Y1和Y2各自表示磺基或羧基; L1，L2和L3各自表示次甲基; L4和L5各自表示亚烷基; m1和m2各自表示1或2; n表示0,1或2; p1和p2各自表示0或1; q1和q2各自表示0,1,2,3或4; s1和s2各自表示1或2。

6. 发明授权

US5106990A Indolenine derivatives as dyes 失效
标题翻译：吲哚啉衍生物作为染发剂
公开(公告)号：US5106990A
公开(公告)日：1992-04-21
申请号：US329858
申请日：1989-03-28
申请人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi
发明人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi
IPC分类号： G03C1/825 , G03C1/83
CPC分类号： G03C1/832
摘要： The present invention relates to a dye represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a C.sub.1 -C.sub.5 alkyl group or a C.sub.1 -C.sub.5 alkyl group having a substituent selected from the group consisting of a sulfonic group, carboxyl group and hydroxyl group, and Z.sup.1 and Z.sup.2 each represents a group of non-metallic atoms necessary for the formation of a benzo-condensed of naphtho-condensed ring, or a benzo-condensed or naphtho-condensed ring having a substituent selected from the group consisting of a sulfonic group, a carboxyl group, an hydroxyl group, a halogen atom, a cyano group, an amino group and a C.sub.1 -C.sub.5 alkyl group connected to the ring directly or through a divalent connection group, with a proviso that R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, Z.sup.1 and Z.sup.2 represent those groups which permit the dye molecule to have at least three acid radicals; L represents a methine group of a methine group having a substituent selected from the group consisting of a C.sub.1 -C.sub.5 alkyl group, a C.sub.1 -C.sub.5 alkyl group having a substituent selected from an hydroxyl group, a phenyl group, or a sulfo group, a halogen atom, a phenyl group, a 4-chlorophenyl group, and a C.sub.1 -C.sub.2 alkoxyl group; X represents an anion; and n represents 1 or 2, n being 1 when the dye forms an inner salt.

7. 发明授权

US4933268A Silver halide photographic material having at least one dyed hydrophilic colloid layer 失效
标题翻译：卤化银照相材料具有至少一种染色的亲水胶体层
公开(公告)号：US4933268A
公开(公告)日：1990-06-12
申请号：US270585
申请日：1988-11-14
申请人： Shigeru Ohno , Tadashi Ito , Sumito Yamada , Tomokazu Yasuda , Keiichi Adachi
发明人： Shigeru Ohno , Tadashi Ito , Sumito Yamada , Tomokazu Yasuda , Keiichi Adachi
IPC分类号： G03C1/83
CPC分类号： G03C1/832 , Y10S430/142
摘要： A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer containing at least one dye represented by formula (I), ##STR1## wherein R.sub.1 represents a substituted aryl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or a substituted or unsubstituted heterocyclic group, each group being substituted by at least one carboxylic acid group or sulfonic acid group; R.sub.2 represents --CONR.sub.3 R.sub.4 or --NR.sub.3 COR.sub.4, wherein R.sub.3 represents a hydrogen atom or an alkyl group and R.sub.4 represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group having a hydrophobic substituent constant .pi. in the range of about 1.60.ltoreq..pi..ltoreq.about 3.90; L.sub.1, L.sub.2, and L.sub.3 each represents a substituted or unsubstituted methine group; and n represents 0, 1, or 2.

8. 发明授权

US4879204A Silver halide photographic element containing anhydazine compound and specific dyes 失效
标题翻译：含有肼基化合物和特定染料的卤化银照相元件
公开(公告)号：US4879204A
公开(公告)日：1989-11-07
申请号：US232526
申请日：1988-08-16
申请人： Kunio Ishigaki , Toshiro Takahashi , Yuji Mihara , Keiichi Adachi , Shigeru Ohno , Masahiro Okada , Naomi Saeki
发明人： Kunio Ishigaki , Toshiro Takahashi , Yuji Mihara , Keiichi Adachi , Shigeru Ohno , Masahiro Okada , Naomi Saeki
IPC分类号： G03C1/06 , G03C1/825 , G03C7/30
CPC分类号： G03C1/825 , G03C1/061 , G03C7/30 , G03C2001/0471 , Y10S430/162
摘要： A silver halide photographic material is described, comprising a support having formed thereon at least one silver halide emulsion layer and at least one light-insensitive hydrophilic colloid layer, wherein at least one of layers consisting of said at least one silver halide emulsion layer and said at least one light-insensitive hydrophilic colloid layer contains a hydrazine derivative, and wherein at least one of said at least one light-insensitive hydrophilic colloid layer that is formed on the uppermost silver halide emulsion layer contains a dye.
摘要翻译：描述了卤化银照相材料，其包括其上形成有至少一个卤化银乳剂层和至少一种不透光的亲水胶体层的载体，其中至少一层由所述至少一个卤化银乳剂层和所述至少一个不透光的亲水胶体层含有肼衍生物，并且其中形成在最上面的卤化银乳剂层上的所述至少一个不透光的亲水胶体层中的至少一个含有染料。

9. 发明授权

US4839265A Silver halide photosensitive material containing an infrared absorption dye 失效
标题翻译：含有红外吸收染料的卤化银感光材料
公开(公告)号：US4839265A
公开(公告)日：1989-06-13
申请号：US147571
申请日：1988-01-19
申请人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi
发明人： Shigeru Ohno , Yuji Mihara , Keiichi Adachi
IPC分类号： G03C1/825 , G03C1/83 , G03C1/84
CPC分类号： G03C1/832
摘要： A silver halide photosensitive material having a hydrophilic colloid layer containing a specific water-soluble dye including at least three acid radicals. The water-soluble dye in the hydrophilic colloid layer absorbs light in the infrared region but does not adversely affect the photographic characterisitics of the photographic emulsion and is discolored upon photographic processing.
摘要翻译：具有亲水胶体层的卤化银感光材料含有至少包含三个酸基的特定水溶性染料。亲水胶体层中的水溶性染料吸收红外区域的光，但不影响照相乳剂的照相特性，并且在照相处理时变色。

10. 发明授权

US5013636A Silver halide color photographic materials 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5013636A
公开(公告)日：1991-05-07
申请号：US321829
申请日：1989-03-10
申请人： Shigeru Ohno , Yoshihiro Jimbo , Keiichi Adachi , Shigeru Kuwashima
发明人： Shigeru Ohno , Yoshihiro Jimbo , Keiichi Adachi , Shigeru Kuwashima
IPC分类号： G03C7/38 , C09B23/02 , G03C1/83 , G03C7/30
CPC分类号： G03C1/832 , C09B23/02 , G03C7/301
摘要： A silver halide color photographic material comprising a support having in a layer thereon at least a dye represented by general formula (I) ##STR1## wherein R.sub.1 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, -NR.sub.7 R.sub.8, --NR.sub.7 CONR.sub.7 R.sub.8, --NR.sub.8 COR.sub.9 or --NR.sub.8 SO.sub.2 R.sub.9 ;R.sub.2 and R.sub.5, which may be the same or different, each represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, a cyano group, a sulfonic acid group, --NR.sub.7 R.sub.8, --NR.sub.8 COR.sub.9, --NR.sub.8 SO.sub.2 R.sub.9, --NR.sub.7 CONR.sub.7 R.sub.8, --COOR.sub.7, --CONR.sub.7 R.sub.8, --COR.sub.9, --SO.sub.2 R.sub.9 or --SO.sub.2 NR.sub.7 R.sub.8 ;R.sub.3 and R.sub.6, which may be the same or different, each represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, --OR.sub.7, --COOR.sub.7, --COR.sub.9, --CONR.sub.7 R.sub.8, --NR.sub.7 R.sub.8, --NR.sub.8 COR.sub.9 or --NR.sub.8 SO.sub.2 R.sub.9, --NR.sub.7 CONR.sub.7 R.sub.8, --SO.sub.2 R.sub.9, SO.sub.2 NR.sub.7 R.sub.8, --OR.sub.7 or cyano group, where R.sub.7 and R.sub.8, which may be the same or different, each represents a hydrogen atom, an aliphatic group or an aromatic group;R.sub.9 represents an aliphatic group or an aromatic group; andR.sub.7 and R.sub.8 or R.sub.8 and R.sub.9 may combine to form a 5- or 6-membered ring;L.sub.1, L.sub.2 and L.sub.3 each represents a methine group, m represents 0, 1, or 2; andM.sup..sym. represents a cation of valency n where n represents 1, 2 or 3;and least a coupler represented by general formula (II) ##STR2## wherein X represents a hydrogen atom or a substituent group; Z.sub.2 represents a hydrogen atom or coupling leaving group; W represents a hydrogen atom, an acyl group, an aliphatic sulfonyl group or an aromatic sulfonyl group; and Za and Zb represent methine, substituted methine or --N.dbd.; and dimers or higher oligomers involving X, Z.sub.2 or Za, or Zb as substituted methine.
摘要翻译：一种卤化银彩色照相材料，其包含在其上至少具有由通式（I）表示的染料的层中的载体，其中R 1和R 4可以相同或不同，各自表示氢原子，脂族基，芳基，杂环基，-NR7R8，-NR7CONR7R8，-NR8COR9或-NR8SO2R9; R 2和R 5可以相同或不同，各自表示氢原子，脂族基团，芳族基团，杂环基，氰基，磺酸基，-NR 7 R 8，-NR 8 COR 9，-NR 8 SO 2 R 9，-NR 7 CONR 7 R 8 ，-COOR 7，-CONR 7 R 8，-COR 9，-SO 2 R 9或-SO 2 NR 7 R 8; R 3和R 6可以相同或不同，表示氢原子，脂族基团，芳族基团，杂环基，-OR7，-COOR7，-COR9，-CONR7R8，-NR7R8，-NR8COR9或-NR8SO2R9 ，-NR7CONR7R8，-SO2R9，SO2NR7R8，-OR7或氰基，其中R7和R8可以相同或不同，各自表示氢原子，脂族基团或芳族基团; R9表示脂族基团或芳香族基团; 并且R 7和R 8或R 8和R 9可以结合形成5-或6-元环; L1，L2和L3各自表示次甲基，m表示0,1或2; 并且M（+）表示n价阳离子n，其中n表示1,2或3; 和最小的由通式（II）表示的成色剂（II），其中X表示氢原子或取代基; Z2表示氢原子或离去基团; W表示氢原子，酰基，脂族磺酰基或芳香族磺酰基; Za和Zb表示次甲基，取代的次甲基或-N =; 以及涉及X，Z2或Za或Zb作为取代的次甲基的二聚体或更高级的低聚物。

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